The potential of agricultural biomass for adsorption of humic substances from tropical black water

The presence of humic substances in water affects the water quality as well as its treatability. They are removed using the conventional coagulation approach in the water treatment system. Adsorption using alternative adsorbents from agricultural wastes has received increasing attention due to their...

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Main Author: Mohd Irwan Lu, Nurul Aida Lu
Format: Thesis
Language:English
Published: Universiti Malaysia Sarawak (UNIMAS) 2015
Subjects:
Online Access:http://ir.unimas.my/id/eprint/10937/
http://ir.unimas.my/id/eprint/10937/4/Nurul%20Aida%20Lu.pdf
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author Mohd Irwan Lu, Nurul Aida Lu
author_facet Mohd Irwan Lu, Nurul Aida Lu
author_sort Mohd Irwan Lu, Nurul Aida Lu
building UNIMAS Institutional Repository
collection Online Access
description The presence of humic substances in water affects the water quality as well as its treatability. They are removed using the conventional coagulation approach in the water treatment system. Adsorption using alternative adsorbents from agricultural wastes has received increasing attention due to their advantages of low cost, abundant availability and environmental friendly. To the best of our understanding, application of biosorbent for removal of humic substances from water remains scarce. Hence, in this study, we investigated the adsorption potential of various indigenous agriculture biomasses for removal of humic substances from peat swamp runoff. The adsorption isotherms were further evaluated using the standard humic acid. The adsorption potential of untreated biomass was less promising (< 45 %). With citric acid pretreatment, the adsorption capacity was significantly improved especially for groundnut shell, rice husk and sugarcane bagasse where the percentage removal attained were 63.81%, 58.70% and 57.48%, respectively. It was observed that various biomasses experienced delignification, dissolution and eventually chemical functionalization to different extents upon treatment. The isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich and Temkin) showed that after treatment, the adsorption capacities was increased up to 4.99 mg/g, 3.93 mg/g and 18.98 mg/g for modified groundnut shell, rice husk and sugarcane bagasse, respectively.
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institution Universiti Malaysia Sarawak
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spelling unimas-109372025-07-01T06:27:03Z http://ir.unimas.my/id/eprint/10937/ The potential of agricultural biomass for adsorption of humic substances from tropical black water Mohd Irwan Lu, Nurul Aida Lu GE Environmental Sciences S Agriculture (General) The presence of humic substances in water affects the water quality as well as its treatability. They are removed using the conventional coagulation approach in the water treatment system. Adsorption using alternative adsorbents from agricultural wastes has received increasing attention due to their advantages of low cost, abundant availability and environmental friendly. To the best of our understanding, application of biosorbent for removal of humic substances from water remains scarce. Hence, in this study, we investigated the adsorption potential of various indigenous agriculture biomasses for removal of humic substances from peat swamp runoff. The adsorption isotherms were further evaluated using the standard humic acid. The adsorption potential of untreated biomass was less promising (< 45 %). With citric acid pretreatment, the adsorption capacity was significantly improved especially for groundnut shell, rice husk and sugarcane bagasse where the percentage removal attained were 63.81%, 58.70% and 57.48%, respectively. It was observed that various biomasses experienced delignification, dissolution and eventually chemical functionalization to different extents upon treatment. The isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich and Temkin) showed that after treatment, the adsorption capacities was increased up to 4.99 mg/g, 3.93 mg/g and 18.98 mg/g for modified groundnut shell, rice husk and sugarcane bagasse, respectively. Universiti Malaysia Sarawak (UNIMAS) 2015 Thesis NonPeerReviewed text en http://ir.unimas.my/id/eprint/10937/4/Nurul%20Aida%20Lu.pdf Mohd Irwan Lu, Nurul Aida Lu (2015) The potential of agricultural biomass for adsorption of humic substances from tropical black water. Masters thesis, Universiti Malaysia Sarawak, (UNIMAS).
spellingShingle GE Environmental Sciences
S Agriculture (General)
Mohd Irwan Lu, Nurul Aida Lu
The potential of agricultural biomass for adsorption of humic substances from tropical black water
title The potential of agricultural biomass for adsorption of humic substances from tropical black water
title_full The potential of agricultural biomass for adsorption of humic substances from tropical black water
title_fullStr The potential of agricultural biomass for adsorption of humic substances from tropical black water
title_full_unstemmed The potential of agricultural biomass for adsorption of humic substances from tropical black water
title_short The potential of agricultural biomass for adsorption of humic substances from tropical black water
title_sort potential of agricultural biomass for adsorption of humic substances from tropical black water
topic GE Environmental Sciences
S Agriculture (General)
url http://ir.unimas.my/id/eprint/10937/
http://ir.unimas.my/id/eprint/10937/4/Nurul%20Aida%20Lu.pdf