Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands
Synthesis and spectroscopic characterization of gallium(Ill) complexes with chalcone and Schiff base are reported in this thesis. Tautomerization was happening in chalcone before coordinated with gallium(Ill) bromide. For Schiff base compounds, which OH group located in ortho- or puru- substituti...
| Main Author: | |
|---|---|
| Format: | Final Year Project Report / IMRAD |
| Language: | English |
| Published: |
Universiti Malaysia Sarawak, (UNIMAS)
2004
|
| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/1514/ http://ir.unimas.my/id/eprint/1514/8/2013-03-prChiaufull.pdf |
| _version_ | 1848834776562139136 |
|---|---|
| author | Chiau, Shis Hoong |
| author_facet | Chiau, Shis Hoong |
| author_sort | Chiau, Shis Hoong |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | Synthesis and spectroscopic characterization of gallium(Ill) complexes with chalcone and
Schiff base are reported in this thesis. Tautomerization was happening in chalcone before
coordinated with gallium(Ill) bromide. For Schiff base compounds, which OH group
located in ortho- or puru- substitution, a intramolecular hydrogen bond present between
hydrogen atom from phenolic group with nitrogen atom from C:= N group. Reactions of
chalcone as well as Schiff base with gallium(Ill) bromide gave a new respective
coordination mode of Ga-O bonds. The ligands appear to act as monodentate species in
Ga(III) complexes, making gallium atom four-coordinated in tetrahedron structure. The
ratio between Ga : ligand is 1: 1 for all the Ga(III) complexes in this research. |
| first_indexed | 2025-11-15T05:57:21Z |
| format | Final Year Project Report / IMRAD |
| id | unimas-1514 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T05:57:21Z |
| publishDate | 2004 |
| publisher | Universiti Malaysia Sarawak, (UNIMAS) |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-15142023-02-14T07:49:53Z http://ir.unimas.my/id/eprint/1514/ Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands Chiau, Shis Hoong QD Chemistry Synthesis and spectroscopic characterization of gallium(Ill) complexes with chalcone and Schiff base are reported in this thesis. Tautomerization was happening in chalcone before coordinated with gallium(Ill) bromide. For Schiff base compounds, which OH group located in ortho- or puru- substitution, a intramolecular hydrogen bond present between hydrogen atom from phenolic group with nitrogen atom from C:= N group. Reactions of chalcone as well as Schiff base with gallium(Ill) bromide gave a new respective coordination mode of Ga-O bonds. The ligands appear to act as monodentate species in Ga(III) complexes, making gallium atom four-coordinated in tetrahedron structure. The ratio between Ga : ligand is 1: 1 for all the Ga(III) complexes in this research. Universiti Malaysia Sarawak, (UNIMAS) 2004 Final Year Project Report / IMRAD NonPeerReviewed text en http://ir.unimas.my/id/eprint/1514/8/2013-03-prChiaufull.pdf Chiau, Shis Hoong (2004) Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands. [Final Year Project Report / IMRAD] (Unpublished) |
| spellingShingle | QD Chemistry Chiau, Shis Hoong Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands |
| title | Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands |
| title_full | Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands |
| title_fullStr | Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands |
| title_full_unstemmed | Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands |
| title_short | Synthesis and characterization og gallium (III) complexes with chalcone and schiff base ligands |
| title_sort | synthesis and characterization og gallium (iii) complexes with chalcone and schiff base ligands |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/1514/ http://ir.unimas.my/id/eprint/1514/8/2013-03-prChiaufull.pdf |