An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes
In the present work, the effect of SiO2 nanofiller on the electrochemical properties of GPEs prepared from PMMA/PLA has been discussed in detail. Two different systems are examined: PMMA/PLA-LiBOB (System I) and PMMA/PLA-LiBOB-SiO2 (System II). The Cole–Cole plots illustrate a notable reduction in b...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Springer
2024
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/43966/ http://umpir.ump.edu.my/id/eprint/43966/1/An%20enhancement%20on%20electrochemical%20properties%20of%20Li%2B%20ions%20battery.pdf http://umpir.ump.edu.my/id/eprint/43966/2/An%20enhancement%20on%20electrochemical%20properties%20of%20Li%2B%20ions%20battery-based%20PMMA_PLA-LiBOB%20gel%20polymer%20electrolytes_ABS.pdf |
| _version_ | 1848827000928600064 |
|---|---|
| author | Nurhasniza, Mamajan Khan Mohd Zieauddin, Kufian Ahmad Salihin, Samsudin |
| author_facet | Nurhasniza, Mamajan Khan Mohd Zieauddin, Kufian Ahmad Salihin, Samsudin |
| author_sort | Nurhasniza, Mamajan Khan |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | In the present work, the effect of SiO2 nanofiller on the electrochemical properties of GPEs prepared from PMMA/PLA has been discussed in detail. Two different systems are examined: PMMA/PLA-LiBOB (System I) and PMMA/PLA-LiBOB-SiO2 (System II). The Cole–Cole plots illustrate a notable reduction in bulk resistance consequent to the incorporation of SiO2, which results in a substantial improvement in ionic conductivity from 1.69 × 10–6 S cm−1 to 1.37 × 10–3 S cm−1 at ambient temperature, with the peak conductivity identified at 6 wt.% SiO2. The dielectric analysis reveals that SiO2 markedly augmented both the dielectric constant and dielectric loss, attributable to its elevated polarizability and the contributions from space charge polarization. Linear Sweep Voltammetry (LSV) measurements indicate voltage stability of 4.1 V for System I and 4.7 V for System II. Electrochemical performance comparisons demonstrate that System II outperforms System I in terms of stability and cycling performance, with differential capacity analysis further confirming the positive impact of SiO2 nanofiller on electrochemical activity. |
| first_indexed | 2025-11-15T03:53:46Z |
| format | Article |
| id | ump-43966 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:53:46Z |
| publishDate | 2024 |
| publisher | Springer |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-439662025-03-03T03:43:00Z http://umpir.ump.edu.my/id/eprint/43966/ An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes Nurhasniza, Mamajan Khan Mohd Zieauddin, Kufian Ahmad Salihin, Samsudin HD Industries. Land use. Labor Q Science (General) T Technology (General) In the present work, the effect of SiO2 nanofiller on the electrochemical properties of GPEs prepared from PMMA/PLA has been discussed in detail. Two different systems are examined: PMMA/PLA-LiBOB (System I) and PMMA/PLA-LiBOB-SiO2 (System II). The Cole–Cole plots illustrate a notable reduction in bulk resistance consequent to the incorporation of SiO2, which results in a substantial improvement in ionic conductivity from 1.69 × 10–6 S cm−1 to 1.37 × 10–3 S cm−1 at ambient temperature, with the peak conductivity identified at 6 wt.% SiO2. The dielectric analysis reveals that SiO2 markedly augmented both the dielectric constant and dielectric loss, attributable to its elevated polarizability and the contributions from space charge polarization. Linear Sweep Voltammetry (LSV) measurements indicate voltage stability of 4.1 V for System I and 4.7 V for System II. Electrochemical performance comparisons demonstrate that System II outperforms System I in terms of stability and cycling performance, with differential capacity analysis further confirming the positive impact of SiO2 nanofiller on electrochemical activity. Springer 2024-12 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/43966/1/An%20enhancement%20on%20electrochemical%20properties%20of%20Li%2B%20ions%20battery.pdf pdf en http://umpir.ump.edu.my/id/eprint/43966/2/An%20enhancement%20on%20electrochemical%20properties%20of%20Li%2B%20ions%20battery-based%20PMMA_PLA-LiBOB%20gel%20polymer%20electrolytes_ABS.pdf Nurhasniza, Mamajan Khan and Mohd Zieauddin, Kufian and Ahmad Salihin, Samsudin (2024) An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes. Journal of Materials Science: Materials in Electronics, 35 (2205). pp. 1-15. ISSN 0957-4522. (Published) https://doi.org/10.1007/s10854-024-13946-x https://doi.org/10.1007/s10854-024-13946-x |
| spellingShingle | HD Industries. Land use. Labor Q Science (General) T Technology (General) Nurhasniza, Mamajan Khan Mohd Zieauddin, Kufian Ahmad Salihin, Samsudin An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes |
| title | An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes |
| title_full | An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes |
| title_fullStr | An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes |
| title_full_unstemmed | An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes |
| title_short | An enhancement on electrochemical properties of Li+ ions battery-based PMMA/PLA-LiBOB gel polymer electrolytes |
| title_sort | enhancement on electrochemical properties of li+ ions battery-based pmma/pla-libob gel polymer electrolytes |
| topic | HD Industries. Land use. Labor Q Science (General) T Technology (General) |
| url | http://umpir.ump.edu.my/id/eprint/43966/ http://umpir.ump.edu.my/id/eprint/43966/ http://umpir.ump.edu.my/id/eprint/43966/ http://umpir.ump.edu.my/id/eprint/43966/1/An%20enhancement%20on%20electrochemical%20properties%20of%20Li%2B%20ions%20battery.pdf http://umpir.ump.edu.my/id/eprint/43966/2/An%20enhancement%20on%20electrochemical%20properties%20of%20Li%2B%20ions%20battery-based%20PMMA_PLA-LiBOB%20gel%20polymer%20electrolytes_ABS.pdf |