Regioselectivity in nucleophilic ring-opening of aziridinones

QR Code

Regioselectivity in nucleophilic ring-opening of aziridinones

The proportions of products derived from competing modes of ring-opening of 1,3-di-tert-butylaziridinone and similar aziridinones by a variety of nitrogen, oxygen, sulfur and halogen nucleophiles do not agree with simple guidelines postulated in the literature for these types of aziridinones.

Bibliographic Details
Main Authors:	M. M., Yusoff, Talaty, Erach R.
Format:	Article
Language:	English
Published:	Royal Society of Chemistry 1998
Subjects:	Q Science (General) QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/4771/ http://umpir.ump.edu.my/id/eprint/4771/1/Regioselectivity_in_nucleophilic_ring-opening_of_aziridinones.pdf

Similar Items

Preparation of Substituted Imidazolidinones and Hydantoins by Ring-Expansion of Aziridinones
by: M. M., Yusoff, et al.
Published: (1997)

Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement
by: M. M., Yusoff, et al.
Published: (1996)

Synthesis and X-ray Analysis of (RS)-N-tert-butyl-2-anilino- 3,3-dimethylbutanamide
by: M. M., Yusoff, et al.
Published: (1997)

Crystal structure of 1,5-di-tert-butyl-2-(methylamino)-2-imidazolin-4-one monohydrate, C12H24N3O1.5
by: M. M., Yusoff, et al.
Published: (1998)

Crystal structure of 1,5-di-tert-butyl-2-iminoimidazolidin-4-one, C11H21N3O
by: M. M., Yusoff, et al.
Published: (1998)

An analysis of chloride…π(chelate ring) interactions
by: Tiekink, Edward R. T. *
Published: (2019)

High Performance Dye-Sensitized Solar Cells with Record Open Circuit Voltage using Tin Oxide Nanoflowers Developed by Electrospinning
by: M. M., Yusoff, et al.
Published: (2012)

Nucleophilic thiol-Michael chemistry and hyperbranched (co)polymers: Synthesis and ring-opening metathesis (co)polymerization of novel difunctional exo-7-oxanorbornenes with in situ inimer formation
by: Liu, M., et al.
Published: (2013)

Copper(i) complexes: intramolecular and intermolecular arene-c– h···π(quasi-chelate ring) interactions
by: Yeo, Chien Ing *, et al.
Published: (2017)

Synthesis and characterization of 1,3,4-oxadiazoles bearing an indole ring
by: Ng, Yu Xuan
Published: (2020)

Structural Study Of Epoxidized Natural Rubber (Enr-50) And Its Derivatives Synthesized Via Epoxide Ring-Opening Reactions Using Nmr Techniques
by: Hamzah, Rosniza
Published: (2015)

Synthesis, characterization and antioxidant activity of 1,3,4-oxadiazoles bearing an indole ring
by: Kong, Kian Liang
Published: (2019)

Synthesis, characterization and antioxidant activity of 1,3,4-oxadiazoles bearing an indole ring
by: Kong, Kian Liang
Published: (2019)

Experimental and computational evidence for a stabilising C–Cl(lone-pair)⋯π(chelate-ring) interaction
by: Tan, Sang Loon *, et al.
Published: (2021)

Bismuth-Mediated Arylation of Weak Nucleophiles
by: Ruffell, Katie
Published: (2023)

Synthesis and Characterization of Liquid Crystalline Azobenzene Chromophores with Fluorobenzene Terminal
by: M. M., Yusoff, et al.
Published: (2013)

Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
by: Sarkar, Shaheen M., et al.
Published: (2016)

Isolation, Identification of Secondary Metabolites and Anti Bacterial Property of Memecylon Edule Leaves Extract
by: M. M., Yusoff, et al.
Published: (2012)

Nanocrystals of a New Complex Perovskite Dielectric Ba2TmSbO6
by: M. M., Yusoff, et al.
Published: (2012)

Chemical And Biological Studies Of Zingiber Phillipseae Rhizomes Extract
by: M. M., Yusoff, et al.
Published: (2012)

Physicochemical, Minerals and Antioxidant Properties of Labisia pumila var. alata of Selected Geographic Origin
by: M. M., Yusoff, et al.
Published: (2012)

The remarkable propensity for the formation of C–H⋯π(chelate ring) interactions in the crystals of the first-row transition metal dithiocarbamates and the supramolecular architectures they sustain.
by: Tiekink, Edward R. T. *
Published: (2020)

1-[4-(Prop-2-en-1-yloxy)benzyl]-2-[4-(prop-2-en-1-yloxy)phenyl]-1H benzimidazole
by: Hegde, Gurumurthy, et al.
Published: (2012)

Process for preparation of labisia pumila extract
by: M. M., Yusoff, et al.
Published: (2011)

Synthesis of Gold Dendrites in a Green Chemistry Approach Using Hydroxyethyl Cellulose
by: Jahir Hussain, Fathima Shahitha, et al.
Published: (2011)

Chemical Characterization and Antimicrobial Activity of Rhizome Essential Oils of Very Closely Allied Zingiberaceae Species Endemic to Borneo: Alpinia Ligulata K. Schum. and Alpinia nieuwenhuizii Val.
by: M. M., Yusoff, et al.
Published: (2011)

New Pyrimidine-based Photo-switchable Bent-core Liquid Crystals
by: M. M., Yusoff, et al.
Published: (2013)

Catalytic activation of nitriles towards nucleophilic addition
by: Lester, Roy P.
Published: (2015)

Gold-catalysed nucleophilic allylation of azinium ions
by: O'Brien, Luke
Published: (2023)

Remote nucleophilic allylation by allylrhodium chain walking
by: Groves, Alistair, et al.
Published: (2018)

4-{(E)-2-[4-(But-3-en-1-yloxy)phenyl]diazen-1-yl}Benzoic Acid
by: Lutfor, M. R., et al.
Published: (2012)

Gingers at the Dagat Limestone Ridge, Tabin Wildlife Reserve
by: M. M., Yusoff, et al.
Published: (2003)

A case study - Regulation and Functional Mechanisms of Cancer Cells and Control its Activity Using Plants and their Derivatives
by: Gaanty Pragas, Maniam, et al.
Published: (2013)

The pyrrolidine ring and its relation with the psychoactivity of mitragynine
by: Mohd Ghazali, Masitah, et al.
Published: (2015)

Characterization of the Chemical Constituents of Agarwood Oils from Malaysia by Comprehensive Two-Dimensional Gas Chromatography–Time-of-Flight Mass Spectrometry
by: Saiful Nizam, Tajuddin, et al.
Published: (2013)

Fatty Acid Composition and Antibacterial Activity of Swietenia Macrophylla King Seed Oil
by: M. M., Yusoff, et al.
Published: (2013)

Standardization of Photoelectrode Area of Dye-Sensitized Solar Cells
by: Fakharuddin, Azhar, et al.
Published: (2013)

Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
by: M. M., Yusoff, et al.
Published: (2013)

Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
by: M. M., Yusoff, et al.
Published: (2013)

Nanostructured Materials From Hydroxyethyl Cellulose For Skin Tissue Engineering
by: Farah Hanani, Zulkifli, et al.
Published: (2014)