Lithium-ion adsorption on surface modified porous carbon
Lithium-ion storage in porous carbon electrodes offers challenges due to poor electrode kinetics and limited storability. In this article, we demonstrate improved lithium-ion storage kinetics and rate capability in carbon electrode with appropriate surface or void modifications. The surface of porou...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English English |
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Elsevier Ltd
2023
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| Online Access: | http://umpir.ump.edu.my/id/eprint/41470/ http://umpir.ump.edu.my/id/eprint/41470/1/Lithium-ion%20adsorption%20on%20surface.pdf http://umpir.ump.edu.my/id/eprint/41470/2/Lithium-ion%20adsorption%20on%20surface%20modified%20porous%20carbon.pdf |
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| author | Vijayan, Bincy Lathakumary Amina, Yasin Izan Izwan, Misnon Karuppiah, Chelladurai Yang, Chun-Chen Rajan, Jose |
| author_facet | Vijayan, Bincy Lathakumary Amina, Yasin Izan Izwan, Misnon Karuppiah, Chelladurai Yang, Chun-Chen Rajan, Jose |
| author_sort | Vijayan, Bincy Lathakumary |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Lithium-ion storage in porous carbon electrodes offers challenges due to poor electrode kinetics and limited storability. In this article, we demonstrate improved lithium-ion storage kinetics and rate capability in carbon electrode with appropriate surface or void modifications. The surface of porous carbon is modified by developing a thin film of either a metal oxide (Mn2O3) or a metal (cobalt) or the large voids in them are filled using hierarchical MnCo2O4 or TiO2 nanoflowers. Lithium-ion capacitors are fabricated in the Carbon//LiPF6//Li configuration and evaluated their lithium storage performance using cyclic voltammetry, galvanostatic charge discharge cycling, and electrochemical impedance spectroscopy. While the surface or void modification nominally increased the specific capacitance, the potential window and rate capability of the resulting devices remarkably increased. Among all the tested devices, the MnCo2O4 flowers filled electrode showed the largest capacitance and capacity retention, which are ascribed to its lower lithium transfer resistance. |
| first_indexed | 2025-11-15T03:43:19Z |
| format | Article |
| id | ump-41470 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:43:19Z |
| publishDate | 2023 |
| publisher | Elsevier Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-414702024-06-05T08:56:25Z http://umpir.ump.edu.my/id/eprint/41470/ Lithium-ion adsorption on surface modified porous carbon Vijayan, Bincy Lathakumary Amina, Yasin Izan Izwan, Misnon Karuppiah, Chelladurai Yang, Chun-Chen Rajan, Jose HD28 Management. Industrial Management Lithium-ion storage in porous carbon electrodes offers challenges due to poor electrode kinetics and limited storability. In this article, we demonstrate improved lithium-ion storage kinetics and rate capability in carbon electrode with appropriate surface or void modifications. The surface of porous carbon is modified by developing a thin film of either a metal oxide (Mn2O3) or a metal (cobalt) or the large voids in them are filled using hierarchical MnCo2O4 or TiO2 nanoflowers. Lithium-ion capacitors are fabricated in the Carbon//LiPF6//Li configuration and evaluated their lithium storage performance using cyclic voltammetry, galvanostatic charge discharge cycling, and electrochemical impedance spectroscopy. While the surface or void modification nominally increased the specific capacitance, the potential window and rate capability of the resulting devices remarkably increased. Among all the tested devices, the MnCo2O4 flowers filled electrode showed the largest capacitance and capacity retention, which are ascribed to its lower lithium transfer resistance. Elsevier Ltd 2023 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/41470/1/Lithium-ion%20adsorption%20on%20surface.pdf pdf en http://umpir.ump.edu.my/id/eprint/41470/2/Lithium-ion%20adsorption%20on%20surface%20modified%20porous%20carbon.pdf Vijayan, Bincy Lathakumary and Amina, Yasin and Izan Izwan, Misnon and Karuppiah, Chelladurai and Yang, Chun-Chen and Rajan, Jose (2023) Lithium-ion adsorption on surface modified porous carbon. Journal of Energy Storage, 71 (108221). pp. 1-10. ISSN 2352-152X. (Published) https://doi.org/10.1016/j.est.2023.108221 10.1016/j.est.2023.108221 |
| spellingShingle | HD28 Management. Industrial Management Vijayan, Bincy Lathakumary Amina, Yasin Izan Izwan, Misnon Karuppiah, Chelladurai Yang, Chun-Chen Rajan, Jose Lithium-ion adsorption on surface modified porous carbon |
| title | Lithium-ion adsorption on surface modified porous carbon |
| title_full | Lithium-ion adsorption on surface modified porous carbon |
| title_fullStr | Lithium-ion adsorption on surface modified porous carbon |
| title_full_unstemmed | Lithium-ion adsorption on surface modified porous carbon |
| title_short | Lithium-ion adsorption on surface modified porous carbon |
| title_sort | lithium-ion adsorption on surface modified porous carbon |
| topic | HD28 Management. Industrial Management |
| url | http://umpir.ump.edu.my/id/eprint/41470/ http://umpir.ump.edu.my/id/eprint/41470/ http://umpir.ump.edu.my/id/eprint/41470/ http://umpir.ump.edu.my/id/eprint/41470/1/Lithium-ion%20adsorption%20on%20surface.pdf http://umpir.ump.edu.my/id/eprint/41470/2/Lithium-ion%20adsorption%20on%20surface%20modified%20porous%20carbon.pdf |