3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea
In the title thiourea derivative, C16H17N3OS, the hydroxy-and methyl-substituted benzene rings form dihedral angles of 9.62 (12) and 55.69 (6)degrees, respectively, with the central CN3S chromophore (r.m.s. deviation = 0.0117 angstrom). An intramolecular O-H center dot center dot center dot N hydrog...
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| Format: | Article |
| Language: | English |
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IUCR
2011
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| Online Access: | http://ir.unimas.my/id/eprint/14381/ http://ir.unimas.my/id/eprint/14381/1/3-%7B%28E%29-%5B1-%282-Hydroxyphenyl%29ethylidene%5D-amino%7D-1-%282-methylphenyl%29thiourea%20%28abstract%29.pdf |
| _version_ | 1848837635842244608 |
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| author | Abdus, Salam Md. Abu, Affan Mohd Razip, Asaruddin Tiekink, Edward |
| author_facet | Abdus, Salam Md. Abu, Affan Mohd Razip, Asaruddin Tiekink, Edward |
| author_sort | Abdus, Salam |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | In the title thiourea derivative, C16H17N3OS, the hydroxy-and methyl-substituted benzene rings form dihedral angles of 9.62 (12) and 55.69 (6)degrees, respectively, with the central CN3S chromophore (r.m.s. deviation = 0.0117 angstrom). An intramolecular O-H center dot center dot center dot N hydrogen bond ensures the coplanarity of the central atoms. The H atoms of the NH groups are syn and the conformation about the N = C double bond [1.295 (4) angstrom] is E. In the crystal, helical supramolecular chains sustained primarily by N-H center dot center dot center dot S hydrogen bonds are found. Additional stabilization is provided by C-H center dot center dot center dot pi and pi-pi [ring centroid(hydroxybenzene)center dot center dot center dot ring centroid(methylbenzene) = 3.8524 (18) angstrom] interactions. |
| first_indexed | 2025-11-15T06:42:48Z |
| format | Article |
| id | unimas-14381 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:42:48Z |
| publishDate | 2011 |
| publisher | IUCR |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-143812016-11-22T02:31:45Z http://ir.unimas.my/id/eprint/14381/ 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea Abdus, Salam Md. Abu, Affan Mohd Razip, Asaruddin Tiekink, Edward QD Chemistry In the title thiourea derivative, C16H17N3OS, the hydroxy-and methyl-substituted benzene rings form dihedral angles of 9.62 (12) and 55.69 (6)degrees, respectively, with the central CN3S chromophore (r.m.s. deviation = 0.0117 angstrom). An intramolecular O-H center dot center dot center dot N hydrogen bond ensures the coplanarity of the central atoms. The H atoms of the NH groups are syn and the conformation about the N = C double bond [1.295 (4) angstrom] is E. In the crystal, helical supramolecular chains sustained primarily by N-H center dot center dot center dot S hydrogen bonds are found. Additional stabilization is provided by C-H center dot center dot center dot pi and pi-pi [ring centroid(hydroxybenzene)center dot center dot center dot ring centroid(methylbenzene) = 3.8524 (18) angstrom] interactions. IUCR 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/14381/1/3-%7B%28E%29-%5B1-%282-Hydroxyphenyl%29ethylidene%5D-amino%7D-1-%282-methylphenyl%29thiourea%20%28abstract%29.pdf Abdus, Salam and Md. Abu, Affan and Mohd Razip, Asaruddin and Tiekink, Edward (2011) 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea. Acta Crystallographica Section E Structure Reports Online, 67 (5). ISSN 1600-5368 https://www.researchgate.net/publication/216577206_3-E-1-2-Hydroxyphenylethylidene-amino-1-2-methylphenylthiourea?origin=publication_list DOI: 10.1107/S1600536811013729 |
| spellingShingle | QD Chemistry Abdus, Salam Md. Abu, Affan Mohd Razip, Asaruddin Tiekink, Edward 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| title | 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| title_full | 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| title_fullStr | 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| title_full_unstemmed | 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| title_short | 3-{(E)-[1-(2-Hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| title_sort | 3-{(e)-[1-(2-hydroxyphenyl)ethylidene]-amino}-1-(2-methylphenyl)thiourea |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/14381/ http://ir.unimas.my/id/eprint/14381/ http://ir.unimas.my/id/eprint/14381/ http://ir.unimas.my/id/eprint/14381/1/3-%7B%28E%29-%5B1-%282-Hydroxyphenyl%29ethylidene%5D-amino%7D-1-%282-methylphenyl%29thiourea%20%28abstract%29.pdf |