The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution

Palm oil processing waste which is palm oil kernel shell (POKS) was converted to activated carbon (POKS AC) through 7 min microwave pyrolysis at temperature 270 °C followed by chemical activation using NaOH and HCl. The adsorption study on Ni(II), Cu(II) and Cr(IV) was conducted to evaluate the eff...

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Main Authors: Wahi, Rafeah, Senghie, Herman
Format: Article
Language:English
Published: Penerbit UTHM 2011
Subjects:
Online Access:http://ir.unimas.my/id/eprint/10870/
http://ir.unimas.my/id/eprint/10870/7/The%20Use%20of%20Microwave%20Derived%20Activated%20Carbon%20%28abstract%29.pdf
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author Wahi, Rafeah
Senghie, Herman
author_facet Wahi, Rafeah
Senghie, Herman
author_sort Wahi, Rafeah
building UNIMAS Institutional Repository
collection Online Access
description Palm oil processing waste which is palm oil kernel shell (POKS) was converted to activated carbon (POKS AC) through 7 min microwave pyrolysis at temperature 270 °C followed by chemical activation using NaOH and HCl. The adsorption study on Ni(II), Cu(II) and Cr(IV) was conducted to evaluate the efficiency of the prepared activated carbon to remove heavy metal. The adsorption capacity was determined as a function of adsorbate initial concentration and adsorbent dosage. Based on Langmuir isotherm, Ni(II) showed highest adsorption capacity of 40.98 mg/g, followed by Cr(IV) and Cu(II) with adsorption capacity of 40.60 mg/g and 13.69 mg/g, respectively. Cr(IV) and Cu(II) showed better fitting to Freundlich isotherm model with high correlation regression indicating the applicability of heterogeneous adsorption. Ni(II) show better fitting with Langmuir isotherm that indicate monolayer coverage. The use of POKS AC is not only effective for adsorption of Cr(IV), Ni(II) and Cu(II) in aqueous solution but also helps to overcome the over abundance of POKS waste problem.
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spelling unimas-108702016-03-14T02:29:28Z http://ir.unimas.my/id/eprint/10870/ The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution Wahi, Rafeah Senghie, Herman QD Chemistry Palm oil processing waste which is palm oil kernel shell (POKS) was converted to activated carbon (POKS AC) through 7 min microwave pyrolysis at temperature 270 °C followed by chemical activation using NaOH and HCl. The adsorption study on Ni(II), Cu(II) and Cr(IV) was conducted to evaluate the efficiency of the prepared activated carbon to remove heavy metal. The adsorption capacity was determined as a function of adsorbate initial concentration and adsorbent dosage. Based on Langmuir isotherm, Ni(II) showed highest adsorption capacity of 40.98 mg/g, followed by Cr(IV) and Cu(II) with adsorption capacity of 40.60 mg/g and 13.69 mg/g, respectively. Cr(IV) and Cu(II) showed better fitting to Freundlich isotherm model with high correlation regression indicating the applicability of heterogeneous adsorption. Ni(II) show better fitting with Langmuir isotherm that indicate monolayer coverage. The use of POKS AC is not only effective for adsorption of Cr(IV), Ni(II) and Cu(II) in aqueous solution but also helps to overcome the over abundance of POKS waste problem. Penerbit UTHM 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/10870/7/The%20Use%20of%20Microwave%20Derived%20Activated%20Carbon%20%28abstract%29.pdf Wahi, Rafeah and Senghie, Herman (2011) The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution. Journal of Science and Technology, 3 (1). pp. 97-108. ISSN 2229-8460 https://scholar.google.de/citations?view_op=view_citation&hl=de&user=XDQF0e4AAAAJ&citation_for_view=XDQF0e4AAAAJ:d1gkVwhDpl0C
spellingShingle QD Chemistry
Wahi, Rafeah
Senghie, Herman
The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
title The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
title_full The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
title_fullStr The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
title_full_unstemmed The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
title_short The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
title_sort use of microwave derived activated carbon for removal of heavy metal in aqueous solution
topic QD Chemistry
url http://ir.unimas.my/id/eprint/10870/
http://ir.unimas.my/id/eprint/10870/
http://ir.unimas.my/id/eprint/10870/7/The%20Use%20of%20Microwave%20Derived%20Activated%20Carbon%20%28abstract%29.pdf