Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges

Perovskite solar cells (PSCs) have appeared as a growing photovoltaic technology owing to their unprecedented performance compared to the market leader, silicon solar cells. The high efficiency (η) of 26 % within a decade brings hope for the photovoltaic community. However, their operational stabili...

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Main Authors: Wali, Qamar, Aamir, Muhammad, Ejaz Khan, Muhammad, Jose, Rajan, Fan, Wei, Yang, Shengyuan
Format: Article
Language:English
English
Published: Elsevier Ltd 2024
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/43126/
http://umpir.ump.edu.my/id/eprint/43126/1/Tin%20oxide%20as%20an%20electron%20transport%20layer%20in%20perovskite%20solar%20cells_ABST.pdf
http://umpir.ump.edu.my/id/eprint/43126/2/Tin%20oxide%20as%20an%20electron%20transport%20layer%20in%20perovskite%20solar%20cells.pdf
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author Wali, Qamar
Aamir, Muhammad
Ejaz Khan, Muhammad
Jose, Rajan
Fan, Wei
Yang, Shengyuan
author_facet Wali, Qamar
Aamir, Muhammad
Ejaz Khan, Muhammad
Jose, Rajan
Fan, Wei
Yang, Shengyuan
author_sort Wali, Qamar
building UMP Institutional Repository
collection Online Access
description Perovskite solar cells (PSCs) have appeared as a growing photovoltaic technology owing to their unprecedented performance compared to the market leader, silicon solar cells. The high efficiency (η) of 26 % within a decade brings hope for the photovoltaic community. However, their operational stability remains a critical issue and hinders their commercialization. Charge transport layers play a key role in the stability and overall performance of PSCs. While TiO2 is the most common and successfully employed electron transport layer (ETL), it is neither a very efficient charge extractor at the interfaces nor stable under UV illumination. Alternatively, another promising ETL, such as SnO2, has recently emerged, producing remarkable performance in PSCs. The outstanding performance in SnO2-based ETL is owing to its extraordinary properties, such as its better band alignment with common perovskite material and higher mobility while being processable at low temperatures (∼150 °C). The best reported result with η = 25.4 % for SnO2 ETL has been achieved so far, comparable to that of the most employed ETL-based TiO2 (η = 26 %). In this review, recent progresses in SnO2-based PSCs with η greater than 20 % and stability (>1000 h) are summarized together with a discussion on associated challenges and opportunities, with an emphasis on the road ahead for commercialization.
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spelling ump-431262024-12-11T04:22:39Z http://umpir.ump.edu.my/id/eprint/43126/ Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges Wali, Qamar Aamir, Muhammad Ejaz Khan, Muhammad Jose, Rajan Fan, Wei Yang, Shengyuan Q Science (General) TA Engineering (General). Civil engineering (General) TK Electrical engineering. Electronics Nuclear engineering Perovskite solar cells (PSCs) have appeared as a growing photovoltaic technology owing to their unprecedented performance compared to the market leader, silicon solar cells. The high efficiency (η) of 26 % within a decade brings hope for the photovoltaic community. However, their operational stability remains a critical issue and hinders their commercialization. Charge transport layers play a key role in the stability and overall performance of PSCs. While TiO2 is the most common and successfully employed electron transport layer (ETL), it is neither a very efficient charge extractor at the interfaces nor stable under UV illumination. Alternatively, another promising ETL, such as SnO2, has recently emerged, producing remarkable performance in PSCs. The outstanding performance in SnO2-based ETL is owing to its extraordinary properties, such as its better band alignment with common perovskite material and higher mobility while being processable at low temperatures (∼150 °C). The best reported result with η = 25.4 % for SnO2 ETL has been achieved so far, comparable to that of the most employed ETL-based TiO2 (η = 26 %). In this review, recent progresses in SnO2-based PSCs with η greater than 20 % and stability (>1000 h) are summarized together with a discussion on associated challenges and opportunities, with an emphasis on the road ahead for commercialization. Elsevier Ltd 2024-03-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/43126/1/Tin%20oxide%20as%20an%20electron%20transport%20layer%20in%20perovskite%20solar%20cells_ABST.pdf pdf en http://umpir.ump.edu.my/id/eprint/43126/2/Tin%20oxide%20as%20an%20electron%20transport%20layer%20in%20perovskite%20solar%20cells.pdf Wali, Qamar and Aamir, Muhammad and Ejaz Khan, Muhammad and Jose, Rajan and Fan, Wei and Yang, Shengyuan (2024) Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges. Solar Energy, 270 (112382). pp. 1-20. ISSN 0038-092X. (Published) https://doi.org/10.1016/j.solener.2024.112382 https://doi.org/10.1016/j.solener.2024.112382
spellingShingle Q Science (General)
TA Engineering (General). Civil engineering (General)
TK Electrical engineering. Electronics Nuclear engineering
Wali, Qamar
Aamir, Muhammad
Ejaz Khan, Muhammad
Jose, Rajan
Fan, Wei
Yang, Shengyuan
Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges
title Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges
title_full Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges
title_fullStr Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges
title_full_unstemmed Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges
title_short Tin oxide as an electron transport layer in perovskite solar cells: Advances and challenges
title_sort tin oxide as an electron transport layer in perovskite solar cells: advances and challenges
topic Q Science (General)
TA Engineering (General). Civil engineering (General)
TK Electrical engineering. Electronics Nuclear engineering
url http://umpir.ump.edu.my/id/eprint/43126/
http://umpir.ump.edu.my/id/eprint/43126/
http://umpir.ump.edu.my/id/eprint/43126/
http://umpir.ump.edu.my/id/eprint/43126/1/Tin%20oxide%20as%20an%20electron%20transport%20layer%20in%20perovskite%20solar%20cells_ABST.pdf
http://umpir.ump.edu.my/id/eprint/43126/2/Tin%20oxide%20as%20an%20electron%20transport%20layer%20in%20perovskite%20solar%20cells.pdf