Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte
The present work highlights on the structural and conduction properties of the solid biopolymer electrolytes (SBPE) based carboxymethyl cellulose (CMC) doped dodecyltrimethyl ammonium bromide (DTAB) and plasticized with ethylene carbonate (EC). The SBPE exhibits high ionic conductivity at room tempe...
| Main Authors: | , , |
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| Format: | Conference or Workshop Item |
| Language: | English English |
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Trans Tech Publications
2021
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/37747/ http://umpir.ump.edu.my/id/eprint/37747/1/MSF.1025.26.pdf http://umpir.ump.edu.my/id/eprint/37747/7/Effect%20of%20intermolecular%20interaction%20on%20ionic%20conductivity%20of%20CMC-DTAB%20plasticized%20.pdf |
| _version_ | 1848825334898622464 |
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| author | Nurhasniza, Mamajan Khan Noor Saadiah, Mohd Ali Ahmad Salihin, Samsudin |
| author_facet | Nurhasniza, Mamajan Khan Noor Saadiah, Mohd Ali Ahmad Salihin, Samsudin |
| author_sort | Nurhasniza, Mamajan Khan |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | The present work highlights on the structural and conduction properties of the solid biopolymer electrolytes (SBPE) based carboxymethyl cellulose (CMC) doped dodecyltrimethyl ammonium bromide (DTAB) and plasticized with ethylene carbonate (EC). The SBPE exhibits high ionic conductivity at room temperature where the highest value reaching 1.0 × 10-3 S cm-1 for sample containing with 10 wt. % of EC and increases the ionic conductivity when temperature was increased. Complexation within the SBPE has been confirmed by the FTIR analysis where the intermolecular interaction has improvised the coordination between CMC-DTAB and EC resulting in better structural and conductivity ability. The findings suggest that the great potential of CMC and make it promising to serve as an electrolyte for electrochemical devices. |
| first_indexed | 2025-11-15T03:27:17Z |
| format | Conference or Workshop Item |
| id | ump-37747 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:27:17Z |
| publishDate | 2021 |
| publisher | Trans Tech Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-377472023-12-14T04:38:09Z http://umpir.ump.edu.my/id/eprint/37747/ Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte Nurhasniza, Mamajan Khan Noor Saadiah, Mohd Ali Ahmad Salihin, Samsudin T Technology (General) TP Chemical technology The present work highlights on the structural and conduction properties of the solid biopolymer electrolytes (SBPE) based carboxymethyl cellulose (CMC) doped dodecyltrimethyl ammonium bromide (DTAB) and plasticized with ethylene carbonate (EC). The SBPE exhibits high ionic conductivity at room temperature where the highest value reaching 1.0 × 10-3 S cm-1 for sample containing with 10 wt. % of EC and increases the ionic conductivity when temperature was increased. Complexation within the SBPE has been confirmed by the FTIR analysis where the intermolecular interaction has improvised the coordination between CMC-DTAB and EC resulting in better structural and conductivity ability. The findings suggest that the great potential of CMC and make it promising to serve as an electrolyte for electrochemical devices. Trans Tech Publications 2021-03-30 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/37747/1/MSF.1025.26.pdf pdf en http://umpir.ump.edu.my/id/eprint/37747/7/Effect%20of%20intermolecular%20interaction%20on%20ionic%20conductivity%20of%20CMC-DTAB%20plasticized%20.pdf Nurhasniza, Mamajan Khan and Noor Saadiah, Mohd Ali and Ahmad Salihin, Samsudin (2021) Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte. In: Materials Science Forum; 2nd Postgraduate Symposium on Industrial Science and Technology, SISTEC 2020 , 26 - 27 August 2020 , Virtual, Online. pp. 26-31., 1025 (257819). ISSN 0255-5476 ISBN 978-303573757-8 (Published) https://doi.org/10.4028/www.scientific.net/MSF.1025.26 |
| spellingShingle | T Technology (General) TP Chemical technology Nurhasniza, Mamajan Khan Noor Saadiah, Mohd Ali Ahmad Salihin, Samsudin Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte |
| title | Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte |
| title_full | Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte |
| title_fullStr | Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte |
| title_full_unstemmed | Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte |
| title_short | Effect of intermolecular interaction on ionic conductivity of CMC-DTAB plasticized with Ec based solid biopolymer electrolyte |
| title_sort | effect of intermolecular interaction on ionic conductivity of cmc-dtab plasticized with ec based solid biopolymer electrolyte |
| topic | T Technology (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/37747/ http://umpir.ump.edu.my/id/eprint/37747/ http://umpir.ump.edu.my/id/eprint/37747/1/MSF.1025.26.pdf http://umpir.ump.edu.my/id/eprint/37747/7/Effect%20of%20intermolecular%20interaction%20on%20ionic%20conductivity%20of%20CMC-DTAB%20plasticized%20.pdf |