Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals

In order to investigate the photoalignment mechanism of nematic liquid crystals on an oxadiazoles, new 1,3,4-oxadiazole having fluorine atoms as terminal, as well as sideways was synthesized. Linearly polarized UV light shined in these nano-layered films causes the preferential direction of the liqu...

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Main Authors: M. M., Yusoff, Rasha, Ata Alaa, Hegde, Gurumurthy, Arun, M Isloor, Boodappa, Chandrakantha, Shridhar, Mallad, Lachezar, Komitov
Format: Article
Language:English
Published: Scientific Research Publishing Inc 2013
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Online Access:http://umpir.ump.edu.my/id/eprint/4696/
http://umpir.ump.edu.my/id/eprint/4696/1/NanoEngineering_of_New_Photoreactive_Materials_Having_Fluorine_Units_Synthesis_and_Photoalignment_of_Liquid_Crystals.pdf
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author M. M., Yusoff
Rasha, Ata Alaa
Hegde, Gurumurthy
Arun, M Isloor
Boodappa, Chandrakantha
Shridhar, Mallad
Lachezar, Komitov
author_facet M. M., Yusoff
Rasha, Ata Alaa
Hegde, Gurumurthy
Arun, M Isloor
Boodappa, Chandrakantha
Shridhar, Mallad
Lachezar, Komitov
author_sort M. M., Yusoff
building UMP Institutional Repository
collection Online Access
description In order to investigate the photoalignment mechanism of nematic liquid crystals on an oxadiazoles, new 1,3,4-oxadiazole having fluorine atoms as terminal, as well as sideways was synthesized. Linearly polarized UV light shined in these nano-layered films causes the preferential direction of the liquid crystal molecules either perpendicular (in the case of terminal fluoro substitution) or parallel (in the case of sideways fluorine substitution) to the polarized direction. A powerful indication about the relationship between molecular structure and alignment properties where just by changing fluorine atom can change the entire alignment direction is proposed. Such information is indispensable for the design and synthesis of photoalignment materials for liquid crystal displays of high quality.
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publishDate 2013
publisher Scientific Research Publishing Inc
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spelling ump-46962018-07-27T03:24:21Z http://umpir.ump.edu.my/id/eprint/4696/ Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals M. M., Yusoff Rasha, Ata Alaa Hegde, Gurumurthy Arun, M Isloor Boodappa, Chandrakantha Shridhar, Mallad Lachezar, Komitov Q Science (General) QD Chemistry In order to investigate the photoalignment mechanism of nematic liquid crystals on an oxadiazoles, new 1,3,4-oxadiazole having fluorine atoms as terminal, as well as sideways was synthesized. Linearly polarized UV light shined in these nano-layered films causes the preferential direction of the liquid crystal molecules either perpendicular (in the case of terminal fluoro substitution) or parallel (in the case of sideways fluorine substitution) to the polarized direction. A powerful indication about the relationship between molecular structure and alignment properties where just by changing fluorine atom can change the entire alignment direction is proposed. Such information is indispensable for the design and synthesis of photoalignment materials for liquid crystal displays of high quality. Scientific Research Publishing Inc 2013-01 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/4696/1/NanoEngineering_of_New_Photoreactive_Materials_Having_Fluorine_Units_Synthesis_and_Photoalignment_of_Liquid_Crystals.pdf M. M., Yusoff and Rasha, Ata Alaa and Hegde, Gurumurthy and Arun, M Isloor and Boodappa, Chandrakantha and Shridhar, Mallad and Lachezar, Komitov (2013) Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals. Soft Nanoscience Letters, 3 (1). pp. 1-6. ISSN 2160-0600 (print), 2160-0740 (online). (Published) http://dx.doi.org/ 10.4236/snl.2013.31001 DOI: 10.4236/snl.2013.31001
spellingShingle Q Science (General)
QD Chemistry
M. M., Yusoff
Rasha, Ata Alaa
Hegde, Gurumurthy
Arun, M Isloor
Boodappa, Chandrakantha
Shridhar, Mallad
Lachezar, Komitov
Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
title Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
title_full Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
title_fullStr Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
title_full_unstemmed Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
title_short Nano-Engineering of New Photoreactive Materials Having Fluorine Units: Synthesis and Photoalignment of Liquid Crystals
title_sort nano-engineering of new photoreactive materials having fluorine units: synthesis and photoalignment of liquid crystals
topic Q Science (General)
QD Chemistry
url http://umpir.ump.edu.my/id/eprint/4696/
http://umpir.ump.edu.my/id/eprint/4696/
http://umpir.ump.edu.my/id/eprint/4696/
http://umpir.ump.edu.my/id/eprint/4696/1/NanoEngineering_of_New_Photoreactive_Materials_Having_Fluorine_Units_Synthesis_and_Photoalignment_of_Liquid_Crystals.pdf