Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template

Molecularly Imprinted Polymer-Oleic Acid (MIPOA) and Molecularly Imprinted Polymer-Palmitic Acid (MIPPA) were synthesized using oleic acid and palmitic acid as the templates; acetonitrile as the porogenic solvent; and allylthiourea as the monomer; and EDGMA as a crosslinker via bulk polymerization....

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Main Authors: Siti Maizatul Ameera, Azhar, Muyang, Brody Sambang, Gaanty Pragas, Maniam, Nurlin, Abu Samah
Format: Book Chapter
Language:English
Published: Trans Tech Publications Ltd. 2022
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/38045/
http://umpir.ump.edu.my/id/eprint/38045/1/1.jpg
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author Siti Maizatul Ameera, Azhar
Muyang, Brody Sambang
Gaanty Pragas, Maniam
Nurlin, Abu Samah
author_facet Siti Maizatul Ameera, Azhar
Muyang, Brody Sambang
Gaanty Pragas, Maniam
Nurlin, Abu Samah
author_sort Siti Maizatul Ameera, Azhar
building UMP Institutional Repository
collection Online Access
description Molecularly Imprinted Polymer-Oleic Acid (MIPOA) and Molecularly Imprinted Polymer-Palmitic Acid (MIPPA) were synthesized using oleic acid and palmitic acid as the templates; acetonitrile as the porogenic solvent; and allylthiourea as the monomer; and EDGMA as a crosslinker via bulk polymerization. The non-imprinted polymers (NIP) as a control were prepared with the same procedure, but with the absence of template molecule. The synthesized MIPs and NIP were characterized using Fourier Transform Infrared Spectroscopy (FTIR) and the results showed the narrowing of –OH peak which shows that crosslinking has occurred. Field Emission Scanning Electron Microscope-Energy Dispersive X-Ray (FESEM-EDX) was used to analyze the composition of in both MIPs and NIP. The results yielded a composition of C, O, and S. This analysis corresponds to the composition of oleic acid and sulfuric acid as both templates contain -COOH group. These results suggested that the molecularly imprinted polymers can be employed as a potential adsorbent for the removal of oleic acid and palmitic acid from palm fatty acid distillate (PFAD) waste.
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institution Universiti Malaysia Pahang
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language English
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spelling ump-380452023-08-02T08:24:16Z http://umpir.ump.edu.my/id/eprint/38045/ Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template Siti Maizatul Ameera, Azhar Muyang, Brody Sambang Gaanty Pragas, Maniam Nurlin, Abu Samah QD Chemistry Molecularly Imprinted Polymer-Oleic Acid (MIPOA) and Molecularly Imprinted Polymer-Palmitic Acid (MIPPA) were synthesized using oleic acid and palmitic acid as the templates; acetonitrile as the porogenic solvent; and allylthiourea as the monomer; and EDGMA as a crosslinker via bulk polymerization. The non-imprinted polymers (NIP) as a control were prepared with the same procedure, but with the absence of template molecule. The synthesized MIPs and NIP were characterized using Fourier Transform Infrared Spectroscopy (FTIR) and the results showed the narrowing of –OH peak which shows that crosslinking has occurred. Field Emission Scanning Electron Microscope-Energy Dispersive X-Ray (FESEM-EDX) was used to analyze the composition of in both MIPs and NIP. The results yielded a composition of C, O, and S. This analysis corresponds to the composition of oleic acid and sulfuric acid as both templates contain -COOH group. These results suggested that the molecularly imprinted polymers can be employed as a potential adsorbent for the removal of oleic acid and palmitic acid from palm fatty acid distillate (PFAD) waste. Trans Tech Publications Ltd. 2022-10-20 Book Chapter PeerReviewed image en http://umpir.ump.edu.my/id/eprint/38045/1/1.jpg Siti Maizatul Ameera, Azhar and Muyang, Brody Sambang and Gaanty Pragas, Maniam and Nurlin, Abu Samah (2022) Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template. In: Key Engineering Materials. Trans Tech Publications Ltd., pp. 71-76. ISBN 10139826 https://doi.org/10.4028/p-9l60lo https://doi.org/10.4028/p-9l60lo
spellingShingle QD Chemistry
Siti Maizatul Ameera, Azhar
Muyang, Brody Sambang
Gaanty Pragas, Maniam
Nurlin, Abu Samah
Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template
title Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template
title_full Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template
title_fullStr Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template
title_full_unstemmed Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template
title_short Synthesis and Characterization of Molecularly Imprinted Polymer with Oleic Acid as a Template
title_sort synthesis and characterization of molecularly imprinted polymer with oleic acid as a template
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/38045/
http://umpir.ump.edu.my/id/eprint/38045/
http://umpir.ump.edu.my/id/eprint/38045/
http://umpir.ump.edu.my/id/eprint/38045/1/1.jpg