Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating

Synergistic effect composed of graphene oxide (GO) and halloysite (HNT) to serve as a promising anticorrosion performance and to enhance flame retardant (FR) properties of epoxy nanocomposite coating (NC) is studied. Using an epoxy as the matrix, GO/epoxy, HNT/epoxy, and hybrid GO/HNT/epoxy samples...

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Main Authors: Siti Maznah, Kabeb, Azman, Hassan, Zurina, Mohamad, Zalilah, Sharer, Munirah, Mokhtar, Faiz, Ahmad
Format: Article
Language:English
Published: The Italian Association of Chemical Engineering-AIDIC 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/40346/
http://umpir.ump.edu.my/id/eprint/40346/1/2.%20Synergistic%20Effect%20of%20Graphene%20OxideHalloysite%20in%20AnticorrosionPerformance%20and%20FR%20Properties%20of%20Epoxy%20Nanocomposite%20Coating.pdf
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author Siti Maznah, Kabeb
Azman, Hassan
Zurina, Mohamad
Zalilah, Sharer
Munirah, Mokhtar
Faiz, Ahmad
author_facet Siti Maznah, Kabeb
Azman, Hassan
Zurina, Mohamad
Zalilah, Sharer
Munirah, Mokhtar
Faiz, Ahmad
author_sort Siti Maznah, Kabeb
building UMP Institutional Repository
collection Online Access
description Synergistic effect composed of graphene oxide (GO) and halloysite (HNT) to serve as a promising anticorrosion performance and to enhance flame retardant (FR) properties of epoxy nanocomposite coating (NC) is studied. Using an epoxy as the matrix, GO/epoxy, HNT/epoxy, and hybrid GO/HNT/epoxy samples are prepared and the performance is characterized. The hybridization of GO and HNT leads to improve the barrier properties with EGO0.6H0.3 hybrid sample endows optimum synergistic effect. This is due to the improved state of nanofiller dispersion as well as better interfacial adhesion between the nanofillers and matrix which was confirmed by Transmission Electron microscopy (TEM) images. The Salt Spray test (SST) results corresponding to these effects reaffirmed that the corrosion resistance of the hybrid coatings improved with increasing the inorganic phase content. The thermal stability and flammability properties were investigated using Thermogravimetric Analysis (TGA) and Limiting Oxygen Index (LOI). The results of the LOI test showed that the addition of nanofillers marginally increases the LOI value of the epoxy NC. These results manifestly demonstrated that the formation of an efficient hybrid network slightly enhanced the coating performance through the synergy effect of hybrid nanofillers.
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language English
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publishDate 2020
publisher The Italian Association of Chemical Engineering-AIDIC
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spelling ump-403462024-02-14T08:09:05Z http://umpir.ump.edu.my/id/eprint/40346/ Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating Siti Maznah, Kabeb Azman, Hassan Zurina, Mohamad Zalilah, Sharer Munirah, Mokhtar Faiz, Ahmad Q Science (General) QD Chemistry Synergistic effect composed of graphene oxide (GO) and halloysite (HNT) to serve as a promising anticorrosion performance and to enhance flame retardant (FR) properties of epoxy nanocomposite coating (NC) is studied. Using an epoxy as the matrix, GO/epoxy, HNT/epoxy, and hybrid GO/HNT/epoxy samples are prepared and the performance is characterized. The hybridization of GO and HNT leads to improve the barrier properties with EGO0.6H0.3 hybrid sample endows optimum synergistic effect. This is due to the improved state of nanofiller dispersion as well as better interfacial adhesion between the nanofillers and matrix which was confirmed by Transmission Electron microscopy (TEM) images. The Salt Spray test (SST) results corresponding to these effects reaffirmed that the corrosion resistance of the hybrid coatings improved with increasing the inorganic phase content. The thermal stability and flammability properties were investigated using Thermogravimetric Analysis (TGA) and Limiting Oxygen Index (LOI). The results of the LOI test showed that the addition of nanofillers marginally increases the LOI value of the epoxy NC. These results manifestly demonstrated that the formation of an efficient hybrid network slightly enhanced the coating performance through the synergy effect of hybrid nanofillers. The Italian Association of Chemical Engineering-AIDIC 2020 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40346/1/2.%20Synergistic%20Effect%20of%20Graphene%20OxideHalloysite%20in%20AnticorrosionPerformance%20and%20FR%20Properties%20of%20Epoxy%20Nanocomposite%20Coating.pdf Siti Maznah, Kabeb and Azman, Hassan and Zurina, Mohamad and Zalilah, Sharer and Munirah, Mokhtar and Faiz, Ahmad (2020) Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating. CHEMICAL ENGINEERING TRANSACTIONS, 78. pp. 529-534. ISSN 2283-9216. (Published) https://doi.org/10.3303/CET2078089 https://doi.org/10.3303/CET2078089
spellingShingle Q Science (General)
QD Chemistry
Siti Maznah, Kabeb
Azman, Hassan
Zurina, Mohamad
Zalilah, Sharer
Munirah, Mokhtar
Faiz, Ahmad
Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
title Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
title_full Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
title_fullStr Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
title_full_unstemmed Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
title_short Synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
title_sort synergistic effect of graphene oxide/halloysite in anticorrosion performance and flame retardancy properties of epoxy nanocomposite coating
topic Q Science (General)
QD Chemistry
url http://umpir.ump.edu.my/id/eprint/40346/
http://umpir.ump.edu.my/id/eprint/40346/
http://umpir.ump.edu.my/id/eprint/40346/
http://umpir.ump.edu.my/id/eprint/40346/1/2.%20Synergistic%20Effect%20of%20Graphene%20OxideHalloysite%20in%20AnticorrosionPerformance%20and%20FR%20Properties%20of%20Epoxy%20Nanocomposite%20Coating.pdf