Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries

The advancement of modified anodes and cathodes for the next generation of sulfur-based batteries has become a prominent focus of research. This study introduces a methodology for the design and synthesis of silicon/graphene nanoplates (Si/GNPs) through a one-step hydrothermal process. Additionally,...

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Main Authors: Aslfattahi, Navid, Kiai, Maryam Sadat, Baydogan, Nilgun, Samylingam, Lingenthiran, Kadirgama, Kumaran, Kok, Chee Kuang
Format: Article
Language:English
Published: American Chemical Society (ACS Publications)
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/44814/
http://umpir.ump.edu.my/id/eprint/44814/1/Integration%20of%20carbon-doped%20ZnOS%20cathode%20and%20silicon.pdf
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author Aslfattahi, Navid
Kiai, Maryam Sadat
Baydogan, Nilgun
Samylingam, Lingenthiran
Kadirgama, Kumaran
Kok, Chee Kuang
author_facet Aslfattahi, Navid
Kiai, Maryam Sadat
Baydogan, Nilgun
Samylingam, Lingenthiran
Kadirgama, Kumaran
Kok, Chee Kuang
author_sort Aslfattahi, Navid
building UMP Institutional Repository
collection Online Access
description The advancement of modified anodes and cathodes for the next generation of sulfur-based batteries has become a prominent focus of research. This study introduces a methodology for the design and synthesis of silicon/graphene nanoplates (Si/GNPs) through a one-step hydrothermal process. Additionally, we suggest nanocomposite carbon-doped ZnO/S as a potential cathode material through the urea-assisted thermal decomposition of zinc acetate. C/ZnO/S has the special capability to alleviate volume change and hinder sulfur dissolution of the electrolyte. Additionally, ZnO possesses a superior distribution of sulfur in the ZnO/S composite and enhanced sulfur conversion reactions. This configuration of the cell is mentioned for the first time and shows an outstanding retention capacity of 916 mAh g–1 after 500 cycles, indicating a minimal decay rate of merely 0.047% per cycle.
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format Article
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institution Universiti Malaysia Pahang
institution_category Local University
language English
last_indexed 2025-11-15T03:56:45Z
publisher American Chemical Society (ACS Publications)
recordtype eprints
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spelling ump-448142025-06-16T03:11:45Z http://umpir.ump.edu.my/id/eprint/44814/ Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries Aslfattahi, Navid Kiai, Maryam Sadat Baydogan, Nilgun Samylingam, Lingenthiran Kadirgama, Kumaran Kok, Chee Kuang QD Chemistry TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TK Electrical engineering. Electronics Nuclear engineering The advancement of modified anodes and cathodes for the next generation of sulfur-based batteries has become a prominent focus of research. This study introduces a methodology for the design and synthesis of silicon/graphene nanoplates (Si/GNPs) through a one-step hydrothermal process. Additionally, we suggest nanocomposite carbon-doped ZnO/S as a potential cathode material through the urea-assisted thermal decomposition of zinc acetate. C/ZnO/S has the special capability to alleviate volume change and hinder sulfur dissolution of the electrolyte. Additionally, ZnO possesses a superior distribution of sulfur in the ZnO/S composite and enhanced sulfur conversion reactions. This configuration of the cell is mentioned for the first time and shows an outstanding retention capacity of 916 mAh g–1 after 500 cycles, indicating a minimal decay rate of merely 0.047% per cycle. American Chemical Society (ACS Publications) Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/44814/1/Integration%20of%20carbon-doped%20ZnOS%20cathode%20and%20silicon.pdf Aslfattahi, Navid and Kiai, Maryam Sadat and Baydogan, Nilgun and Samylingam, Lingenthiran and Kadirgama, Kumaran and Kok, Chee Kuang Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries. ACS Applied Nano Materials. ISSN 2574-0970. (Published) https://doi.org/10.1021/acsanm.5c00563 https://doi.org/10.1021/acsanm.5c00563
spellingShingle QD Chemistry
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
Aslfattahi, Navid
Kiai, Maryam Sadat
Baydogan, Nilgun
Samylingam, Lingenthiran
Kadirgama, Kumaran
Kok, Chee Kuang
Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
title Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
title_full Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
title_fullStr Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
title_full_unstemmed Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
title_short Integration of carbon-doped ZnO/S cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
title_sort integration of carbon-doped zno/s cathode and silicon/graphene nanoplate anode for silicon-sulfur batteries
topic QD Chemistry
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
url http://umpir.ump.edu.my/id/eprint/44814/
http://umpir.ump.edu.my/id/eprint/44814/
http://umpir.ump.edu.my/id/eprint/44814/
http://umpir.ump.edu.my/id/eprint/44814/1/Integration%20of%20carbon-doped%20ZnOS%20cathode%20and%20silicon.pdf