Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal

Polysulfone (PSF) membranes blended with cellulose nanocrystals (CNC) and graphene oxide (GO) nanofiller were prepared for copper removal in this study. The impacts of single CNC, GO, and mixed CNC-GO addition on the morphology, hydrophilicity, permeability, copper ion rejection, and membrane bindin...

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Main Authors: Siti Nurul Najiah, Abd Rasid, Nor Azura, Che Mahmud, Syed Mohd, Saufi, Takriff, Mohd Sobri, Ang, Wei Lun
Format: Article
Language:English
Published: Desalination Publications 2022
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/40188/
http://umpir.ump.edu.my/id/eprint/40188/1/Hybrid%20cellulose%20nanocrystals%20and%20graphene%20oxide%20polysulfone.pdf
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author Siti Nurul Najiah, Abd Rasid
Nor Azura, Che Mahmud
Syed Mohd, Saufi
Takriff, Mohd Sobri
Ang, Wei Lun
author_facet Siti Nurul Najiah, Abd Rasid
Nor Azura, Che Mahmud
Syed Mohd, Saufi
Takriff, Mohd Sobri
Ang, Wei Lun
author_sort Siti Nurul Najiah, Abd Rasid
building UMP Institutional Repository
collection Online Access
description Polysulfone (PSF) membranes blended with cellulose nanocrystals (CNC) and graphene oxide (GO) nanofiller were prepared for copper removal in this study. The impacts of single CNC, GO, and mixed CNC-GO addition on the morphology, hydrophilicity, permeability, copper ion rejection, and membrane binding capacity were discussed. Scanning electron microscopy results showed that incorporating CNC, GO, and CNC-GO resulted in a more porous membrane structure with a high porosity value. The hydrophilicity of hybrid CNC-GO-PSF membranes were improved with the increment of CNC content and inclusion of the GO filler. Hybrid membranes showed a significant increment of flux compared to pristine PSF membrane. The water flux of the hybrid P-1GO-2C membrane is 8-fold higher than the pure PSF membrane (3.31 L/m2•h). However, the copper rejection of the hybrid CNC-GO-PSF membranes was less than 50%. The increment of the CNC in the hybrid CNC-GO-PSF membrane increases the membrane porosity, and the sub-layer structure of the membrane is becoming very loose. In adsorptive filtration mode, the GO-PSF membrane showed the highest copper binding capacity of 8.49 mg•Cu/g membrane.
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spelling ump-401882024-02-08T04:41:13Z http://umpir.ump.edu.my/id/eprint/40188/ Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal Siti Nurul Najiah, Abd Rasid Nor Azura, Che Mahmud Syed Mohd, Saufi Takriff, Mohd Sobri Ang, Wei Lun QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Polysulfone (PSF) membranes blended with cellulose nanocrystals (CNC) and graphene oxide (GO) nanofiller were prepared for copper removal in this study. The impacts of single CNC, GO, and mixed CNC-GO addition on the morphology, hydrophilicity, permeability, copper ion rejection, and membrane binding capacity were discussed. Scanning electron microscopy results showed that incorporating CNC, GO, and CNC-GO resulted in a more porous membrane structure with a high porosity value. The hydrophilicity of hybrid CNC-GO-PSF membranes were improved with the increment of CNC content and inclusion of the GO filler. Hybrid membranes showed a significant increment of flux compared to pristine PSF membrane. The water flux of the hybrid P-1GO-2C membrane is 8-fold higher than the pure PSF membrane (3.31 L/m2•h). However, the copper rejection of the hybrid CNC-GO-PSF membranes was less than 50%. The increment of the CNC in the hybrid CNC-GO-PSF membrane increases the membrane porosity, and the sub-layer structure of the membrane is becoming very loose. In adsorptive filtration mode, the GO-PSF membrane showed the highest copper binding capacity of 8.49 mg•Cu/g membrane. Desalination Publications 2022-10 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/40188/1/Hybrid%20cellulose%20nanocrystals%20and%20graphene%20oxide%20polysulfone.pdf Siti Nurul Najiah, Abd Rasid and Nor Azura, Che Mahmud and Syed Mohd, Saufi and Takriff, Mohd Sobri and Ang, Wei Lun (2022) Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal. Desalination and Water Treatment, 274. pp. 39-48. ISSN 1944-3994. (Published) https://doi.org/10.5004/dwt.2022.28912 https://doi.org/10.5004/dwt.2022.28912
spellingShingle QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Siti Nurul Najiah, Abd Rasid
Nor Azura, Che Mahmud
Syed Mohd, Saufi
Takriff, Mohd Sobri
Ang, Wei Lun
Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
title Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
title_full Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
title_fullStr Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
title_full_unstemmed Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
title_short Hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
title_sort hybrid cellulose nanocrystals and graphene oxide polysulfone membranes for copper removal
topic QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/40188/
http://umpir.ump.edu.my/id/eprint/40188/
http://umpir.ump.edu.my/id/eprint/40188/
http://umpir.ump.edu.my/id/eprint/40188/1/Hybrid%20cellulose%20nanocrystals%20and%20graphene%20oxide%20polysulfone.pdf