Modeling and Characterization of Ion-Imprinted Polymer for Arsenic Species Removal From Aqueous Solution
Arsenic (As) contamination is a global issue, especially in As-rich geological formations. In this study, an ion-imprinted polymer (As(III)-IIP) is synthesized and characterized in terms of kinetic modeling and application via solid phase extraction (SPE). As is detected by using the inductively cou...
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| Format: | Article |
| Language: | English |
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John Wiley & Sons, Inc.
2025
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| Online Access: | https://umpir.ump.edu.my/id/eprint/45333/ |
| _version_ | 1848827386880065536 |
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| author | Nurlin, Abu Samah |
| author_facet | Nurlin, Abu Samah |
| author_sort | Nurlin, Abu Samah |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Arsenic (As) contamination is a global issue, especially in As-rich geological formations. In this study, an ion-imprinted polymer (As(III)-IIP) is synthesized and characterized in terms of kinetic modeling and application via solid phase extraction (SPE). As is detected by using the inductively coupled plasma-mass spectrometer (ICP-MS). The surface study is also included in this study, in which the differences between non-imprinted polymer (NIP) and As(III)-IIP before and after sorption are observed via field electron scanning electron microscope (FESEM). As a result, As(III)-IIP follows the pseudo-second-order of reaction in kinetics and reaches 95% within 5 min of removal. In FESEM micrographs, As(III)-IIP shows the particles on the surface are likely homogenous compared to NIP. Whereas As(III)-IIP after sorption is much more likely bigger than the original As(III)-IIP due to the expansion of particles during agitation in an aqueous solution. In the first cycle, 99.53% ± 0.45% of removal in real wastewater analysis is obtained via SPE. However, for the second cycle onwards, the removal is not removed totally, which shows that a new combination of eluent is required. In conclusion, As(III)-IIP shows good potential as a sorbent to be used for the removal of As from wastewater. |
| first_indexed | 2025-11-15T03:59:54Z |
| format | Article |
| id | ump-45333 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T03:59:54Z |
| publishDate | 2025 |
| publisher | John Wiley & Sons, Inc. |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-453332025-08-12T03:57:12Z https://umpir.ump.edu.my/id/eprint/45333/ Modeling and Characterization of Ion-Imprinted Polymer for Arsenic Species Removal From Aqueous Solution Nurlin, Abu Samah QD Chemistry TP Chemical technology Arsenic (As) contamination is a global issue, especially in As-rich geological formations. In this study, an ion-imprinted polymer (As(III)-IIP) is synthesized and characterized in terms of kinetic modeling and application via solid phase extraction (SPE). As is detected by using the inductively coupled plasma-mass spectrometer (ICP-MS). The surface study is also included in this study, in which the differences between non-imprinted polymer (NIP) and As(III)-IIP before and after sorption are observed via field electron scanning electron microscope (FESEM). As a result, As(III)-IIP follows the pseudo-second-order of reaction in kinetics and reaches 95% within 5 min of removal. In FESEM micrographs, As(III)-IIP shows the particles on the surface are likely homogenous compared to NIP. Whereas As(III)-IIP after sorption is much more likely bigger than the original As(III)-IIP due to the expansion of particles during agitation in an aqueous solution. In the first cycle, 99.53% ± 0.45% of removal in real wastewater analysis is obtained via SPE. However, for the second cycle onwards, the removal is not removed totally, which shows that a new combination of eluent is required. In conclusion, As(III)-IIP shows good potential as a sorbent to be used for the removal of As from wastewater. John Wiley & Sons, Inc. 2025-02-17 Article PeerReviewed pdf en https://umpir.ump.edu.my/id/eprint/45333/1/100105409.pdf Nurlin, Abu Samah (2025) Modeling and Characterization of Ion-Imprinted Polymer for Arsenic Species Removal From Aqueous Solution. Macromolecular Symposia, 414 (2300222). pp. 1-6. ISSN 1521-3900. (Published) https://doi.org/10.1002/masy.202300222 https://doi.org/10.1002/masy.202300222 https://doi.org/10.1002/masy.202300222 |
| spellingShingle | QD Chemistry TP Chemical technology Nurlin, Abu Samah Modeling and Characterization of Ion-Imprinted Polymer for Arsenic Species Removal From Aqueous Solution |
| title | Modeling and Characterization of Ion-Imprinted Polymer for
Arsenic Species Removal From Aqueous Solution |
| title_full | Modeling and Characterization of Ion-Imprinted Polymer for
Arsenic Species Removal From Aqueous Solution |
| title_fullStr | Modeling and Characterization of Ion-Imprinted Polymer for
Arsenic Species Removal From Aqueous Solution |
| title_full_unstemmed | Modeling and Characterization of Ion-Imprinted Polymer for
Arsenic Species Removal From Aqueous Solution |
| title_short | Modeling and Characterization of Ion-Imprinted Polymer for
Arsenic Species Removal From Aqueous Solution |
| title_sort | modeling and characterization of ion-imprinted polymer for
arsenic species removal from aqueous solution |
| topic | QD Chemistry TP Chemical technology |
| url | https://umpir.ump.edu.my/id/eprint/45333/ https://umpir.ump.edu.my/id/eprint/45333/ https://umpir.ump.edu.my/id/eprint/45333/ |