Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation

Thermal oxidation is widely used in substrate surface modification before applying bioceramic coating to enhance implant resistant against corrosion and biocompatibility. In this work, mechanical and microstructural characteristics of a medium-entropy alloy Co61.9Cr29.6Mo6.5C0.24 (in wt.%) was therm...

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Main Authors: Rosdi, Daud, Mas Ayu, Hassan, R., Norizah, A. K., Nasution
Format: Conference or Workshop Item
Language:English
English
Published: Springer Singapore 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/38864/
http://umpir.ump.edu.my/id/eprint/38864/1/Deformation%20Behaviour%20of%20a%20High%20Carbon%20Co.pdf
http://umpir.ump.edu.my/id/eprint/38864/2/Deformation%20Behaviour%20of%20a%20High%20Carbon%20Co%E2%80%93Cr%E2%80%93Mo%20Medium-Entropy%20Alloy%20via%20Thermal%20Oxidation.pdf
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author Rosdi, Daud
Mas Ayu, Hassan
R., Norizah
A. K., Nasution
author_facet Rosdi, Daud
Mas Ayu, Hassan
R., Norizah
A. K., Nasution
author_sort Rosdi, Daud
building UMP Institutional Repository
collection Online Access
description Thermal oxidation is widely used in substrate surface modification before applying bioceramic coating to enhance implant resistant against corrosion and biocompatibility. In this work, mechanical and microstructural characteristics of a medium-entropy alloy Co61.9Cr29.6Mo6.5C0.24 (in wt.%) was thermally oxidize under controlled furnace atmosphere, at 450 °C, 650 °C, 850 °C, 1050 °C and 1250 °C for 3 h. It has been demonstrated that by oxidizing high carbon Co–Cr–Mo alloy can create a reasonably thick, stable and hard Cr2O3 layer on the substrate at 1050 °C. The exchange of substrate colour from silver to brownish and lastly dark green of oxide layer was observed and is evident from the variations of the surface morphology which is also a cause response to the increment of temperature. Within the interval of extremely high temperature considered (1250 °C), the alloy exhibits several unusual features, such as presence of massive porosity with clumpy blended of distinct composition of oxide layer like CoCr2O4 and Co0.8Cr0.2. The results also demonstrate that Cr2O3 layer recede in thickness as the temperature reaches 1250 °C and experienced oxide layer spalling due to bounteous chemosorption of O2 atoms react with dominant elements like cobalt and chromium in the substrate.
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institution Universiti Malaysia Pahang
institution_category Local University
language English
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publishDate 2023
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spelling ump-388642023-10-12T07:51:37Z http://umpir.ump.edu.my/id/eprint/38864/ Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation Rosdi, Daud Mas Ayu, Hassan R., Norizah A. K., Nasution TA Engineering (General). Civil engineering (General) TS Manufactures Thermal oxidation is widely used in substrate surface modification before applying bioceramic coating to enhance implant resistant against corrosion and biocompatibility. In this work, mechanical and microstructural characteristics of a medium-entropy alloy Co61.9Cr29.6Mo6.5C0.24 (in wt.%) was thermally oxidize under controlled furnace atmosphere, at 450 °C, 650 °C, 850 °C, 1050 °C and 1250 °C for 3 h. It has been demonstrated that by oxidizing high carbon Co–Cr–Mo alloy can create a reasonably thick, stable and hard Cr2O3 layer on the substrate at 1050 °C. The exchange of substrate colour from silver to brownish and lastly dark green of oxide layer was observed and is evident from the variations of the surface morphology which is also a cause response to the increment of temperature. Within the interval of extremely high temperature considered (1250 °C), the alloy exhibits several unusual features, such as presence of massive porosity with clumpy blended of distinct composition of oxide layer like CoCr2O4 and Co0.8Cr0.2. The results also demonstrate that Cr2O3 layer recede in thickness as the temperature reaches 1250 °C and experienced oxide layer spalling due to bounteous chemosorption of O2 atoms react with dominant elements like cobalt and chromium in the substrate. Springer Singapore 2023 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/38864/1/Deformation%20Behaviour%20of%20a%20High%20Carbon%20Co.pdf pdf en http://umpir.ump.edu.my/id/eprint/38864/2/Deformation%20Behaviour%20of%20a%20High%20Carbon%20Co%E2%80%93Cr%E2%80%93Mo%20Medium-Entropy%20Alloy%20via%20Thermal%20Oxidation.pdf Rosdi, Daud and Mas Ayu, Hassan and R., Norizah and A. K., Nasution (2023) Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation. In: International Manufacturing Engineering Conference & The Asia Pacific Conference on Manufacturing Systems , 27-28 October 2022 , Surakarta, Indonesia. pp. 649-656.. ISSN 2195-4356 ISBN 978-981-99-1244-5 (Published) https://doi.org/10.1007/978-981-99-1245-2_60
spellingShingle TA Engineering (General). Civil engineering (General)
TS Manufactures
Rosdi, Daud
Mas Ayu, Hassan
R., Norizah
A. K., Nasution
Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation
title Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation
title_full Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation
title_fullStr Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation
title_full_unstemmed Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation
title_short Deformation Behaviour of a High Carbon Co–Cr–Mo Medium-Entropy Alloy via Thermal Oxidation
title_sort deformation behaviour of a high carbon co–cr–mo medium-entropy alloy via thermal oxidation
topic TA Engineering (General). Civil engineering (General)
TS Manufactures
url http://umpir.ump.edu.my/id/eprint/38864/
http://umpir.ump.edu.my/id/eprint/38864/
http://umpir.ump.edu.my/id/eprint/38864/1/Deformation%20Behaviour%20of%20a%20High%20Carbon%20Co.pdf
http://umpir.ump.edu.my/id/eprint/38864/2/Deformation%20Behaviour%20of%20a%20High%20Carbon%20Co%E2%80%93Cr%E2%80%93Mo%20Medium-Entropy%20Alloy%20via%20Thermal%20Oxidation.pdf