Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst
Bi-reforming of methane (BRM) technology has the potential to serve as an alternative energy source while also mitigating greenhouse gas emissions. However, the main hurdle in the commercialization of BRM is catalyst deactivation. In this study, the ultrasonic-assisted impregnation method was utiliz...
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| Format: | Article |
| Language: | English English |
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Springer
2023
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| Online Access: | http://umpir.ump.edu.my/id/eprint/38607/ http://umpir.ump.edu.my/id/eprint/38607/1/Syngas%20production%20via%20bi-reforming%20of%20methane%20Over%20Fibrous%20KCC-1.pdf http://umpir.ump.edu.my/id/eprint/38607/2/Syngas%20production%20via%20bi-reforming%20of%20methane%20over%20fibrous%20KCC-1%20stabilized%20ni%20catalyst_ABS.pdf |
| _version_ | 1848825550870675456 |
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| author | Ahmad Salam, Farooqi Siti Nur Fatihah, Adnan Setiabudi, Herma Dina Syed Anuar Faua’ad d, Sye Muhammad Shahrul, Ismail Aslam, Sameen Bawadi, Abdullah |
| author_facet | Ahmad Salam, Farooqi Siti Nur Fatihah, Adnan Setiabudi, Herma Dina Syed Anuar Faua’ad d, Sye Muhammad Shahrul, Ismail Aslam, Sameen Bawadi, Abdullah |
| author_sort | Ahmad Salam, Farooqi |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Bi-reforming of methane (BRM) technology has the potential to serve as an alternative energy source while also mitigating greenhouse gas emissions. However, the main hurdle in the commercialization of BRM is catalyst deactivation. In this study, the ultrasonic-assisted impregnation method was utilized to prepare a Ni-based catalyst supported on fibrous KCC-1 and tested in the BRM process. The prepared catalysts were characterized by XRD, BET, FESEM and TPR-H2 techniques to determine the textural and morphological properties of the catalyst. The catalytic performance was tested in a tabular fixed-bed continuous reactor at 800 °C with a stoichiometric feed ratio of 3:2:1 for CH4: H2O: CO2. For high nickel loadings, it was discovered that agglomerates of the Ni-active phase form on the surface of the support. The catalysts with a 10 wt% Ni content produced the best CO2 (79.2%) and CH4 (82.1%) conversions, as well as an optimum H2/CO = 1.62 ratio. |
| first_indexed | 2025-11-15T03:30:43Z |
| format | Article |
| id | ump-38607 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:30:43Z |
| publishDate | 2023 |
| publisher | Springer |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-386072023-10-31T08:03:25Z http://umpir.ump.edu.my/id/eprint/38607/ Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst Ahmad Salam, Farooqi Siti Nur Fatihah, Adnan Setiabudi, Herma Dina Syed Anuar Faua’ad d, Sye Muhammad Shahrul, Ismail Aslam, Sameen Bawadi, Abdullah QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Bi-reforming of methane (BRM) technology has the potential to serve as an alternative energy source while also mitigating greenhouse gas emissions. However, the main hurdle in the commercialization of BRM is catalyst deactivation. In this study, the ultrasonic-assisted impregnation method was utilized to prepare a Ni-based catalyst supported on fibrous KCC-1 and tested in the BRM process. The prepared catalysts were characterized by XRD, BET, FESEM and TPR-H2 techniques to determine the textural and morphological properties of the catalyst. The catalytic performance was tested in a tabular fixed-bed continuous reactor at 800 °C with a stoichiometric feed ratio of 3:2:1 for CH4: H2O: CO2. For high nickel loadings, it was discovered that agglomerates of the Ni-active phase form on the surface of the support. The catalysts with a 10 wt% Ni content produced the best CO2 (79.2%) and CH4 (82.1%) conversions, as well as an optimum H2/CO = 1.62 ratio. Springer 2023-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/38607/1/Syngas%20production%20via%20bi-reforming%20of%20methane%20Over%20Fibrous%20KCC-1.pdf pdf en http://umpir.ump.edu.my/id/eprint/38607/2/Syngas%20production%20via%20bi-reforming%20of%20methane%20over%20fibrous%20KCC-1%20stabilized%20ni%20catalyst_ABS.pdf Ahmad Salam, Farooqi and Siti Nur Fatihah, Adnan and Setiabudi, Herma Dina and Syed Anuar Faua’ad d, Sye Muhammad and Shahrul, Ismail and Aslam, Sameen and Bawadi, Abdullah (2023) Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst. Topics in Catalysis, 66 (1-4). pp. 235-246. ISSN 1022-5528. (Published) https://doi.org/10.1007/s11244-022-01713-3 https://doi.org/10.1007/s11244-022-01713-3 |
| spellingShingle | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Ahmad Salam, Farooqi Siti Nur Fatihah, Adnan Setiabudi, Herma Dina Syed Anuar Faua’ad d, Sye Muhammad Shahrul, Ismail Aslam, Sameen Bawadi, Abdullah Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst |
| title | Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst |
| title_full | Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst |
| title_fullStr | Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst |
| title_full_unstemmed | Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst |
| title_short | Syngas production via bi-reforming of methane over fibrous KCC-1 stabilized ni catalyst |
| title_sort | syngas production via bi-reforming of methane over fibrous kcc-1 stabilized ni catalyst |
| topic | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/38607/ http://umpir.ump.edu.my/id/eprint/38607/ http://umpir.ump.edu.my/id/eprint/38607/ http://umpir.ump.edu.my/id/eprint/38607/1/Syngas%20production%20via%20bi-reforming%20of%20methane%20Over%20Fibrous%20KCC-1.pdf http://umpir.ump.edu.my/id/eprint/38607/2/Syngas%20production%20via%20bi-reforming%20of%20methane%20over%20fibrous%20KCC-1%20stabilized%20ni%20catalyst_ABS.pdf |