Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands
The synthesis and spectroscopic characterization of two hydrazone Schiff base ligands(1-2) and their metal complexes Zn(C30H30N6O2), Co(C30H30N6O2), Fe(C30H30N6O2), Ni(C30H26N4O6), Zn(C30H26N4O6) & Fe(C30H26N4O6) (3-8) are reported in this thesis.Hydrazone Schiff base ligands 1 and 2 were obtain...
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| Format: | Final Year Project Report / IMRAD |
| Language: | English English |
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University Malaysia Sarawak, UNIMAS.
2013
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| Online Access: | http://ir.unimas.my/id/eprint/3333/ http://ir.unimas.my/id/eprint/3333/1/Suok%20Ing%20%2824pgs%29.pdf http://ir.unimas.my/id/eprint/3333/3/Tang%20Suok%20Ing.pdf |
| _version_ | 1848835190483320832 |
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| author | Tang,, Suok Ing |
| author_facet | Tang,, Suok Ing |
| author_sort | Tang,, Suok Ing |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | The synthesis and spectroscopic characterization of two hydrazone Schiff base ligands(1-2) and their metal complexes Zn(C30H30N6O2), Co(C30H30N6O2), Fe(C30H30N6O2), Ni(C30H26N4O6), Zn(C30H26N4O6) & Fe(C30H26N4O6) (3-8) are reported in this thesis.Hydrazone Schiff base ligands 1 and 2 were obtained through the condensation reactions of 4-aminoacetophenone with benzhydrazide and 2’-hydroxyacetophenone with 4-hydroxybenzhydrazide respectively. The metal:ligand ratio is 1:2 for all
complexes 3-8. The ligands experienced keto and enol tautomerization. The hydrazone Schiff base ligands (1-2) and their metal complexes (3-8) were characterized using
FTIR, UV-Vis and 1H NMR spectroscopic studies. All hydrazone Schiff base ligands(1-2) and their metal complexes (3-8) are non-electrolyte in nature. Spectral studies suggested that hydrazone Schiff base ligand 1 acts as neutral bidentate ligand (N,O)whereas ligand 2 acts as a monoanionic bidentate ligand (N,O) towards central transition metal ions, and their metal complexes (3-8) were suggested to demonstrate a square planar geometry. |
| first_indexed | 2025-11-15T06:03:56Z |
| format | Final Year Project Report / IMRAD |
| id | unimas-3333 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T06:03:56Z |
| publishDate | 2013 |
| publisher | University Malaysia Sarawak, UNIMAS. |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-33332024-09-30T08:47:12Z http://ir.unimas.my/id/eprint/3333/ Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands Tang,, Suok Ing Q Science (General) QD Chemistry The synthesis and spectroscopic characterization of two hydrazone Schiff base ligands(1-2) and their metal complexes Zn(C30H30N6O2), Co(C30H30N6O2), Fe(C30H30N6O2), Ni(C30H26N4O6), Zn(C30H26N4O6) & Fe(C30H26N4O6) (3-8) are reported in this thesis.Hydrazone Schiff base ligands 1 and 2 were obtained through the condensation reactions of 4-aminoacetophenone with benzhydrazide and 2’-hydroxyacetophenone with 4-hydroxybenzhydrazide respectively. The metal:ligand ratio is 1:2 for all complexes 3-8. The ligands experienced keto and enol tautomerization. The hydrazone Schiff base ligands (1-2) and their metal complexes (3-8) were characterized using FTIR, UV-Vis and 1H NMR spectroscopic studies. All hydrazone Schiff base ligands(1-2) and their metal complexes (3-8) are non-electrolyte in nature. Spectral studies suggested that hydrazone Schiff base ligand 1 acts as neutral bidentate ligand (N,O)whereas ligand 2 acts as a monoanionic bidentate ligand (N,O) towards central transition metal ions, and their metal complexes (3-8) were suggested to demonstrate a square planar geometry. University Malaysia Sarawak, UNIMAS. 2013 Final Year Project Report / IMRAD NonPeerReviewed text en http://ir.unimas.my/id/eprint/3333/1/Suok%20Ing%20%2824pgs%29.pdf text en http://ir.unimas.my/id/eprint/3333/3/Tang%20Suok%20Ing.pdf Tang,, Suok Ing (2013) Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands. [Final Year Project Report / IMRAD] (Unpublished) |
| spellingShingle | Q Science (General) QD Chemistry Tang,, Suok Ing Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| title | Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| title_full | Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| title_fullStr | Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| title_full_unstemmed | Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| title_short | Synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| title_sort | synthesis and charactherization of transition metal complexes with hydrazone schiff base ligands |
| topic | Q Science (General) QD Chemistry |
| url | http://ir.unimas.my/id/eprint/3333/ http://ir.unimas.my/id/eprint/3333/1/Suok%20Ing%20%2824pgs%29.pdf http://ir.unimas.my/id/eprint/3333/3/Tang%20Suok%20Ing.pdf |