The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel

Biodiesel is a highly sustainable alternative to alleviate fossil fuel shortages and environmental concerns. Many countries have adopted the practice of blending biodiesel into diesel at specific ratios. This study focused on the effect of different biodiesel-diesel blend ratio in terms of acid valu...

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Main Authors: Ying, C. Z., Maniam, Gaanty Pragas, Nurliyana, Moh Hussin, S. N. M., Khazaai
Format: Article
Language:English
Published: Penerbit Universiti Malaysia Pahang 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/44278/
http://umpir.ump.edu.my/id/eprint/44278/1/The%20Effect%20of%20Diesel_Biodiesel%20Blend%20Ratio%20on%20Physical_Chemical%20Properties.pdf
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author Ying, C. Z.
Maniam, Gaanty Pragas
Nurliyana, Moh Hussin
S. N. M., Khazaai
author_facet Ying, C. Z.
Maniam, Gaanty Pragas
Nurliyana, Moh Hussin
S. N. M., Khazaai
author_sort Ying, C. Z.
building UMP Institutional Repository
collection Online Access
description Biodiesel is a highly sustainable alternative to alleviate fossil fuel shortages and environmental concerns. Many countries have adopted the practice of blending biodiesel into diesel at specific ratios. This study focused on the effect of different biodiesel-diesel blend ratio in terms of acid value, saponification value, peroxide value, and iodine value, and analysed by using Ultraviolet-Visible (UV-Vis) spectroscopy. A series of diesel-biodiesel blends of B20, B40, B60, and B80 were prepared by mixing the biodiesel produced by refined, bleached, and deodorized palm oil through transesterification reaction with pure diesel. Based on the result, the FTIR spectrum showed a slight change in intensity and wavenumber for some possible functional groups but retained the same main characteristic peaks such as C=O, C-O, and OCH3. Predominant compound in biodiesel is oleic acid. Furthermore, acid value, saponification value, iodine value, and peroxide value increased from Euro 5 (B7) to B80 with linear regression (R2) of 0.9817, 0.9971, 0.7521, and 0.9911, respectively. The absence of aromatic compounds in biodiesel causes a decrease in the absorbance of UV light from Euro 5 to B80. Yet, tested parameters were positively accepted according to ASTM - D6751 standard method. Hence, determining the physicochemical properties of blend ratio is vital for industries to counter false claims economically and effectively.
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spelling ump-442782025-04-09T04:15:44Z http://umpir.ump.edu.my/id/eprint/44278/ The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel Ying, C. Z. Maniam, Gaanty Pragas Nurliyana, Moh Hussin S. N. M., Khazaai TP Chemical technology Biodiesel is a highly sustainable alternative to alleviate fossil fuel shortages and environmental concerns. Many countries have adopted the practice of blending biodiesel into diesel at specific ratios. This study focused on the effect of different biodiesel-diesel blend ratio in terms of acid value, saponification value, peroxide value, and iodine value, and analysed by using Ultraviolet-Visible (UV-Vis) spectroscopy. A series of diesel-biodiesel blends of B20, B40, B60, and B80 were prepared by mixing the biodiesel produced by refined, bleached, and deodorized palm oil through transesterification reaction with pure diesel. Based on the result, the FTIR spectrum showed a slight change in intensity and wavenumber for some possible functional groups but retained the same main characteristic peaks such as C=O, C-O, and OCH3. Predominant compound in biodiesel is oleic acid. Furthermore, acid value, saponification value, iodine value, and peroxide value increased from Euro 5 (B7) to B80 with linear regression (R2) of 0.9817, 0.9971, 0.7521, and 0.9911, respectively. The absence of aromatic compounds in biodiesel causes a decrease in the absorbance of UV light from Euro 5 to B80. Yet, tested parameters were positively accepted according to ASTM - D6751 standard method. Hence, determining the physicochemical properties of blend ratio is vital for industries to counter false claims economically and effectively. Penerbit Universiti Malaysia Pahang 2023-12-29 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/44278/1/The%20Effect%20of%20Diesel_Biodiesel%20Blend%20Ratio%20on%20Physical_Chemical%20Properties.pdf Ying, C. Z. and Maniam, Gaanty Pragas and Nurliyana, Moh Hussin and S. N. M., Khazaai (2023) The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel. Current Science and Technology (CST), 3 (2). pp. 30-35. ISSN 2785-8804. (Published) https://doi.org/10.15282/cst.v3i2.10710 https://doi.org/10.15282/cst.v3i2.10710
spellingShingle TP Chemical technology
Ying, C. Z.
Maniam, Gaanty Pragas
Nurliyana, Moh Hussin
S. N. M., Khazaai
The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
title The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
title_full The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
title_fullStr The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
title_full_unstemmed The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
title_short The effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
title_sort effect of diesel/biodiesel blend ratio on physical-chemical properties of biodiesel
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/44278/
http://umpir.ump.edu.my/id/eprint/44278/
http://umpir.ump.edu.my/id/eprint/44278/
http://umpir.ump.edu.my/id/eprint/44278/1/The%20Effect%20of%20Diesel_Biodiesel%20Blend%20Ratio%20on%20Physical_Chemical%20Properties.pdf