Preparation of Mesoporous Silica-Supported Chiral Amino Alcohols for the Enantioselective Addition of Diethylzinc to Aldehyde and Asymmetric Transfer Hydrogenation to Ketones
Optically active (−)-ephedrine, (−)-norephedrine, and (−)-prolinol were immobilized onto cubicmesoporousMCM-48 silica. The immobilized amino alcohols served as a heterogeneous chiral catalyst for the asymmetric addition of diethylzinc to aldehydes and transfer hydrogenation to ketones. The developed...
| Main Authors: | Sarkar, Shaheen M., Md. Eaqub, Ali, Lutfor, M. R., M. M., Yusoff |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Hindawi Publishing Corporation
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/8176/ http://umpir.ump.edu.my/id/eprint/8176/1/Sha_JNM-3.pdf |
Similar Items
Asymmetric Transfer Hydrogenation Catalyzed by Mesoporous MCM-41-Supported Chiral Ru-Complex
by: Sarkar, Shaheen M., et al.
Published: (2014)
by: Sarkar, Shaheen M., et al.
Published: (2014)
Preparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefins
by: Sarkar, Shaheen M., et al.
Published: (2014)
by: Sarkar, Shaheen M., et al.
Published: (2014)
Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
by: Sarkar, Shaheen M., et al.
Published: (2015)
by: Sarkar, Shaheen M., et al.
Published: (2015)
Enantioselective binding of additives to chiral crystals
by: Carter, D., et al.
Published: (2012)
by: Carter, D., et al.
Published: (2012)
Mesoporous Silica MCM-41 Supported N-Heterocyclic Carbene-Pd Complex for Heck and Sonogashira Coupling Reactions
by: Sarkar, Shaheen M., et al.
Published: (2015)
by: Sarkar, Shaheen M., et al.
Published: (2015)
Nanoengineering of amino - functionalized mesoporous silica nanospheres as nanoreactors
by: Gao, J., et al.
Published: (2018)
by: Gao, J., et al.
Published: (2018)
Lipase catalyzed enantioselective esterification reaction to produce chiral products
by: Basri, Mahiran, et al.
Published: (1999)
by: Basri, Mahiran, et al.
Published: (1999)
Chiral separation by enantioselective inclusion complexation-organic solvent nanofiltration
by: Ghazali, Nazlee Faisal, et al.
Published: (2006)
by: Ghazali, Nazlee Faisal, et al.
Published: (2006)
Synthesis and Application of Distally-Bridged Chiral Resorcinarenes as Enantioselective Membrane Carriers
by: Tan , Daniel Aquila
Published: (2018)
by: Tan , Daniel Aquila
Published: (2018)
An iridium–SPO complex as bifunctional catalyst for the highly selective hydrogenation of aldehydes
by: Cano, Israel, et al.
Published: (2018)
by: Cano, Israel, et al.
Published: (2018)
Ionic Liquid-Supported (ILS) (S)-Pyrrolidine Sulfonamide for Asymmetric Michael addition reactions of Aldehydes with Nitroolefins.
by: Abdul Rahman, Mohd Basyaruddin, et al.
Published: (2011)
by: Abdul Rahman, Mohd Basyaruddin, et al.
Published: (2011)
Enantioselective synthesis of chiral cyclopent-2-enones by nickel-catalyzed desymmetrization of malonate esters
by: Karad, Somnath Narayan, et al.
Published: (2018)
by: Karad, Somnath Narayan, et al.
Published: (2018)
Robert Boyle's Chiral Crystal Chemistry: Computational Re-evaluation of Enantioselective Adsorption on Quartz
by: Rohl, Andrew, et al.
Published: (2006)
by: Rohl, Andrew, et al.
Published: (2006)
High surface area mesoporous silica for hydrogen sulfide effective removal
by: Ali, Gomaa A. M., et al.
Published: (2018)
by: Ali, Gomaa A. M., et al.
Published: (2018)
Computational analysis of the enantioselectivity of diels-alder reactions involving chiral cationic oxazaborolidinium catalyst / Nasr Y.M. Omar
by: Nasr, Y. M. O.
Published: (2011)
by: Nasr, Y. M. O.
Published: (2011)
Chiral Mesoporous Organosilicas with R-(+)-Binol Integrated in the Framework
by: Wang, P., et al.
Published: (2009)
by: Wang, P., et al.
Published: (2009)
Functionalized Periodic Mesoporous Organosilicas: Hierarchical and Chiral Materials
by: Yang, Q., et al.
Published: (2010)
by: Yang, Q., et al.
Published: (2010)
Enantioselective synthesis of 6,6-disubstituted pentafulvenes containing a chiral pendant hydroxy group
by: Nouch, Ryan, et al.
Published: (2017)
by: Nouch, Ryan, et al.
Published: (2017)
Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells
by: Zhang, Jin, et al.
Published: (2016)
by: Zhang, Jin, et al.
Published: (2016)
Tartardiamide-functionalized Chiral Organosilicas with Highly Ordered Mesoporous Structure
by: Zhang, Lei, et al.
Published: (2008)
by: Zhang, Lei, et al.
Published: (2008)
Silica coated ionic liquid templated mesoporous silica nanoparticles
by: Isa, E. D. M., et al.
Published: (2017)
by: Isa, E. D. M., et al.
Published: (2017)
Asymmetric addition reactions using chiral diamine derived catalysts
by: Davison, Christopher
Published: (2015)
by: Davison, Christopher
Published: (2015)
Kinetic study of asymmetric synthesis of chiral amine with immobilized transaminase
by: S. D., Vijaya Kumar, et al.
Published: (2019)
by: S. D., Vijaya Kumar, et al.
Published: (2019)
A Scalable Synthesis of Chiral Himbert Diene Ligands for Asymmetric Catalysis
by: LI, Hongyi
Published: (2024)
by: LI, Hongyi
Published: (2024)
Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membranes for elevated temperature proton exchange membrane fuel cells
by: Zhang, Jin, et al.
Published: (2016)
by: Zhang, Jin, et al.
Published: (2016)
Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells
by: Zhang, J., et al.
Published: (2017)
by: Zhang, J., et al.
Published: (2017)
Asymmetric transition metal-catalyzed alkyl addition to imines with chiral phosphine ligands
by: El Hajjaji, Samir
Published: (2010)
by: El Hajjaji, Samir
Published: (2010)
Chirally Functionalized Hollow Nanospheres Containing l-Prolinamide: Synthesis and Asymmetric Catalysis
by: Gao, J., et al.
Published: (2010)
by: Gao, J., et al.
Published: (2010)
Adsorption and release of biocides with mesoporous silica nanoparticles
by: Popat, A., et al.
Published: (2012)
by: Popat, A., et al.
Published: (2012)
Possible origin of electronic effects in Rh(I)-catalyzed enantioselective hydrogenation
by: Wu, Hai-Chen, et al.
Published: (2009)
by: Wu, Hai-Chen, et al.
Published: (2009)
Nanosized mesoporous silicas for drug delivery
by: Li, Ka, et al.
Published: (2009)
by: Li, Ka, et al.
Published: (2009)
Enantioselective Inhibition of Human Papillomavirus L1 Pentamer Formation by Chiral-Proline Modified Calix[4]arenes: Targeting the Protein Interface
by: Fu, D., et al.
Published: (2016)
by: Fu, D., et al.
Published: (2016)
Asymmetric rhodium catalysed additions to activated imines : new approaches to α-chiral amines
by: Crampton, Rosemary Helen
Published: (2012)
by: Crampton, Rosemary Helen
Published: (2012)
Planar Chiral Ferrocene Lithium Amide Bases: A New Generation of Bases for Asymmetric Synthesis
by: Arnall-Culliford, Jennifer
Published: (2002)
by: Arnall-Culliford, Jennifer
Published: (2002)
Dependence of mesoporous silica properties on its template
by: Mohamed Isa, Eleen Dayana, et al.
Published: (2019)
by: Mohamed Isa, Eleen Dayana, et al.
Published: (2019)
A polyisoprenylated ketone from Calophyllum enervosum
by: Bakhtiar, M. Taher, et al.
Published: (2005)
by: Bakhtiar, M. Taher, et al.
Published: (2005)
Synthesis and physico-chemical properties of new tetraethylammonium-based amino acid chiral ionic liquids
by: Abdul Rahman, Mohd Basyaruddin, et al.
Published: (2010)
by: Abdul Rahman, Mohd Basyaruddin, et al.
Published: (2010)
Enantioselective immobilized lipase
by: Basri, Mahiran, et al.
Published: (2008)
by: Basri, Mahiran, et al.
Published: (2008)
Cellulose Supported Poly(amidoxime) Copper Complex for Click Reaction
by: Sarkar, Shaheen M., et al.
Published: (2017)
by: Sarkar, Shaheen M., et al.
Published: (2017)
Development of proline-based chiral ionic liquid organocatalyst for asymmetric Michael reaction under microwave irradiation
by: Omar, Emmy Maryati
Published: (2013)
by: Omar, Emmy Maryati
Published: (2013)
Similar Items
-
Asymmetric Transfer Hydrogenation Catalyzed by Mesoporous MCM-41-Supported Chiral Ru-Complex
by: Sarkar, Shaheen M., et al.
Published: (2014) -
Preparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefins
by: Sarkar, Shaheen M., et al.
Published: (2014) -
Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
by: Sarkar, Shaheen M., et al.
Published: (2015) -
Enantioselective binding of additives to chiral crystals
by: Carter, D., et al.
Published: (2012) -
Mesoporous Silica MCM-41 Supported N-Heterocyclic Carbene-Pd Complex for Heck and Sonogashira Coupling Reactions
by: Sarkar, Shaheen M., et al.
Published: (2015)