Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites

Styrene-co-glycidyl methacrylate-fumed silica-clay (ST-co-GMA-fsi-clay) nanocomposites have been prepared via free radical polymerization in the presence of benzoyl peroxide. The nanocomposites are characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM),...

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Main Authors: Chang, Josephine Hui Lai, Md Rezaur, Rahman, Sinin, Hamdan
Format: Article
Language:English
Published: UTM Press 2017
Subjects:
Online Access:http://ir.unimas.my/id/eprint/17945/
http://ir.unimas.my/id/eprint/17945/1/Chang%2C%20Josephine%20Hui%20Lai.pdf
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author Chang, Josephine Hui Lai
Md Rezaur, Rahman
Sinin, Hamdan
author_facet Chang, Josephine Hui Lai
Md Rezaur, Rahman
Sinin, Hamdan
author_sort Chang, Josephine Hui Lai
building UNIMAS Institutional Repository
collection Online Access
description Styrene-co-glycidyl methacrylate-fumed silica-clay (ST-co-GMA-fsi-clay) nanocomposites have been prepared via free radical polymerization in the presence of benzoyl peroxide. The nanocomposites are characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), adsorption isotherm, tensile test, thermogravimetric analysis (TGA) and moisture absorption. FT-IR shows the Si-O-C peak that represented ST-co-GMA-fsi bonding while Si-O-Si peak shows the bonding of fsi-clay. The surface morphology shows the well dispersion of clay (1.30E) into ST-co-GMA-fsi nanocomposite. 2wt% of ST-co-GMA-fsi-clay (1.30E) nanocomposite has higher specific surface area and average pore volume with less pore size. Incorporation of 2wt% of clay (1.30E) improves the tensile strength and modulus of the nanocomposites as well as higher thermal stability and activation energy. 2wt% of ST-co-GMA-fsi-clay (1.30E) nanocomposite shows the lowest moisture absorption value. © 2017 Penerbit UTM Press. All rights reserved.
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spelling unimas-179452021-05-24T06:20:30Z http://ir.unimas.my/id/eprint/17945/ Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites Chang, Josephine Hui Lai Md Rezaur, Rahman Sinin, Hamdan TJ Mechanical engineering and machinery Styrene-co-glycidyl methacrylate-fumed silica-clay (ST-co-GMA-fsi-clay) nanocomposites have been prepared via free radical polymerization in the presence of benzoyl peroxide. The nanocomposites are characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), adsorption isotherm, tensile test, thermogravimetric analysis (TGA) and moisture absorption. FT-IR shows the Si-O-C peak that represented ST-co-GMA-fsi bonding while Si-O-Si peak shows the bonding of fsi-clay. The surface morphology shows the well dispersion of clay (1.30E) into ST-co-GMA-fsi nanocomposite. 2wt% of ST-co-GMA-fsi-clay (1.30E) nanocomposite has higher specific surface area and average pore volume with less pore size. Incorporation of 2wt% of clay (1.30E) improves the tensile strength and modulus of the nanocomposites as well as higher thermal stability and activation energy. 2wt% of ST-co-GMA-fsi-clay (1.30E) nanocomposite shows the lowest moisture absorption value. © 2017 Penerbit UTM Press. All rights reserved. UTM Press 2017-07 Article PeerReviewed text en http://ir.unimas.my/id/eprint/17945/1/Chang%2C%20Josephine%20Hui%20Lai.pdf Chang, Josephine Hui Lai and Md Rezaur, Rahman and Sinin, Hamdan (2017) Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites. Jurnal Teknologi, 79 (5). pp. 1-10. ISSN 2180–3722 http://www.jurnalteknologi.utm.my/index.php/jurnalteknologi/article/view/10004/6139 DOI: 10.11113/jt.v79.10004
spellingShingle TJ Mechanical engineering and machinery
Chang, Josephine Hui Lai
Md Rezaur, Rahman
Sinin, Hamdan
Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
title Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
title_full Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
title_fullStr Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
title_full_unstemmed Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
title_short Physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
title_sort physical, mechanical, morphological and thermal analysis of styrene-co-glycidyl methacrylate / fumed silica / clay nanocomposites
topic TJ Mechanical engineering and machinery
url http://ir.unimas.my/id/eprint/17945/
http://ir.unimas.my/id/eprint/17945/
http://ir.unimas.my/id/eprint/17945/
http://ir.unimas.my/id/eprint/17945/1/Chang%2C%20Josephine%20Hui%20Lai.pdf