Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands

In this study, Cu(II) and Ni(II) complexes of thiourea ligands have been synthesized. The synthesized thiourea ligands were different according to the types of amino acids used which are glycine and phenylalanine. The thiourea ligands and their complexes were characterized using FTIR, UV/Visible,...

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Main Author: Norsyafikah Asyilla, Binti Nordin
Format: Final Year Project Report / IMRAD
Language:English
Published: Universiti Malaysia Sarawak, UNIMAS 2012
Subjects:
Online Access:http://ir.unimas.my/id/eprint/6270/
http://ir.unimas.my/id/eprint/6270/4/Norsyafikah%20Asyilla%20Binti%20Nordin%20ft.pdf
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author Norsyafikah Asyilla, Binti Nordin
author_facet Norsyafikah Asyilla, Binti Nordin
author_sort Norsyafikah Asyilla, Binti Nordin
building UNIMAS Institutional Repository
collection Online Access
description In this study, Cu(II) and Ni(II) complexes of thiourea ligands have been synthesized. The synthesized thiourea ligands were different according to the types of amino acids used which are glycine and phenylalanine. The thiourea ligands and their complexes were characterized using FTIR, UV/Visible, 1H and 13C NMR spectroscopic methods, CHN microelemental analysis, molar conductivity and melting points. The FTIR stretching vibrations of the complexes showed significant shift compared to the stretching vibrations for the ligands. The n→π* transition were shown for the ligands and π →π* transition were observed for the complexes. For 1H and 13CNMR, the spectra of the complexes were shifted from the spectra of the ligands. The proposed structures for the complexes were square planar and the ligands were coordinated to the metals through the carboxylate group. Complex (3) showed significant activity towards the growth of E. coli with the MIC value of 92.5 ppm.
first_indexed 2025-11-15T06:14:54Z
format Final Year Project Report / IMRAD
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institution Universiti Malaysia Sarawak
institution_category Local University
language English
last_indexed 2025-11-15T06:14:54Z
publishDate 2012
publisher Universiti Malaysia Sarawak, UNIMAS
recordtype eprints
repository_type Digital Repository
spelling unimas-62702023-11-20T07:58:23Z http://ir.unimas.my/id/eprint/6270/ Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands Norsyafikah Asyilla, Binti Nordin Q Science (General) QH301 Biology RA Public aspects of medicine In this study, Cu(II) and Ni(II) complexes of thiourea ligands have been synthesized. The synthesized thiourea ligands were different according to the types of amino acids used which are glycine and phenylalanine. The thiourea ligands and their complexes were characterized using FTIR, UV/Visible, 1H and 13C NMR spectroscopic methods, CHN microelemental analysis, molar conductivity and melting points. The FTIR stretching vibrations of the complexes showed significant shift compared to the stretching vibrations for the ligands. The n→π* transition were shown for the ligands and π →π* transition were observed for the complexes. For 1H and 13CNMR, the spectra of the complexes were shifted from the spectra of the ligands. The proposed structures for the complexes were square planar and the ligands were coordinated to the metals through the carboxylate group. Complex (3) showed significant activity towards the growth of E. coli with the MIC value of 92.5 ppm. Universiti Malaysia Sarawak, UNIMAS 2012 Final Year Project Report / IMRAD NonPeerReviewed text en http://ir.unimas.my/id/eprint/6270/4/Norsyafikah%20Asyilla%20Binti%20Nordin%20ft.pdf Norsyafikah Asyilla, Binti Nordin (2012) Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands. [Final Year Project Report / IMRAD] (Unpublished)
spellingShingle Q Science (General)
QH301 Biology
RA Public aspects of medicine
Norsyafikah Asyilla, Binti Nordin
Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
title Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
title_full Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
title_fullStr Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
title_full_unstemmed Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
title_short Synthesis, characterization and antibacterial activity of cu(II) and ni(II) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
title_sort synthesis, characterization and antibacterial activity of cu(ii) and ni(ii) complexes of 3,4,5-trimethoxybenzoyl thiourea ligands
topic Q Science (General)
QH301 Biology
RA Public aspects of medicine
url http://ir.unimas.my/id/eprint/6270/
http://ir.unimas.my/id/eprint/6270/4/Norsyafikah%20Asyilla%20Binti%20Nordin%20ft.pdf