Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands

Seven new organotin(IV) complexes (3-9) of pyruvic acid-4-ethyl-3-thiosemicarbazone (H2L1) (1) and 2- acetylpyridine-4-ethyl-3-thiosemicarbazone (HL) (2) have been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis, FT-IR and 1H NMR spectral studies. The spectroscopic...

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Main Author: Adibah Amirah, Binti Abdul Nasir
Format: Final Year Project Report / IMRAD
Language:English
Published: Universiti Malaysia Sarawak, (UNIMAS) 2012
Subjects:
Online Access:http://ir.unimas.my/id/eprint/6165/
http://ir.unimas.my/id/eprint/6165/1/Adibah%20Amirah%20Binti%20Abdul%20Nasir%20ft.pdf
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author Adibah Amirah, Binti Abdul Nasir
author_facet Adibah Amirah, Binti Abdul Nasir
author_sort Adibah Amirah, Binti Abdul Nasir
building UNIMAS Institutional Repository
collection Online Access
description Seven new organotin(IV) complexes (3-9) of pyruvic acid-4-ethyl-3-thiosemicarbazone (H2L1) (1) and 2- acetylpyridine-4-ethyl-3-thiosemicarbazone (HL) (2) have been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis, FT-IR and 1H NMR spectral studies. The spectroscopic data indicate that all the organotin(IV) complexes (3-7) of the ligand [(H2L1) (1)], the ligand moiety COO‾ act as monodentate group, and coordinated to tin(IV) atom through carboxylato-O, azomethine-N, and thiolato-S atoms. Another organotin(IV) complexes (8-9) of the ligand [(HL) (2)], coordinated to tin (IV) atom through pyridine-N, azomethine-N, and thiolato-S atoms.
first_indexed 2025-11-15T06:14:27Z
format Final Year Project Report / IMRAD
id unimas-6165
institution Universiti Malaysia Sarawak
institution_category Local University
language English
last_indexed 2025-11-15T06:14:27Z
publishDate 2012
publisher Universiti Malaysia Sarawak, (UNIMAS)
recordtype eprints
repository_type Digital Repository
spelling unimas-61652023-02-22T04:27:14Z http://ir.unimas.my/id/eprint/6165/ Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands Adibah Amirah, Binti Abdul Nasir GE Environmental Sciences Q Science (General) Seven new organotin(IV) complexes (3-9) of pyruvic acid-4-ethyl-3-thiosemicarbazone (H2L1) (1) and 2- acetylpyridine-4-ethyl-3-thiosemicarbazone (HL) (2) have been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis, FT-IR and 1H NMR spectral studies. The spectroscopic data indicate that all the organotin(IV) complexes (3-7) of the ligand [(H2L1) (1)], the ligand moiety COO‾ act as monodentate group, and coordinated to tin(IV) atom through carboxylato-O, azomethine-N, and thiolato-S atoms. Another organotin(IV) complexes (8-9) of the ligand [(HL) (2)], coordinated to tin (IV) atom through pyridine-N, azomethine-N, and thiolato-S atoms. Universiti Malaysia Sarawak, (UNIMAS) 2012 Final Year Project Report / IMRAD NonPeerReviewed text en http://ir.unimas.my/id/eprint/6165/1/Adibah%20Amirah%20Binti%20Abdul%20Nasir%20ft.pdf Adibah Amirah, Binti Abdul Nasir (2012) Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands. [Final Year Project Report / IMRAD] (Unpublished)
spellingShingle GE Environmental Sciences
Q Science (General)
Adibah Amirah, Binti Abdul Nasir
Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
title Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
title_full Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
title_fullStr Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
title_full_unstemmed Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
title_short Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
title_sort coordination chemistry of organotin(iv) complexes with substitute thiosemicarbazone ligands
topic GE Environmental Sciences
Q Science (General)
url http://ir.unimas.my/id/eprint/6165/
http://ir.unimas.my/id/eprint/6165/1/Adibah%20Amirah%20Binti%20Abdul%20Nasir%20ft.pdf