Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device

The spacer effect caused by the system of molecules during the process of E/Z isomerization is reported. The phenomenon was predicted by absorption measurements with UV light of 365nm wavelength was illuminated to the solution of azobenzene dimers with aliphatic and aromatic spacers were incorporate...

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Main Authors: Yuvaraj, A. R., Tay, Joo Hui, Siti Maznah, Kabeb, Lutfor, M. R., M. M., Yusoff, Hegde, Gurumurthy
Format: Conference or Workshop Item
Language:English
English
Published: 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8793/
http://umpir.ump.edu.my/id/eprint/8793/1/Spacer%20Effect%20Caused%20by%20Azobenzene%20System%20in%20E%2C%20Z%20Isomerization-%20An%20Application%20for%20Optical%20Storage%20Device.pdf
http://umpir.ump.edu.my/id/eprint/8793/7/fist-2015-yuvaraj-Spacer%20effect%20caused.pdf
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author Yuvaraj, A. R.
Tay, Joo Hui
Siti Maznah, Kabeb
Lutfor, M. R.
M. M., Yusoff
Hegde, Gurumurthy
author_facet Yuvaraj, A. R.
Tay, Joo Hui
Siti Maznah, Kabeb
Lutfor, M. R.
M. M., Yusoff
Hegde, Gurumurthy
author_sort Yuvaraj, A. R.
building UMP Institutional Repository
collection Online Access
description The spacer effect caused by the system of molecules during the process of E/Z isomerization is reported. The phenomenon was predicted by absorption measurements with UV light of 365nm wavelength was illuminated to the solution of azobenzene dimers with aliphatic and aromatic spacers were incorporated. The photosaturation was observed within 18 seconds for both compounds. But, the dramatic variation in thermal back relaxation is the significant interest in this study. That is Z-E isomerization or thermal back relaxation was occurred around 7-13hours. Here the variation in back relaxation is directly related to the nature of spaced associated with the molecular structure. In particular, the spacer effect is very much important in synthesizing the materials for the optical storage device fabrication.
first_indexed 2025-11-15T01:36:00Z
format Conference or Workshop Item
id ump-8793
institution Universiti Malaysia Pahang
institution_category Local University
language English
English
last_indexed 2025-11-15T01:36:00Z
publishDate 2015
recordtype eprints
repository_type Digital Repository
spelling ump-87932018-01-22T00:50:53Z http://umpir.ump.edu.my/id/eprint/8793/ Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device Yuvaraj, A. R. Tay, Joo Hui Siti Maznah, Kabeb Lutfor, M. R. M. M., Yusoff Hegde, Gurumurthy Q Science (General) The spacer effect caused by the system of molecules during the process of E/Z isomerization is reported. The phenomenon was predicted by absorption measurements with UV light of 365nm wavelength was illuminated to the solution of azobenzene dimers with aliphatic and aromatic spacers were incorporated. The photosaturation was observed within 18 seconds for both compounds. But, the dramatic variation in thermal back relaxation is the significant interest in this study. That is Z-E isomerization or thermal back relaxation was occurred around 7-13hours. Here the variation in back relaxation is directly related to the nature of spaced associated with the molecular structure. In particular, the spacer effect is very much important in synthesizing the materials for the optical storage device fabrication. 2015 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8793/1/Spacer%20Effect%20Caused%20by%20Azobenzene%20System%20in%20E%2C%20Z%20Isomerization-%20An%20Application%20for%20Optical%20Storage%20Device.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/8793/7/fist-2015-yuvaraj-Spacer%20effect%20caused.pdf Yuvaraj, A. R. and Tay, Joo Hui and Siti Maznah, Kabeb and Lutfor, M. R. and M. M., Yusoff and Hegde, Gurumurthy (2015) Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device. In: National Conference for Postgraduate Research (NCON-PGR 2015) , 24-25 January 2015 , Universiti Malaysia Pahang (UMP). pp. 1-5.. (Published) http://www.researchgate.net/publication/272136015_Spacer_effect_caused_by_azobenzene_system_in_EZ_isomerization_An_application_for_optical_storage_device
spellingShingle Q Science (General)
Yuvaraj, A. R.
Tay, Joo Hui
Siti Maznah, Kabeb
Lutfor, M. R.
M. M., Yusoff
Hegde, Gurumurthy
Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device
title Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device
title_full Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device
title_fullStr Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device
title_full_unstemmed Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device
title_short Spacer Effect Caused by Azobenzene System in E/Z Isomerization: An Application for Optical Storage Device
title_sort spacer effect caused by azobenzene system in e/z isomerization: an application for optical storage device
topic Q Science (General)
url http://umpir.ump.edu.my/id/eprint/8793/
http://umpir.ump.edu.my/id/eprint/8793/
http://umpir.ump.edu.my/id/eprint/8793/1/Spacer%20Effect%20Caused%20by%20Azobenzene%20System%20in%20E%2C%20Z%20Isomerization-%20An%20Application%20for%20Optical%20Storage%20Device.pdf
http://umpir.ump.edu.my/id/eprint/8793/7/fist-2015-yuvaraj-Spacer%20effect%20caused.pdf