A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water

Pharmaceuticals and personal care products (PPCPs) are one of the threats to water safety and security. These contaminants are hard to be removed due to toxicity and resistant to breakdown. In this study, thin film composite polypiperazine-amide membrane modified with graphene oxide (GO) was synthes...

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Main Authors: Ntone, Ellora Priscille Ndia, Sunarti, Abd Rahman, Rozaimi, Abu Samah, Mohamad Syafiq, Abdul Wahab, Abbas Jawad, Zeinab, Hasrinah, Hasbullah
Format: Article
Language:English
English
Published: Elsevier Ltd 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/37901/
http://umpir.ump.edu.my/id/eprint/37901/1/A%20comparison%20study%20on%20performance%20of%20thin%20film%20composite.pdf
http://umpir.ump.edu.my/id/eprint/37901/2/A%20comparison%20study%20on%20performance%20of%20thin%20film_FULL.pdf
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author Ntone, Ellora Priscille Ndia
Sunarti, Abd Rahman
Rozaimi, Abu Samah
Mohamad Syafiq, Abdul Wahab
Abbas Jawad, Zeinab
Hasrinah, Hasbullah
author_facet Ntone, Ellora Priscille Ndia
Sunarti, Abd Rahman
Rozaimi, Abu Samah
Mohamad Syafiq, Abdul Wahab
Abbas Jawad, Zeinab
Hasrinah, Hasbullah
author_sort Ntone, Ellora Priscille Ndia
building UMP Institutional Repository
collection Online Access
description Pharmaceuticals and personal care products (PPCPs) are one of the threats to water safety and security. These contaminants are hard to be removed due to toxicity and resistant to breakdown. In this study, thin film composite polypiperazine-amide membrane modified with graphene oxide (GO) was synthesized as a rejection medium for this groups of contaminants. Acetaminophen (ACT), Diclofenac (DCF), and Ibuprofen (IBF) was selected as pharmaceutical pollutants and was rejected at different pH ranging from 4 to 9. ATR-FTIR, surface hydrophilicity, pure water permeability and rejection % was evaluated. The effect of GO on rejection showed that PES/GO-0.2 had the greatest hydrophilic effect, pure water permeability and rejection efficiency on all three drugs. The effect of pH on the membrane showed that DCF had the highest rejection (99.13%) at pH8–9, followed by IBF (95.78%) at pH 8–9, and lastly ACT (97.7%) at pH 7. Thus, thin film composite polypiperazine-amide membrane modified with graphene oxide can be effectively and sustainably applied in water treatment processes.
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institution Universiti Malaysia Pahang
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language English
English
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publishDate 2023
publisher Elsevier Ltd
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spelling ump-379012023-07-04T02:05:24Z http://umpir.ump.edu.my/id/eprint/37901/ A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water Ntone, Ellora Priscille Ndia Sunarti, Abd Rahman Rozaimi, Abu Samah Mohamad Syafiq, Abdul Wahab Abbas Jawad, Zeinab Hasrinah, Hasbullah RA Public aspects of medicine TP Chemical technology Pharmaceuticals and personal care products (PPCPs) are one of the threats to water safety and security. These contaminants are hard to be removed due to toxicity and resistant to breakdown. In this study, thin film composite polypiperazine-amide membrane modified with graphene oxide (GO) was synthesized as a rejection medium for this groups of contaminants. Acetaminophen (ACT), Diclofenac (DCF), and Ibuprofen (IBF) was selected as pharmaceutical pollutants and was rejected at different pH ranging from 4 to 9. ATR-FTIR, surface hydrophilicity, pure water permeability and rejection % was evaluated. The effect of GO on rejection showed that PES/GO-0.2 had the greatest hydrophilic effect, pure water permeability and rejection efficiency on all three drugs. The effect of pH on the membrane showed that DCF had the highest rejection (99.13%) at pH8–9, followed by IBF (95.78%) at pH 8–9, and lastly ACT (97.7%) at pH 7. Thus, thin film composite polypiperazine-amide membrane modified with graphene oxide can be effectively and sustainably applied in water treatment processes. Elsevier Ltd 2023-05 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/37901/1/A%20comparison%20study%20on%20performance%20of%20thin%20film%20composite.pdf pdf en http://umpir.ump.edu.my/id/eprint/37901/2/A%20comparison%20study%20on%20performance%20of%20thin%20film_FULL.pdf Ntone, Ellora Priscille Ndia and Sunarti, Abd Rahman and Rozaimi, Abu Samah and Mohamad Syafiq, Abdul Wahab and Abbas Jawad, Zeinab and Hasrinah, Hasbullah (2023) A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water. Chemical Engineering Research and Design, 195. pp. 28-37. ISSN 0263-8762. (Published) https://doi.org/10.1016/j.cherd.2023.05.023 https://doi.org/10.1016/j.cherd.2023.05.023
spellingShingle RA Public aspects of medicine
TP Chemical technology
Ntone, Ellora Priscille Ndia
Sunarti, Abd Rahman
Rozaimi, Abu Samah
Mohamad Syafiq, Abdul Wahab
Abbas Jawad, Zeinab
Hasrinah, Hasbullah
A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water
title A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water
title_full A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water
title_fullStr A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water
title_full_unstemmed A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water
title_short A comparison study on performance of thin film composite membrane embedded with graphene oxide for Acetaminophen, Diclofenac and Ibuprofen separation from waste water
title_sort comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
topic RA Public aspects of medicine
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/37901/
http://umpir.ump.edu.my/id/eprint/37901/
http://umpir.ump.edu.my/id/eprint/37901/
http://umpir.ump.edu.my/id/eprint/37901/1/A%20comparison%20study%20on%20performance%20of%20thin%20film%20composite.pdf
http://umpir.ump.edu.my/id/eprint/37901/2/A%20comparison%20study%20on%20performance%20of%20thin%20film_FULL.pdf