A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties

Natural rubber latex (NRL) is a biopolymer consisting of isoprene monomers in a cis configuration connected by double bonds that can degrade naturally. Most natural rubber (NR) based products are single-use items and its microbial degradation process is relatively slow. Hence, this review highlights...

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Main Authors: Tong, Hui Shan, Siti Maznah, Kabeb, Hazrulrizawati, Abd Hamid, Farah Hanani, Zulkifli
Format: Article
Language:English
Published: Elsevier Ltd 2025
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/44831/
http://umpir.ump.edu.my/id/eprint/44831/1/A%20review%20of%20biodegradability%20of%20natural%20rubber%20products_%20Physicochemical%2C%20thermal%20and%20mechanical%20properties_compressed.pdf
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author Tong, Hui Shan
Siti Maznah, Kabeb
Hazrulrizawati, Abd Hamid
Farah Hanani, Zulkifli
author_facet Tong, Hui Shan
Siti Maznah, Kabeb
Hazrulrizawati, Abd Hamid
Farah Hanani, Zulkifli
author_sort Tong, Hui Shan
building UMP Institutional Repository
collection Online Access
description Natural rubber latex (NRL) is a biopolymer consisting of isoprene monomers in a cis configuration connected by double bonds that can degrade naturally. Most natural rubber (NR) based products are single-use items and its microbial degradation process is relatively slow. Hence, this review highlights the importance in the enhancement of biodegradation of NR, the methods applied to increase the biodegradation rate, and characterization of biodegradation of rubber. The biodegradability of NR-based products is enhanced via selective microorganism strains, suitable composting environment and the addition of biofillers. Rubber oxygenase enzymes and latex cleavage protein are major contributors in the biodegradation of NR-based products, while biofillers such as chitosan, cellulose whiskers and starch enhances biodegradation rate up to 60 %. Biodegradation of NR-based products is confirmed through characterization of physicochemical, thermal and mechanical properties using SEM, XRD, FTIR, GPC, TGA, UTM, physical appearance and weight loss. NR-based materials with enhanced biodegradability have many uses, thus its customizability should be studied further in terms of different product forms, fabrication method, orientation of biofiller used and incorporation of metal organic frameworks.
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spelling ump-448312025-06-17T01:57:05Z http://umpir.ump.edu.my/id/eprint/44831/ A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties Tong, Hui Shan Siti Maznah, Kabeb Hazrulrizawati, Abd Hamid Farah Hanani, Zulkifli HD Industries. Land use. Labor Natural rubber latex (NRL) is a biopolymer consisting of isoprene monomers in a cis configuration connected by double bonds that can degrade naturally. Most natural rubber (NR) based products are single-use items and its microbial degradation process is relatively slow. Hence, this review highlights the importance in the enhancement of biodegradation of NR, the methods applied to increase the biodegradation rate, and characterization of biodegradation of rubber. The biodegradability of NR-based products is enhanced via selective microorganism strains, suitable composting environment and the addition of biofillers. Rubber oxygenase enzymes and latex cleavage protein are major contributors in the biodegradation of NR-based products, while biofillers such as chitosan, cellulose whiskers and starch enhances biodegradation rate up to 60 %. Biodegradation of NR-based products is confirmed through characterization of physicochemical, thermal and mechanical properties using SEM, XRD, FTIR, GPC, TGA, UTM, physical appearance and weight loss. NR-based materials with enhanced biodegradability have many uses, thus its customizability should be studied further in terms of different product forms, fabrication method, orientation of biofiller used and incorporation of metal organic frameworks. Elsevier Ltd 2025 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/44831/1/A%20review%20of%20biodegradability%20of%20natural%20rubber%20products_%20Physicochemical%2C%20thermal%20and%20mechanical%20properties_compressed.pdf Tong, Hui Shan and Siti Maznah, Kabeb and Hazrulrizawati, Abd Hamid and Farah Hanani, Zulkifli (2025) A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties. International Journal of Biological Macromolecules, 318 (144973). pp. 1-17. ISSN 0141-8130. (Published) https://doi.org/10.1016/j.ijbiomac.2025.144973 10.1016/j.ijbiomac.2025.144973
spellingShingle HD Industries. Land use. Labor
Tong, Hui Shan
Siti Maznah, Kabeb
Hazrulrizawati, Abd Hamid
Farah Hanani, Zulkifli
A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties
title A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties
title_full A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties
title_fullStr A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties
title_full_unstemmed A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties
title_short A review of biodegradability of natural rubber products: Physicochemical, thermal and mechanical properties
title_sort review of biodegradability of natural rubber products: physicochemical, thermal and mechanical properties
topic HD Industries. Land use. Labor
url http://umpir.ump.edu.my/id/eprint/44831/
http://umpir.ump.edu.my/id/eprint/44831/
http://umpir.ump.edu.my/id/eprint/44831/
http://umpir.ump.edu.my/id/eprint/44831/1/A%20review%20of%20biodegradability%20of%20natural%20rubber%20products_%20Physicochemical%2C%20thermal%20and%20mechanical%20properties_compressed.pdf