Metal coordinated macrocyclic complexes in different chemical transformations
Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for designing new molecules with inherently selective properties. Metal coordinated macrocyclic rings are featured with exceptionally stable π-conjugated cyclic systems containing the metal ion in the central cavity. Th...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
Coordination Chemistry Reviews
2022
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| Online Access: | http://umpir.ump.edu.my/id/eprint/39039/ http://umpir.ump.edu.my/id/eprint/39039/1/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations.pdf http://umpir.ump.edu.my/id/eprint/39039/2/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations_ABS.pdf |
| _version_ | 1848825666773975040 |
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| author | Thakur, Maheshwar S. Singh, Neha Sharma, Arti Rana, Rohit Abdul Syukor, Abd Razak Naushad, Mu Kumar, Sunil Kumar, Manish Anil Singh, Lakhveer |
| author_facet | Thakur, Maheshwar S. Singh, Neha Sharma, Arti Rana, Rohit Abdul Syukor, Abd Razak Naushad, Mu Kumar, Sunil Kumar, Manish Anil Singh, Lakhveer |
| author_sort | Thakur, Maheshwar S. |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for designing new molecules with inherently selective properties. Metal coordinated macrocyclic rings are featured with exceptionally stable π-conjugated cyclic systems containing the metal ion in the central cavity. The cyclic tetra dentate framework of the four central nitrogen atoms makes these macrocyclic rings system unique chelating agents, in addition, these conjugated double bonds impart a vital effect in electrons transportation. Because of inimitable characteristics, these metal coordinated macrocyclic compounds have been effectively applied as catalysts in various important organic transformations. Hence, this review portrays the overview of metal coordinated macrocyclic molecules, classifications, and their catalytic application in redox reactions. This comprehensive and up-to-date review is particularly aligned toward the catalytic applications of four types of metal-coordinated macrocyclic rings, i.e., porphyrin, porphyrazine, corrole, and corrolazines, in different organic transformations. The different synthetic approaches for the preparation of metal coordinated macrocyclic rings and their UV spectrums are also outlined in this review. |
| first_indexed | 2025-11-15T03:32:33Z |
| format | Article |
| id | ump-39039 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:32:33Z |
| publishDate | 2022 |
| publisher | Coordination Chemistry Reviews |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-390392023-10-27T02:56:54Z http://umpir.ump.edu.my/id/eprint/39039/ Metal coordinated macrocyclic complexes in different chemical transformations Thakur, Maheshwar S. Singh, Neha Sharma, Arti Rana, Rohit Abdul Syukor, Abd Razak Naushad, Mu Kumar, Sunil Kumar, Manish Anil Singh, Lakhveer T Technology (General) TA Engineering (General). Civil engineering (General) TN Mining engineering. Metallurgy Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for designing new molecules with inherently selective properties. Metal coordinated macrocyclic rings are featured with exceptionally stable π-conjugated cyclic systems containing the metal ion in the central cavity. The cyclic tetra dentate framework of the four central nitrogen atoms makes these macrocyclic rings system unique chelating agents, in addition, these conjugated double bonds impart a vital effect in electrons transportation. Because of inimitable characteristics, these metal coordinated macrocyclic compounds have been effectively applied as catalysts in various important organic transformations. Hence, this review portrays the overview of metal coordinated macrocyclic molecules, classifications, and their catalytic application in redox reactions. This comprehensive and up-to-date review is particularly aligned toward the catalytic applications of four types of metal-coordinated macrocyclic rings, i.e., porphyrin, porphyrazine, corrole, and corrolazines, in different organic transformations. The different synthetic approaches for the preparation of metal coordinated macrocyclic rings and their UV spectrums are also outlined in this review. Coordination Chemistry Reviews 2022-11-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/39039/1/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations.pdf pdf en http://umpir.ump.edu.my/id/eprint/39039/2/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations_ABS.pdf Thakur, Maheshwar S. and Singh, Neha and Sharma, Arti and Rana, Rohit and Abdul Syukor, Abd Razak and Naushad, Mu and Kumar, Sunil and Kumar, Manish Anil and Singh, Lakhveer (2022) Metal coordinated macrocyclic complexes in different chemical transformations. Coordination Chemistry Reviews, 471 (214739). pp. 1-24. ISSN 0010-8545. (Published) https://doi.org/10.1016/j.ccr.2022.214739 https://doi.org/10.1016/j.ccr.2022.214739 |
| spellingShingle | T Technology (General) TA Engineering (General). Civil engineering (General) TN Mining engineering. Metallurgy Thakur, Maheshwar S. Singh, Neha Sharma, Arti Rana, Rohit Abdul Syukor, Abd Razak Naushad, Mu Kumar, Sunil Kumar, Manish Anil Singh, Lakhveer Metal coordinated macrocyclic complexes in different chemical transformations |
| title | Metal coordinated macrocyclic complexes in different chemical transformations |
| title_full | Metal coordinated macrocyclic complexes in different chemical transformations |
| title_fullStr | Metal coordinated macrocyclic complexes in different chemical transformations |
| title_full_unstemmed | Metal coordinated macrocyclic complexes in different chemical transformations |
| title_short | Metal coordinated macrocyclic complexes in different chemical transformations |
| title_sort | metal coordinated macrocyclic complexes in different chemical transformations |
| topic | T Technology (General) TA Engineering (General). Civil engineering (General) TN Mining engineering. Metallurgy |
| url | http://umpir.ump.edu.my/id/eprint/39039/ http://umpir.ump.edu.my/id/eprint/39039/ http://umpir.ump.edu.my/id/eprint/39039/ http://umpir.ump.edu.my/id/eprint/39039/1/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations.pdf http://umpir.ump.edu.my/id/eprint/39039/2/Metal%20coordinated%20macrocyclic%20complexes%20in%20different%20chemical%20transformations_ABS.pdf |