Pseudocapacitive performance of phenothiazine functionalized graphene aerogel

This study utilizes light adsorbing molecule, phenothiazine (PTZ) to reduce graphene oxide (GO) and functionalize into PTZ-rGO aerogel (PTZ-rGO). The UV excited PTZ reduces GO via electron transfer while PTZ is simultaneously oxidized and functionalized onto rGO to produce PTZ-rGO aerogel. The optim...

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Main Authors: Lee, Soon Poh, Ali, Gomaa A.M., Assiri, Mohammed Ali, Kong, Kien Voon, Teo, Ellie Yi Lih, Chong, Kwok Feng
Format: Article
Language:English
English
Published: Elsevier B.V. 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/40731/
http://umpir.ump.edu.my/id/eprint/40731/1/Pseudocapacitive%20performance%20of%20phenothiazine%20functionalized.pdf
http://umpir.ump.edu.my/id/eprint/40731/2/Pseudocapacitive%20performance%20of%20phenothiazine%20functionalized_ABS.pdf
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author Lee, Soon Poh
Ali, Gomaa A.M.
Assiri, Mohammed Ali
Kong, Kien Voon
Teo, Ellie Yi Lih
Chong, Kwok Feng
author_facet Lee, Soon Poh
Ali, Gomaa A.M.
Assiri, Mohammed Ali
Kong, Kien Voon
Teo, Ellie Yi Lih
Chong, Kwok Feng
author_sort Lee, Soon Poh
building UMP Institutional Repository
collection Online Access
description This study utilizes light adsorbing molecule, phenothiazine (PTZ) to reduce graphene oxide (GO) and functionalize into PTZ-rGO aerogel (PTZ-rGO). The UV excited PTZ reduces GO via electron transfer while PTZ is simultaneously oxidized and functionalized onto rGO to produce PTZ-rGO aerogel. The optimum incorporation of PTZ on rGO sheets renders good electrochemical active surface area of 495.71 m2 g−1 and enhances the diffusion behavior up to 41.92%. This pseudocapacitive effect and the excellent surface property provide promising charge storage results of 235.5 F g−1 at 0.5 A g−1. Furthermore, the stable charge-discharge cycles with 92% capacitance retention after 10,000 cycles render it an excellent electrode material for supercapacitor fabrication.
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institution Universiti Malaysia Pahang
institution_category Local University
language English
English
last_indexed 2025-11-15T03:39:56Z
publishDate 2023
publisher Elsevier B.V.
recordtype eprints
repository_type Digital Repository
spelling ump-407312024-05-28T07:54:49Z http://umpir.ump.edu.my/id/eprint/40731/ Pseudocapacitive performance of phenothiazine functionalized graphene aerogel Lee, Soon Poh Ali, Gomaa A.M. Assiri, Mohammed Ali Kong, Kien Voon Teo, Ellie Yi Lih Chong, Kwok Feng HD Industries. Land use. Labor Q Science (General) T Technology (General) This study utilizes light adsorbing molecule, phenothiazine (PTZ) to reduce graphene oxide (GO) and functionalize into PTZ-rGO aerogel (PTZ-rGO). The UV excited PTZ reduces GO via electron transfer while PTZ is simultaneously oxidized and functionalized onto rGO to produce PTZ-rGO aerogel. The optimum incorporation of PTZ on rGO sheets renders good electrochemical active surface area of 495.71 m2 g−1 and enhances the diffusion behavior up to 41.92%. This pseudocapacitive effect and the excellent surface property provide promising charge storage results of 235.5 F g−1 at 0.5 A g−1. Furthermore, the stable charge-discharge cycles with 92% capacitance retention after 10,000 cycles render it an excellent electrode material for supercapacitor fabrication. Elsevier B.V. 2023-03-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40731/1/Pseudocapacitive%20performance%20of%20phenothiazine%20functionalized.pdf pdf en http://umpir.ump.edu.my/id/eprint/40731/2/Pseudocapacitive%20performance%20of%20phenothiazine%20functionalized_ABS.pdf Lee, Soon Poh and Ali, Gomaa A.M. and Assiri, Mohammed Ali and Kong, Kien Voon and Teo, Ellie Yi Lih and Chong, Kwok Feng (2023) Pseudocapacitive performance of phenothiazine functionalized graphene aerogel. Applied Surface Science, 613 (156069). pp. 1-11. ISSN 0169-4332. (Published) https://doi.org/10.1016/j.apsusc.2022.156069 https://doi.org/10.1016/j.apsusc.2022.156069
spellingShingle HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
Lee, Soon Poh
Ali, Gomaa A.M.
Assiri, Mohammed Ali
Kong, Kien Voon
Teo, Ellie Yi Lih
Chong, Kwok Feng
Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
title Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
title_full Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
title_fullStr Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
title_full_unstemmed Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
title_short Pseudocapacitive performance of phenothiazine functionalized graphene aerogel
title_sort pseudocapacitive performance of phenothiazine functionalized graphene aerogel
topic HD Industries. Land use. Labor
Q Science (General)
T Technology (General)
url http://umpir.ump.edu.my/id/eprint/40731/
http://umpir.ump.edu.my/id/eprint/40731/
http://umpir.ump.edu.my/id/eprint/40731/
http://umpir.ump.edu.my/id/eprint/40731/1/Pseudocapacitive%20performance%20of%20phenothiazine%20functionalized.pdf
http://umpir.ump.edu.my/id/eprint/40731/2/Pseudocapacitive%20performance%20of%20phenothiazine%20functionalized_ABS.pdf