Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT)
A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV–Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data r...
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ScienceDirect
2012
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| Online Access: | http://ir.unimas.my/id/eprint/2371/ |
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| author | M.A., Salam M.A., Affan Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Bohari, Yamin Farina, Yang |
| author_facet | M.A., Salam M.A., Affan Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Bohari, Yamin Farina, Yang |
| author_sort | M.A., Salam |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV–Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) Å, α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm−1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)). |
| first_indexed | 2025-11-15T06:00:25Z |
| format | Article |
| id | unimas-2371 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| last_indexed | 2025-11-15T06:00:25Z |
| publishDate | 2012 |
| publisher | ScienceDirect |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-23712015-09-17T02:08:31Z http://ir.unimas.my/id/eprint/2371/ Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) M.A., Salam M.A., Affan Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Bohari, Yamin Farina, Yang AC Collections. Series. Collected works A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV–Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) Å, α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm−1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)). ScienceDirect 2012 Article NonPeerReviewed M.A., Salam and M.A., Affan and Fasihuddin B., Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Bohari, Yamin and Farina, Yang (2012) Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT). Journal of Organometallic Chemistry Volume 696, Issue 26, 1 January 2012, Pages 4202–4206. http://www.sciencedirect.com/science/article/pii/S0022328X11006024 |
| spellingShingle | AC Collections. Series. Collected works M.A., Salam M.A., Affan Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Bohari, Yamin Farina, Yang Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title | Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_full | Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_fullStr | Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_full_unstemmed | Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_short | Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_sort | synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(iv) complex with pyruvic acid-n(4)-cyclohexylthiosemicarbazone (h2pact) |
| topic | AC Collections. Series. Collected works |
| url | http://ir.unimas.my/id/eprint/2371/ http://ir.unimas.my/id/eprint/2371/ |