Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications

In this study, tin (Sn)-doped zinc oxide (ZnO) nanorod arrays (SZO) were prepared using a sonication assisted sol-gel immersion method, with the growth of the nanorod arrays controlled by varying the immersion time in the precursor material. Morphology images taken using a Field Emission Scanning El...

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Main Authors: Ahmad Syakirin, Ismail @ Rosdi, Mohamad Hafiz, Mamat, Ruziana, Mohamed, Embong, Z., Kossar, Shahnaz
Format: Article
Language:English
English
Published: Elsevier Ltd 2025
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/43817/
http://umpir.ump.edu.my/id/eprint/43817/1/Unveiling%20the%20importance%20of%20controllable%20growth%20of%20c-axis%20oriented.pdf
http://umpir.ump.edu.my/id/eprint/43817/2/Unveiling%20the%20importance%20of%20controllable%20growth%20of%20c-axis%20oriented%20Sn-doped%20ZnO%20nanorod%20arrays_Towards%20humidity%20sensing%20applications_ABS.pdf
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author Ahmad Syakirin, Ismail @ Rosdi
Mohamad Hafiz, Mamat
Ruziana, Mohamed
Embong, Z.
Kossar, Shahnaz
author_facet Ahmad Syakirin, Ismail @ Rosdi
Mohamad Hafiz, Mamat
Ruziana, Mohamed
Embong, Z.
Kossar, Shahnaz
author_sort Ahmad Syakirin, Ismail @ Rosdi
building UMP Institutional Repository
collection Online Access
description In this study, tin (Sn)-doped zinc oxide (ZnO) nanorod arrays (SZO) were prepared using a sonication assisted sol-gel immersion method, with the growth of the nanorod arrays controlled by varying the immersion time in the precursor material. Morphology images taken using a Field Emission Scanning Electron Microscope (FESEM) demonstrated an enlargement of the average diameter of the nanorod arrays from 55 nm at 5 min immersion to 122 nm at 200 min immersion. The cross-sectional and surface elemental analysis showed that the sample immersed for 60 min has the highest detection of Sn, with a bulk concentration of 1.8 at.% and surface concentration of 1 at.%. Interestingly, we noticed that Sn is not exist on the surface of 200 min immersion, indicating the depletion of the Sn precursor due to the prolongation of the immersion time. From the current voltage (I-V) analysis, 60 min immersion sample generated the lowest thin film resistivity, which engendered the best humidity sensitivity of 4.05. This study demonstrated the significant importance of optimizing the immersion or growth time for doped 1-D nanostructures to obtain the best humidity sensing performance.
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institution Universiti Malaysia Pahang
institution_category Local University
language English
English
last_indexed 2025-11-15T03:53:12Z
publishDate 2025
publisher Elsevier Ltd
recordtype eprints
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spelling ump-438172025-02-13T08:39:21Z http://umpir.ump.edu.my/id/eprint/43817/ Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications Ahmad Syakirin, Ismail @ Rosdi Mohamad Hafiz, Mamat Ruziana, Mohamed Embong, Z. Kossar, Shahnaz T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TK Electrical engineering. Electronics Nuclear engineering TS Manufactures In this study, tin (Sn)-doped zinc oxide (ZnO) nanorod arrays (SZO) were prepared using a sonication assisted sol-gel immersion method, with the growth of the nanorod arrays controlled by varying the immersion time in the precursor material. Morphology images taken using a Field Emission Scanning Electron Microscope (FESEM) demonstrated an enlargement of the average diameter of the nanorod arrays from 55 nm at 5 min immersion to 122 nm at 200 min immersion. The cross-sectional and surface elemental analysis showed that the sample immersed for 60 min has the highest detection of Sn, with a bulk concentration of 1.8 at.% and surface concentration of 1 at.%. Interestingly, we noticed that Sn is not exist on the surface of 200 min immersion, indicating the depletion of the Sn precursor due to the prolongation of the immersion time. From the current voltage (I-V) analysis, 60 min immersion sample generated the lowest thin film resistivity, which engendered the best humidity sensitivity of 4.05. This study demonstrated the significant importance of optimizing the immersion or growth time for doped 1-D nanostructures to obtain the best humidity sensing performance. Elsevier Ltd 2025 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/43817/1/Unveiling%20the%20importance%20of%20controllable%20growth%20of%20c-axis%20oriented.pdf pdf en http://umpir.ump.edu.my/id/eprint/43817/2/Unveiling%20the%20importance%20of%20controllable%20growth%20of%20c-axis%20oriented%20Sn-doped%20ZnO%20nanorod%20arrays_Towards%20humidity%20sensing%20applications_ABS.pdf Ahmad Syakirin, Ismail @ Rosdi and Mohamad Hafiz, Mamat and Ruziana, Mohamed and Embong, Z. and Kossar, Shahnaz (2025) Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications. Ceramics International, 51 (4). pp. 4487-4499. ISSN 0272-8842. (Published) https://doi.org/10.1016/j.ceramint.2024.11.424 https://doi.org/10.1016/j.ceramint.2024.11.424
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
TS Manufactures
Ahmad Syakirin, Ismail @ Rosdi
Mohamad Hafiz, Mamat
Ruziana, Mohamed
Embong, Z.
Kossar, Shahnaz
Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications
title Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications
title_full Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications
title_fullStr Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications
title_full_unstemmed Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications
title_short Unveiling the importance of controllable growth of c-axis oriented Sn-doped ZnO nanorod arrays: Towards humidity sensing applications
title_sort unveiling the importance of controllable growth of c-axis oriented sn-doped zno nanorod arrays: towards humidity sensing applications
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TK Electrical engineering. Electronics Nuclear engineering
TS Manufactures
url http://umpir.ump.edu.my/id/eprint/43817/
http://umpir.ump.edu.my/id/eprint/43817/
http://umpir.ump.edu.my/id/eprint/43817/
http://umpir.ump.edu.my/id/eprint/43817/1/Unveiling%20the%20importance%20of%20controllable%20growth%20of%20c-axis%20oriented.pdf
http://umpir.ump.edu.my/id/eprint/43817/2/Unveiling%20the%20importance%20of%20controllable%20growth%20of%20c-axis%20oriented%20Sn-doped%20ZnO%20nanorod%20arrays_Towards%20humidity%20sensing%20applications_ABS.pdf