Thermodynamic Study of Propane Dehydrogenation Into Propylene

Propane dehydrogenation is a one of a promising route for producing propylene by using thermodynamic analysis to replace traditional cracking methods. The purpose of this study is to product distribution as a function over temperature, to identifying the region of the carbon deposition and to analys...

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Main Author: Qurratuaini, Hassanusi
Format: Undergraduates Project Papers
Language:English
Published: 2013
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/7208/
http://umpir.ump.edu.my/id/eprint/7208/1/CD7100.pdf
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author Qurratuaini, Hassanusi
author_facet Qurratuaini, Hassanusi
author_sort Qurratuaini, Hassanusi
building UMP Institutional Repository
collection Online Access
description Propane dehydrogenation is a one of a promising route for producing propylene by using thermodynamic analysis to replace traditional cracking methods. The purpose of this study is to product distribution as a function over temperature, to identifying the region of the carbon deposition and to analysis the effect of temperature on the equilibrium constant. Hydrogen production varies significantly according to the operating conditions such as pressure, temperature and feed reactants ratio. The thermodynamic analysis provides important knowledge about the effects of those variables on the process of propane dehydrogenation. The present work was aimed at analyzing the thermodynamic propane dehydrogenation of propylene, using Gibbs free energy minimization with actual temperature and pressure data found in the literature. The results showed that the extent of side reactions strongly depends on the operating conditions. By computing carbon activities in experimental systems, it was also possible to explain deviations between thermodynamic analysis and experimental results regarding carbon deposition. From the results obtained¸ all of possible reactions are endothermic reaction and the dehydrogenation temperature needs to be evaluated to beyond 500 K to 600 K.
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format Undergraduates Project Papers
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institution Universiti Malaysia Pahang
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language English
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publishDate 2013
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spelling ump-72082021-06-08T07:05:20Z http://umpir.ump.edu.my/id/eprint/7208/ Thermodynamic Study of Propane Dehydrogenation Into Propylene Qurratuaini, Hassanusi TJ Mechanical engineering and machinery Propane dehydrogenation is a one of a promising route for producing propylene by using thermodynamic analysis to replace traditional cracking methods. The purpose of this study is to product distribution as a function over temperature, to identifying the region of the carbon deposition and to analysis the effect of temperature on the equilibrium constant. Hydrogen production varies significantly according to the operating conditions such as pressure, temperature and feed reactants ratio. The thermodynamic analysis provides important knowledge about the effects of those variables on the process of propane dehydrogenation. The present work was aimed at analyzing the thermodynamic propane dehydrogenation of propylene, using Gibbs free energy minimization with actual temperature and pressure data found in the literature. The results showed that the extent of side reactions strongly depends on the operating conditions. By computing carbon activities in experimental systems, it was also possible to explain deviations between thermodynamic analysis and experimental results regarding carbon deposition. From the results obtained¸ all of possible reactions are endothermic reaction and the dehydrogenation temperature needs to be evaluated to beyond 500 K to 600 K. 2013-02 Undergraduates Project Papers NonPeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/7208/1/CD7100.pdf Qurratuaini, Hassanusi (2013) Thermodynamic Study of Propane Dehydrogenation Into Propylene. Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang .
spellingShingle TJ Mechanical engineering and machinery
Qurratuaini, Hassanusi
Thermodynamic Study of Propane Dehydrogenation Into Propylene
title Thermodynamic Study of Propane Dehydrogenation Into Propylene
title_full Thermodynamic Study of Propane Dehydrogenation Into Propylene
title_fullStr Thermodynamic Study of Propane Dehydrogenation Into Propylene
title_full_unstemmed Thermodynamic Study of Propane Dehydrogenation Into Propylene
title_short Thermodynamic Study of Propane Dehydrogenation Into Propylene
title_sort thermodynamic study of propane dehydrogenation into propylene
topic TJ Mechanical engineering and machinery
url http://umpir.ump.edu.my/id/eprint/7208/
http://umpir.ump.edu.my/id/eprint/7208/1/CD7100.pdf