Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]
The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) hav...
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| Format: | Article |
| Language: | English |
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Elsevier B.V.
2011
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| Online Access: | http://ir.unimas.my/id/eprint/2370/ http://ir.unimas.my/id/eprint/2370/1/Synthesis%20and%20spectroscopic.pdf |
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| author | M.A., Affan M.A., Salam Fasihuddin Badruddin, Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali |
| author_facet | M.A., Affan M.A., Salam Fasihuddin Badruddin, Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali |
| author_sort | M.A., Affan |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å, c = 9.4353(2) Å. |
| first_indexed | 2025-11-15T06:00:25Z |
| format | Article |
| id | unimas-2370 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:00:25Z |
| publishDate | 2011 |
| publisher | Elsevier B.V. |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-23702023-03-29T03:27:56Z http://ir.unimas.my/id/eprint/2370/ Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] M.A., Affan M.A., Salam Fasihuddin Badruddin, Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali AC Collections. Series. Collected works The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å, c = 9.4353(2) Å. Elsevier B.V. 2011 Article NonPeerReviewed text en http://ir.unimas.my/id/eprint/2370/1/Synthesis%20and%20spectroscopic.pdf M.A., Affan and M.A., Salam and Fasihuddin Badruddin, Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta Pages 227–232, 366 (1). pp. 277-232. ISSN 0020-1693 http://www.sciencedirect.com/science/article/pii/S0020169310007425 doi:10.1016/j.ica.2010.11.002 |
| spellingShingle | AC Collections. Series. Collected works M.A., Affan M.A., Salam Fasihuddin Badruddin, Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] |
| title | Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_full | Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_fullStr | Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_full_unstemmed | Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_short | Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_sort | synthesis and spectroscopiccharacterization of organotin(iv) complexes with 2-benzoylpyridine-n(4)-cyclohexylthiosemicarbazone (hbpct) : x-ray crystal structure of [phsncl2(bpct)] |
| topic | AC Collections. Series. Collected works |
| url | http://ir.unimas.my/id/eprint/2370/ http://ir.unimas.my/id/eprint/2370/ http://ir.unimas.my/id/eprint/2370/ http://ir.unimas.my/id/eprint/2370/1/Synthesis%20and%20spectroscopic.pdf |