A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition

Chromated copper arsenate (CCA)-treated Malaysian hardwoods have long been used as utility poles, posts, construction piles and motorway fencing in soil contact exposed to the threats of decay fungi and termites. Despite global concerns citing predominantly temperate conditions of long-term leach...

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Main Authors: Wong, Andrew H.H, Chin, Willy S.M.
Format: Article
Language:English
Published: IRGWP 2016
Subjects:
Online Access:http://ir.unimas.my/id/eprint/16020/
http://ir.unimas.my/id/eprint/16020/1/A%20case%20study%20of%20long-term%20CCA%20preservative%20%28abstract%29.pdf
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author Wong, Andrew H.H
Chin, Willy S.M.
author_facet Wong, Andrew H.H
Chin, Willy S.M.
author_sort Wong, Andrew H.H
building UNIMAS Institutional Repository
collection Online Access
description Chromated copper arsenate (CCA)-treated Malaysian hardwoods have long been used as utility poles, posts, construction piles and motorway fencing in soil contact exposed to the threats of decay fungi and termites. Despite global concerns citing predominantly temperate conditions of long-term leaching of CCA toxic heavy metals from wood into surrounding soils and groundwater since the 1990’s, the preservative leaching severity in the tropics has been far less appreciated due to dearth of work in this area. In 2013 (after 30 years exposure), levels of total copper, chromium and arsenic within 20 treated hardwood poles of Sarawak and in soils surrounding these poles, installed in 1980 and 1981 at a plot located in Timber Research and Technical Training Centre, Kuching, Sarawak, Malaysia, were sampled. The ground is waterlogged after heavy rainfall. It is shown that there is insignificant variations of CCA salt retention in wood between 1300 cm above ground and 0-20 cm below ground (P<0.05). Nevertheless levels of these elements are significantly (P<0.05) elevated in soils surrounding, especially up to 25 mm away from, the poles than at distant sampling points (150 – 300 mm) from poles as well as at sites well away from the poles containing very low levels (<6 – 13.4 ppm) of such heavy metals. Metal levels were also highest at the soil surface directly in contact with the poles (0 – 50 mm soil depth position) and decreased with remaining 2 soil depth positions 150 – 200 mm and 300 – 350 mm. Mean extractable arsenic levels ranged from 14.5 to 100.1 ppm, chromium levels from 23.3 to 148.3 ppm and copper from 21.8 to 104.7 ppm. Results, rather than indicating relatively higher CCA leaching, concurred with that reported temperate experience and showed that soil closest to the treated poles are most contaminated, albeit slightly, after 30 years of in-ground exposure.
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spelling unimas-160202017-05-02T04:14:17Z http://ir.unimas.my/id/eprint/16020/ A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition Wong, Andrew H.H Chin, Willy S.M. GE Environmental Sciences Chromated copper arsenate (CCA)-treated Malaysian hardwoods have long been used as utility poles, posts, construction piles and motorway fencing in soil contact exposed to the threats of decay fungi and termites. Despite global concerns citing predominantly temperate conditions of long-term leaching of CCA toxic heavy metals from wood into surrounding soils and groundwater since the 1990’s, the preservative leaching severity in the tropics has been far less appreciated due to dearth of work in this area. In 2013 (after 30 years exposure), levels of total copper, chromium and arsenic within 20 treated hardwood poles of Sarawak and in soils surrounding these poles, installed in 1980 and 1981 at a plot located in Timber Research and Technical Training Centre, Kuching, Sarawak, Malaysia, were sampled. The ground is waterlogged after heavy rainfall. It is shown that there is insignificant variations of CCA salt retention in wood between 1300 cm above ground and 0-20 cm below ground (P<0.05). Nevertheless levels of these elements are significantly (P<0.05) elevated in soils surrounding, especially up to 25 mm away from, the poles than at distant sampling points (150 – 300 mm) from poles as well as at sites well away from the poles containing very low levels (<6 – 13.4 ppm) of such heavy metals. Metal levels were also highest at the soil surface directly in contact with the poles (0 – 50 mm soil depth position) and decreased with remaining 2 soil depth positions 150 – 200 mm and 300 – 350 mm. Mean extractable arsenic levels ranged from 14.5 to 100.1 ppm, chromium levels from 23.3 to 148.3 ppm and copper from 21.8 to 104.7 ppm. Results, rather than indicating relatively higher CCA leaching, concurred with that reported temperate experience and showed that soil closest to the treated poles are most contaminated, albeit slightly, after 30 years of in-ground exposure. IRGWP 2016 Article PeerReviewed text en http://ir.unimas.my/id/eprint/16020/1/A%20case%20study%20of%20long-term%20CCA%20preservative%20%28abstract%29.pdf Wong, Andrew H.H and Chin, Willy S.M. (2016) A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition. International Research Group on Wood Protection. ISSN 2000-8953 https://www.researchgate.net/publication/303497963
spellingShingle GE Environmental Sciences
Wong, Andrew H.H
Chin, Willy S.M.
A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition
title A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition
title_full A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition
title_fullStr A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition
title_full_unstemmed A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition
title_short A case study of long-term CCA preservative leaching from treated hardwood poles in a humid tropical condition
title_sort case study of long-term cca preservative leaching from treated hardwood poles in a humid tropical condition
topic GE Environmental Sciences
url http://ir.unimas.my/id/eprint/16020/
http://ir.unimas.my/id/eprint/16020/
http://ir.unimas.my/id/eprint/16020/1/A%20case%20study%20of%20long-term%20CCA%20preservative%20%28abstract%29.pdf