A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions

Seeding involves introducing a pre- formed Carbamazepine-Saccharin (CBZ-SAC) co-crystal into a solution, influenced by seeding temperature, seed size and seed loading. The primary objective of this research is to explore the effects of seeding temperature, seed size and seed loading on the productio...

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Main Authors: Khairool Azizul, Mohammad, Ping, Kathie L. W., Nurul Asilah, Md. Amin, Engku N. H. E., Zainudin, Syarifah, Abd Rahim
Format: Article
Language:English
Published: Egyptian Journal of Chemistry 2025
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/45051/
http://umpir.ump.edu.my/id/eprint/45051/1/A%20study%20on%20the%20production%20of%20high-quality%20carbamazepine-saccharin.pdf
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author Khairool Azizul, Mohammad
Ping, Kathie L. W.
Nurul Asilah, Md. Amin
Engku N. H. E., Zainudin
Syarifah, Abd Rahim
author_facet Khairool Azizul, Mohammad
Ping, Kathie L. W.
Nurul Asilah, Md. Amin
Engku N. H. E., Zainudin
Syarifah, Abd Rahim
author_sort Khairool Azizul, Mohammad
building UMP Institutional Repository
collection Online Access
description Seeding involves introducing a pre- formed Carbamazepine-Saccharin (CBZ-SAC) co-crystal into a solution, influenced by seeding temperature, seed size and seed loading. The primary objective of this research is to explore the effects of seeding temperature, seed size and seed loading on the production of CBZ-SAC co-crystals. The seeding experiment was done by adding seed crystal at targeted seeding temperature during the second cooling phase. The experiment was repeated with different seeding temperatures of 20 °C, 25 °C, 30 °C, 35 °C and 40 °C; seed size of <90, 106-125, 125-160 and 160-180 μm; and seed loading of 31.85, 63.70, 95.55 and 127.4 mg. The study reveals that higher seeding temperature and larger crystal size decrease crystal nucleation rate, while higher seed loading increases it. The optimal seeding temperature between 25 °C to 30 °C, with the ideal seed size being 125-160 μm and seed loading is 63.7 mg. In conclusion, the research highlights the critical role of seeding temperature, seed size, and seed loading in the production of CBZ-SAC co-crystals. Additional research focusing on commercialization could involve ADME analysis or solubility test of the co-crystal produced for deeper understanding on the economic advantages associated with CBZ-SAC co-crystal.
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institution Universiti Malaysia Pahang
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language English
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publishDate 2025
publisher Egyptian Journal of Chemistry
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spelling ump-450512025-07-10T03:12:31Z http://umpir.ump.edu.my/id/eprint/45051/ A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions Khairool Azizul, Mohammad Ping, Kathie L. W. Nurul Asilah, Md. Amin Engku N. H. E., Zainudin Syarifah, Abd Rahim QD Chemistry RS Pharmacy and materia medica TP Chemical technology Seeding involves introducing a pre- formed Carbamazepine-Saccharin (CBZ-SAC) co-crystal into a solution, influenced by seeding temperature, seed size and seed loading. The primary objective of this research is to explore the effects of seeding temperature, seed size and seed loading on the production of CBZ-SAC co-crystals. The seeding experiment was done by adding seed crystal at targeted seeding temperature during the second cooling phase. The experiment was repeated with different seeding temperatures of 20 °C, 25 °C, 30 °C, 35 °C and 40 °C; seed size of <90, 106-125, 125-160 and 160-180 μm; and seed loading of 31.85, 63.70, 95.55 and 127.4 mg. The study reveals that higher seeding temperature and larger crystal size decrease crystal nucleation rate, while higher seed loading increases it. The optimal seeding temperature between 25 °C to 30 °C, with the ideal seed size being 125-160 μm and seed loading is 63.7 mg. In conclusion, the research highlights the critical role of seeding temperature, seed size, and seed loading in the production of CBZ-SAC co-crystals. Additional research focusing on commercialization could involve ADME analysis or solubility test of the co-crystal produced for deeper understanding on the economic advantages associated with CBZ-SAC co-crystal. Egyptian Journal of Chemistry 2025 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/45051/1/A%20study%20on%20the%20production%20of%20high-quality%20carbamazepine-saccharin.pdf Khairool Azizul, Mohammad and Ping, Kathie L. W. and Nurul Asilah, Md. Amin and Engku N. H. E., Zainudin and Syarifah, Abd Rahim (2025) A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions. Egyptian Journal of Chemistry, 68 (8). pp. 161-168. ISSN 2357-0245 (printed); 0449-2285(online). (Published) https://doi.org/10.21608/EJCHEM.2024.325215.10560 Abstract https://doi.org/10.21608/EJCHEM.2024.325215.10560 Abstract
spellingShingle QD Chemistry
RS Pharmacy and materia medica
TP Chemical technology
Khairool Azizul, Mohammad
Ping, Kathie L. W.
Nurul Asilah, Md. Amin
Engku N. H. E., Zainudin
Syarifah, Abd Rahim
A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions
title A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions
title_full A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions
title_fullStr A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions
title_full_unstemmed A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions
title_short A Study on the Production of High-Quality Carbamazepine-Saccharin Co-Crystals: The Role of Seeding Conditions
title_sort study on the production of high-quality carbamazepine-saccharin co-crystals: the role of seeding conditions
topic QD Chemistry
RS Pharmacy and materia medica
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/45051/
http://umpir.ump.edu.my/id/eprint/45051/
http://umpir.ump.edu.my/id/eprint/45051/
http://umpir.ump.edu.my/id/eprint/45051/1/A%20study%20on%20the%20production%20of%20high-quality%20carbamazepine-saccharin.pdf