Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender

The accumulation of waste tires in our society is a pressing issue due to their short lifespan and increasing demand. This research delves into effective methods for recycling waste tires, with a particular focus on utilising biopolymers. Polylactic acid (PLA), a completely biodegradable polymer, ha...

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Main Authors: Qasem, Ramzi, Mohd Bijarimi, Mat Piah, Alhadadi, Waleed
Format: Article
Language:English
Published: Universiti Malaysia Pahang 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/40432/
http://umpir.ump.edu.my/id/eprint/40432/1/Mechanical%20thermal%20and%20morphological%20properties%20of%20poly.pdf
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author Qasem, Ramzi
Mohd Bijarimi, Mat Piah
Alhadadi, Waleed
author_facet Qasem, Ramzi
Mohd Bijarimi, Mat Piah
Alhadadi, Waleed
author_sort Qasem, Ramzi
building UMP Institutional Repository
collection Online Access
description The accumulation of waste tires in our society is a pressing issue due to their short lifespan and increasing demand. This research delves into effective methods for recycling waste tires, with a particular focus on utilising biopolymers. Polylactic acid (PLA), a completely biodegradable polymer, has gained popularity for its biocompatibility, biodegradability, mechanical strength, and ease of processing. To overcome its toughness and thermal stability limitations, PLA has been blended with commercial polymers, such as rubber. Furthermore, the addition of 10% recycled tyre waste to 90% PLA has been shown to increase its durability and strength. Joncryl® ADR is used as a chain extender and reactive compatibiliser to enhance the chemical interactions in the binary blend. The samples were prepared using a twin-screw extruder with the temperature between 150 and 190 ºC and 60 rpm of screw speed. These blends are then analyzed using a range of characterization techniques, including Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), tensile testing, and notched Izod impact testing. The blends were then characterized by chemical changes, thermal transitions, and thermal degradation. It was found that the 90/10/0.6 (PLA/RW/ADR) nanocomposite exhibited maximum thermal degradation.
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spelling ump-404322024-02-19T08:02:10Z http://umpir.ump.edu.my/id/eprint/40432/ Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender Qasem, Ramzi Mohd Bijarimi, Mat Piah Alhadadi, Waleed TP Chemical technology The accumulation of waste tires in our society is a pressing issue due to their short lifespan and increasing demand. This research delves into effective methods for recycling waste tires, with a particular focus on utilising biopolymers. Polylactic acid (PLA), a completely biodegradable polymer, has gained popularity for its biocompatibility, biodegradability, mechanical strength, and ease of processing. To overcome its toughness and thermal stability limitations, PLA has been blended with commercial polymers, such as rubber. Furthermore, the addition of 10% recycled tyre waste to 90% PLA has been shown to increase its durability and strength. Joncryl® ADR is used as a chain extender and reactive compatibiliser to enhance the chemical interactions in the binary blend. The samples were prepared using a twin-screw extruder with the temperature between 150 and 190 ºC and 60 rpm of screw speed. These blends are then analyzed using a range of characterization techniques, including Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), tensile testing, and notched Izod impact testing. The blends were then characterized by chemical changes, thermal transitions, and thermal degradation. It was found that the 90/10/0.6 (PLA/RW/ADR) nanocomposite exhibited maximum thermal degradation. Universiti Malaysia Pahang 2023-12 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/40432/1/Mechanical%20thermal%20and%20morphological%20properties%20of%20poly.pdf Qasem, Ramzi and Mohd Bijarimi, Mat Piah and Alhadadi, Waleed (2023) Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender. Journal of Chemical Engineering and Industrial Biotechnology (JCEIB), 9 (2). pp. 73-79. ISSN 0126-8139. (Published) https://doi.org/10.15282/jceib.v9i2.10008 https://doi.org/10.15282/jceib.v9i2.10008
spellingShingle TP Chemical technology
Qasem, Ramzi
Mohd Bijarimi, Mat Piah
Alhadadi, Waleed
Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender
title Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender
title_full Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender
title_fullStr Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender
title_full_unstemmed Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender
title_short Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender
title_sort mechanical, thermal, and morphological properties of poly(lactic acid) (pla)/ recycled tyre rubber waste compatibilised with chain extender
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/40432/
http://umpir.ump.edu.my/id/eprint/40432/
http://umpir.ump.edu.my/id/eprint/40432/
http://umpir.ump.edu.my/id/eprint/40432/1/Mechanical%20thermal%20and%20morphological%20properties%20of%20poly.pdf