Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition

The growing wound care market and global waste production increase the demand for biodegradable biomaterials. Epoxidized natural rubber has suitable properties such as biocompatibility, high mechanical strength, flexibility, and elasticity to serve as a biomaterial in the production of cellular scaf...

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Main Authors: Tong, Hui Shan, Farah Hanani, Zulkifli, Siti Maznah, Kabeb
Format: Article
Language:English
Published: John Wiley & Sons, Inc. 2025
Subjects:
Online Access:https://umpir.ump.edu.my/id/eprint/45968/
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author Tong, Hui Shan
Farah Hanani, Zulkifli
Siti Maznah, Kabeb
author_facet Tong, Hui Shan
Farah Hanani, Zulkifli
Siti Maznah, Kabeb
author_sort Tong, Hui Shan
building UMP Institutional Repository
collection Online Access
description The growing wound care market and global waste production increase the demand for biodegradable biomaterials. Epoxidized natural rubber has suitable properties such as biocompatibility, high mechanical strength, flexibility, and elasticity to serve as a biomaterial in the production of cellular scaffolds, wound dressings, transdermal drug delivery patches, and sustained drug delivery system components. To further enhance its suitability as a biomaterial, epoxidized natural rubber is graft copolymerized with hydroxyethyl cellulose and polyvinyl alcohol, which are both highly biocompatible and non-cytotoxic materials. The grafted material is then electrospun to mimic the extracellular matrix of skin, which can potentially improve the healing abilities of the nanofiber. The epoxidation of natural rubber is confirmed through Proton Nuclear Magnetic Resonance (1 H NMR), while a more closely packed, orderly structure and higher carbon to oxygen ratio is seen through Field Emission Scanning Electron Microscopy with Energy Dispersive X-Ray Spectroscopy (FESEM-EDX), along with additional functional groups depicted through Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) with the addition of epoxidized natural rubber. In conclusion, the morphology and chemical composition of epoxidized natural rubber-grafted-hydroxyethyl cellulose (ENR-g-HEC) nanofibers are suitable to be used as a biomaterial in biomedical applications.
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spelling ump-459682025-10-17T06:59:18Z https://umpir.ump.edu.my/id/eprint/45968/ Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition Tong, Hui Shan Farah Hanani, Zulkifli Siti Maznah, Kabeb HD Industries. Land use. Labor TP Chemical technology The growing wound care market and global waste production increase the demand for biodegradable biomaterials. Epoxidized natural rubber has suitable properties such as biocompatibility, high mechanical strength, flexibility, and elasticity to serve as a biomaterial in the production of cellular scaffolds, wound dressings, transdermal drug delivery patches, and sustained drug delivery system components. To further enhance its suitability as a biomaterial, epoxidized natural rubber is graft copolymerized with hydroxyethyl cellulose and polyvinyl alcohol, which are both highly biocompatible and non-cytotoxic materials. The grafted material is then electrospun to mimic the extracellular matrix of skin, which can potentially improve the healing abilities of the nanofiber. The epoxidation of natural rubber is confirmed through Proton Nuclear Magnetic Resonance (1 H NMR), while a more closely packed, orderly structure and higher carbon to oxygen ratio is seen through Field Emission Scanning Electron Microscopy with Energy Dispersive X-Ray Spectroscopy (FESEM-EDX), along with additional functional groups depicted through Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) with the addition of epoxidized natural rubber. In conclusion, the morphology and chemical composition of epoxidized natural rubber-grafted-hydroxyethyl cellulose (ENR-g-HEC) nanofibers are suitable to be used as a biomaterial in biomedical applications. John Wiley & Sons, Inc. 2025-10 Article PeerReviewed pdf en https://umpir.ump.edu.my/id/eprint/45968/1/ICSEM2025%20-%20TONG%20HUI%20SHAN.pdf Tong, Hui Shan and Farah Hanani, Zulkifli and Siti Maznah, Kabeb (2025) Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition. Macromolecular Symposia. pp. 1-8. ISSN 1521-3900. (In Press / Online First) (In Press / Online First) https://doi.org/10.1002/masy.70143
spellingShingle HD Industries. Land use. Labor
TP Chemical technology
Tong, Hui Shan
Farah Hanani, Zulkifli
Siti Maznah, Kabeb
Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition
title Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition
title_full Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition
title_fullStr Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition
title_full_unstemmed Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition
title_short Grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: Morphology and chemical composition
title_sort grafting epoxidized natural rubber on hydroxyethyl cellulose/polyvinyl alcohol nanofiber: morphology and chemical composition
topic HD Industries. Land use. Labor
TP Chemical technology
url https://umpir.ump.edu.my/id/eprint/45968/
https://umpir.ump.edu.my/id/eprint/45968/