n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV)
Two independent mol-ecules comprise the asymmetric unit in the title compound, [Sn(C₄H₉)(C₁₄H₁₉N₄S)Cl₂]. In each mol-ecule, the Sn(IV) atom exists within a distorted octa-hedral geometry defined by the N,N',S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the...
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| Format: | Article |
| Language: | English |
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IUCR
2012
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| Online Access: | http://ir.unimas.my/id/eprint/14380/ http://ir.unimas.my/id/eprint/14380/1/n-Butyldichlorido%7B4-cyclohexyl-1%20%28abstract%29.pdf |
| _version_ | 1848837635595829248 |
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| author | Md. Abu, Affan Abdus, Salam Mohd Razip, Asaruddin Tiekink, Edward |
| author_facet | Md. Abu, Affan Abdus, Salam Mohd Razip, Asaruddin Tiekink, Edward |
| author_sort | Md. Abu, Affan |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | Two independent mol-ecules comprise the asymmetric unit in the title compound, [Sn(C₄H₉)(C₁₄H₁₉N₄S)Cl₂]. In each mol-ecule, the Sn(IV) atom exists within a distorted octa-hedral geometry defined by the N,N',S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, mol-ecules are consolidated into a three-dimensional architecture by a combination of N-H⋯Cl, C-H⋯π and π-π inter-actions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å]. |
| first_indexed | 2025-11-15T06:42:48Z |
| format | Article |
| id | unimas-14380 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:42:48Z |
| publishDate | 2012 |
| publisher | IUCR |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-143802016-11-22T02:26:32Z http://ir.unimas.my/id/eprint/14380/ n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) Md. Abu, Affan Abdus, Salam Mohd Razip, Asaruddin Tiekink, Edward QD Chemistry Two independent mol-ecules comprise the asymmetric unit in the title compound, [Sn(C₄H₉)(C₁₄H₁₉N₄S)Cl₂]. In each mol-ecule, the Sn(IV) atom exists within a distorted octa-hedral geometry defined by the N,N',S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, mol-ecules are consolidated into a three-dimensional architecture by a combination of N-H⋯Cl, C-H⋯π and π-π inter-actions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å]. IUCR 2012 Article PeerReviewed text en http://ir.unimas.my/id/eprint/14380/1/n-Butyldichlorido%7B4-cyclohexyl-1%20%28abstract%29.pdf Md. Abu, Affan and Abdus, Salam and Mohd Razip, Asaruddin and Tiekink, Edward (2012) n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV). Acta Crystallographica Section E Structure Reports Online, 67 (7). pp. 909-910. ISSN 1600-5368 https://www.researchgate.net/publication/229161810_n-Butyldichlorido4-cyclo-hexyl-1-1-pyridin-2-yl-kNethyl-idenethio-semi-carb-azi-dato-kNStinIV DOI: 10.1107/S1600536812025937 |
| spellingShingle | QD Chemistry Md. Abu, Affan Abdus, Salam Mohd Razip, Asaruddin Tiekink, Edward n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) |
| title | n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) |
| title_full | n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) |
| title_fullStr | n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) |
| title_full_unstemmed | n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) |
| title_short | n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV) |
| title_sort | n-butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jn)ethylidene]thiosemicarbazidato-j2n1,s}tin(iv) |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/14380/ http://ir.unimas.my/id/eprint/14380/ http://ir.unimas.my/id/eprint/14380/ http://ir.unimas.my/id/eprint/14380/1/n-Butyldichlorido%7B4-cyclohexyl-1%20%28abstract%29.pdf |