Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT)
A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UVeVis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data...
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| Format: | Article |
| Language: | English |
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Elsevier
2012
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| Online Access: | http://ir.unimas.my/id/eprint/17596/ http://ir.unimas.my/id/eprint/17596/1/Salam.pdf |
| _version_ | 1848838322789548032 |
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| author | Salam, Md. Abdus Affan, Md. Abu Fasihuddin, Badruddin Ahmad Jusoh, Ismail B Mustaffa, B Shamsuddin, Bohari, M Yamin Yang, Farina |
| author_facet | Salam, Md. Abdus Affan, Md. Abu Fasihuddin, Badruddin Ahmad Jusoh, Ismail B Mustaffa, B Shamsuddin, Bohari, M Yamin Yang, Farina |
| author_sort | Salam, Md. Abdus |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone
(H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UVeVis,
FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data
revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone
ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is
coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S
atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the
carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal
geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space
group I-43d, a ¼ b ¼ c ¼ 30.3273(17) Å, a ¼ b ¼ g ¼ 90�, Z ¼ 16, m(MoKa) ¼ 1.209 mm�1, F(000) ¼ 12,144,
and final R1 ¼ 0.0390, wR2 ¼ 0.0843 for observed reflections 4582(I > 2s(I)). |
| first_indexed | 2025-11-15T06:53:43Z |
| format | Article |
| id | unimas-17596 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:53:43Z |
| publishDate | 2012 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-175962021-07-01T14:39:23Z http://ir.unimas.my/id/eprint/17596/ Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) Salam, Md. Abdus Affan, Md. Abu Fasihuddin, Badruddin Ahmad Jusoh, Ismail B Mustaffa, B Shamsuddin, Bohari, M Yamin Yang, Farina Q Science (General) A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UVeVis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a ¼ b ¼ c ¼ 30.3273(17) Å, a ¼ b ¼ g ¼ 90�, Z ¼ 16, m(MoKa) ¼ 1.209 mm�1, F(000) ¼ 12,144, and final R1 ¼ 0.0390, wR2 ¼ 0.0843 for observed reflections 4582(I > 2s(I)). Elsevier 2012 Article PeerReviewed text en http://ir.unimas.my/id/eprint/17596/1/Salam.pdf Salam, Md. Abdus and Affan, Md. Abu and Fasihuddin, Badruddin Ahmad and Jusoh, Ismail B and Mustaffa, B Shamsuddin, and Bohari, M Yamin and Yang, Farina (2012) Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT). Journal of Organometallic Chemistry, 696 (26). pp. 4202-4206. ISSN 0022-328X http://www.sciencedirect.com/science/article/pii/S0022328X11006024 doi : 10.1016/j.jorganchem.2011.09.013 |
| spellingShingle | Q Science (General) Salam, Md. Abdus Affan, Md. Abu Fasihuddin, Badruddin Ahmad Jusoh, Ismail B Mustaffa, B Shamsuddin, Bohari, M Yamin Yang, Farina Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title | Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_full | Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_fullStr | Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_full_unstemmed | Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_short | Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) |
| title_sort | synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(iv) complex with pyruvic acid-n(4)-cyclohexylthiosemicarbazone (h2pact) |
| topic | Q Science (General) |
| url | http://ir.unimas.my/id/eprint/17596/ http://ir.unimas.my/id/eprint/17596/ http://ir.unimas.my/id/eprint/17596/ http://ir.unimas.my/id/eprint/17596/1/Salam.pdf |