2-Amino-4,6-dimethylpyridinium benzoate
In the title compound, C7H11N2 +·C7H5O2 −, the 2-amino-4,6-dimethylpyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R 2 2(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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IUCR
2010
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| Online Access: | http://ir.unimas.my/id/eprint/14382/ http://ir.unimas.my/id/eprint/14382/1/2-Amino-4%2C6-dimethylpyridinium%20benzoate%20%28abstract%29.pdf |
| _version_ | 1848837636127457280 |
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| author | Mohd Razip, Asaruddin Habibah, A Wahab Nornisah, Mohamed Fun, Hoong-Kun |
| author_facet | Mohd Razip, Asaruddin Habibah, A Wahab Nornisah, Mohamed Fun, Hoong-Kun |
| author_sort | Mohd Razip, Asaruddin |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | In the title compound, C7H11N2 +·C7H5O2 −, the 2-amino-4,6-dimethylpyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R 2 2(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the molecules are stabilized by intermolecular N—H⋯O hydrogen bonds. A π–π interaction, with a centroid–centroid distance of 3.661 (2) Å, is also observed. |
| first_indexed | 2025-11-15T06:42:48Z |
| format | Article |
| id | unimas-14382 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:42:48Z |
| publishDate | 2010 |
| publisher | IUCR |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-143822016-11-22T02:36:25Z http://ir.unimas.my/id/eprint/14382/ 2-Amino-4,6-dimethylpyridinium benzoate Mohd Razip, Asaruddin Habibah, A Wahab Nornisah, Mohamed Fun, Hoong-Kun QD Chemistry In the title compound, C7H11N2 +·C7H5O2 −, the 2-amino-4,6-dimethylpyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R 2 2(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the molecules are stabilized by intermolecular N—H⋯O hydrogen bonds. A π–π interaction, with a centroid–centroid distance of 3.661 (2) Å, is also observed. IUCR 2010 Article PeerReviewed text en http://ir.unimas.my/id/eprint/14382/1/2-Amino-4%2C6-dimethylpyridinium%20benzoate%20%28abstract%29.pdf Mohd Razip, Asaruddin and Habibah, A Wahab and Nornisah, Mohamed and Fun, Hoong-Kun (2010) 2-Amino-4,6-dimethylpyridinium benzoate. Acta Crystallographica Section E Structure Reports Online, 66 (10). ISSN 1600-5368 https://www.researchgate.net/publication/51141688_2-Amino-46-dimethylpyridinium_benzoate DOI: 10.1107/S1600536810034811 |
| spellingShingle | QD Chemistry Mohd Razip, Asaruddin Habibah, A Wahab Nornisah, Mohamed Fun, Hoong-Kun 2-Amino-4,6-dimethylpyridinium benzoate |
| title | 2-Amino-4,6-dimethylpyridinium benzoate |
| title_full | 2-Amino-4,6-dimethylpyridinium benzoate |
| title_fullStr | 2-Amino-4,6-dimethylpyridinium benzoate |
| title_full_unstemmed | 2-Amino-4,6-dimethylpyridinium benzoate |
| title_short | 2-Amino-4,6-dimethylpyridinium benzoate |
| title_sort | 2-amino-4,6-dimethylpyridinium benzoate |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/14382/ http://ir.unimas.my/id/eprint/14382/ http://ir.unimas.my/id/eprint/14382/ http://ir.unimas.my/id/eprint/14382/1/2-Amino-4%2C6-dimethylpyridinium%20benzoate%20%28abstract%29.pdf |