Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers

Nowadays, thermoset polymers stand out as notable composites, but the surge in global thermoplastic production has raised concerns due to the non-recyclability of these composites, leading to an increase in landfill waste. In response to these challenges, researchers are investigating innovative app...

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Main Authors: Madduluri, Venkata Rao, Bendi, Anjaneyulu, Chinmay,, Maniam, Gaanty Pragas, Rasidi, Roslan, Mohd Hasbi, Ab Rahim
Format: Article
Language:English
English
Published: Springer 2025
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/43881/
http://umpir.ump.edu.my/id/eprint/43881/1/Recent%20advances%20in%20vitrimers.pdf
http://umpir.ump.edu.my/id/eprint/43881/2/Recent%20advances%20in%20vitrimers_A%20detailed%20study%20on%20the%20synthesis%2C%20properties%20and%20applications%20of%20bio-vitrimers_ABS.pdf
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author Madduluri, Venkata Rao
Bendi, Anjaneyulu
Chinmay, ,
Maniam, Gaanty Pragas
Rasidi, Roslan
Mohd Hasbi, Ab Rahim
author_facet Madduluri, Venkata Rao
Bendi, Anjaneyulu
Chinmay, ,
Maniam, Gaanty Pragas
Rasidi, Roslan
Mohd Hasbi, Ab Rahim
author_sort Madduluri, Venkata Rao
building UMP Institutional Repository
collection Online Access
description Nowadays, thermoset polymers stand out as notable composites, but the surge in global thermoplastic production has raised concerns due to the non-recyclability of these composites, leading to an increase in landfill waste. In response to these challenges, researchers are investigating innovative approaches to enhance thermosetting materials, focusing on the modification of crosslinking agents responsible for forming a covalently bonded network. Vitrimers offer a promising solution by enabling re-processability while maintaining favourable thermo mechanical properties and solvent resistance. Although many current vitrimers use synthetic polymeric molecules from fossil-based sources, there is a growing interest in bio-based vitrimers. While still in early development, these bio-based alternatives leverage biomass for creating durable polymers, aligning with the goal of establishing a circular economy. This review has been designed to highlight the use of covalently modified networks to produce advanced synthetic and bio-based vitrimer composites with diverse applications, contributing to the development of sustainable materials for the next generation through the use of recyclable resources and renewable feedstocks in polymer network synthesis. This review also explores vitrimers, examining their unique characteristics and addressing current limitations hindering their widespread adoption as recyclable materials with superior performance.
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language English
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publishDate 2025
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spelling ump-438812025-02-20T08:53:24Z http://umpir.ump.edu.my/id/eprint/43881/ Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers Madduluri, Venkata Rao Bendi, Anjaneyulu Chinmay, , Maniam, Gaanty Pragas Rasidi, Roslan Mohd Hasbi, Ab Rahim HD Industries. Land use. Labor Q Science (General) T Technology (General) Nowadays, thermoset polymers stand out as notable composites, but the surge in global thermoplastic production has raised concerns due to the non-recyclability of these composites, leading to an increase in landfill waste. In response to these challenges, researchers are investigating innovative approaches to enhance thermosetting materials, focusing on the modification of crosslinking agents responsible for forming a covalently bonded network. Vitrimers offer a promising solution by enabling re-processability while maintaining favourable thermo mechanical properties and solvent resistance. Although many current vitrimers use synthetic polymeric molecules from fossil-based sources, there is a growing interest in bio-based vitrimers. While still in early development, these bio-based alternatives leverage biomass for creating durable polymers, aligning with the goal of establishing a circular economy. This review has been designed to highlight the use of covalently modified networks to produce advanced synthetic and bio-based vitrimer composites with diverse applications, contributing to the development of sustainable materials for the next generation through the use of recyclable resources and renewable feedstocks in polymer network synthesis. This review also explores vitrimers, examining their unique characteristics and addressing current limitations hindering their widespread adoption as recyclable materials with superior performance. Springer 2025 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/43881/1/Recent%20advances%20in%20vitrimers.pdf pdf en http://umpir.ump.edu.my/id/eprint/43881/2/Recent%20advances%20in%20vitrimers_A%20detailed%20study%20on%20the%20synthesis%2C%20properties%20and%20applications%20of%20bio-vitrimers_ABS.pdf Madduluri, Venkata Rao and Bendi, Anjaneyulu and Chinmay, , and Maniam, Gaanty Pragas and Rasidi, Roslan and Mohd Hasbi, Ab Rahim (2025) Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers. Journal of Polymers and the Environment, 33 (1). pp. 301-322. ISSN 1566-2543. (Published) https://doi.org/10.1007/s10924-024-03416-0 https://doi.org/10.1007/s10924-024-03416-0
spellingShingle HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
Madduluri, Venkata Rao
Bendi, Anjaneyulu
Chinmay, ,
Maniam, Gaanty Pragas
Rasidi, Roslan
Mohd Hasbi, Ab Rahim
Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers
title Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers
title_full Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers
title_fullStr Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers
title_full_unstemmed Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers
title_short Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers
title_sort recent advances in vitrimers: a detailed study on the synthesis, properties and applications of bio-vitrimers
topic HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
url http://umpir.ump.edu.my/id/eprint/43881/
http://umpir.ump.edu.my/id/eprint/43881/
http://umpir.ump.edu.my/id/eprint/43881/
http://umpir.ump.edu.my/id/eprint/43881/1/Recent%20advances%20in%20vitrimers.pdf
http://umpir.ump.edu.my/id/eprint/43881/2/Recent%20advances%20in%20vitrimers_A%20detailed%20study%20on%20the%20synthesis%2C%20properties%20and%20applications%20of%20bio-vitrimers_ABS.pdf