A preliminary study of pyrolysis kinetics among various types of oil palm wastes

Oil palm waste such as empty fruit bunch (EFB), mesocarp fibre (MF) and palm kernel shell (PKS) are some of the abundant wastes produced by oil palm mills which have great potential to replace fossil fuel through the application of thermochemical processes like torrefaction which produces solid biof...

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Main Authors: Sheng, Yung Yong, Ruwaida, Abdul Rasid, Mazni, Ismail
Format: Article
Language:English
English
Published: Elsevier Ltd 2023
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/36987/
http://umpir.ump.edu.my/id/eprint/36987/1/A%20preliminary%20study%20of%20pyrolysis%20kinetics%20among%20various%20types%20of%20oil%20palm%20wastes.pdf
http://umpir.ump.edu.my/id/eprint/36987/7/A%20preliminary%20study%20of%20pyrolysis%20kinetics%20among%20various%20types%20of%20oil%20palm%20waste.pdf
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author Sheng, Yung Yong
Ruwaida, Abdul Rasid
Mazni, Ismail
author_facet Sheng, Yung Yong
Ruwaida, Abdul Rasid
Mazni, Ismail
author_sort Sheng, Yung Yong
building UMP Institutional Repository
collection Online Access
description Oil palm waste such as empty fruit bunch (EFB), mesocarp fibre (MF) and palm kernel shell (PKS) are some of the abundant wastes produced by oil palm mills which have great potential to replace fossil fuel through the application of thermochemical processes like torrefaction which produces solid biofuel and pyrolysis that produces bio-oils. The study of the kinetics of a reaction indicates the activation energy and frequency factor of the reaction are often applied in the design of a reactor. In this study, the kinetics of pyrolysis of oil palm wastes were investigated with the aid of a derivative thermogravimetric graph (DTG) using thermogravimetric analyzers. Modelfitting methods including Arrhenius, Coats-Redfern (CR) and Kennedy-Clarke (KC) models were applied to obtain the kinetic parameters which are activation energy (E) and pre-exponential factor (A). As a result, it is clear that the CR model provides the most accurate estimates of the kinetics of the pyrolysis of oil palm wastes.
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spelling ump-369872024-02-27T07:22:40Z http://umpir.ump.edu.my/id/eprint/36987/ A preliminary study of pyrolysis kinetics among various types of oil palm wastes Sheng, Yung Yong Ruwaida, Abdul Rasid Mazni, Ismail QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Oil palm waste such as empty fruit bunch (EFB), mesocarp fibre (MF) and palm kernel shell (PKS) are some of the abundant wastes produced by oil palm mills which have great potential to replace fossil fuel through the application of thermochemical processes like torrefaction which produces solid biofuel and pyrolysis that produces bio-oils. The study of the kinetics of a reaction indicates the activation energy and frequency factor of the reaction are often applied in the design of a reactor. In this study, the kinetics of pyrolysis of oil palm wastes were investigated with the aid of a derivative thermogravimetric graph (DTG) using thermogravimetric analyzers. Modelfitting methods including Arrhenius, Coats-Redfern (CR) and Kennedy-Clarke (KC) models were applied to obtain the kinetic parameters which are activation energy (E) and pre-exponential factor (A). As a result, it is clear that the CR model provides the most accurate estimates of the kinetics of the pyrolysis of oil palm wastes. Elsevier Ltd 2023-11-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/36987/1/A%20preliminary%20study%20of%20pyrolysis%20kinetics%20among%20various%20types%20of%20oil%20palm%20wastes.pdf pdf en http://umpir.ump.edu.my/id/eprint/36987/7/A%20preliminary%20study%20of%20pyrolysis%20kinetics%20among%20various%20types%20of%20oil%20palm%20waste.pdf Sheng, Yung Yong and Ruwaida, Abdul Rasid and Mazni, Ismail (2023) A preliminary study of pyrolysis kinetics among various types of oil palm wastes. Materials Today: Proceedings. pp. 1-9. ISSN 2214-7853. (In Press / Online First) (In Press / Online First) https://doi.org/10.1016/j.matpr.2023.09.160 10.1016/j.matpr.2023.09.160
spellingShingle QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Sheng, Yung Yong
Ruwaida, Abdul Rasid
Mazni, Ismail
A preliminary study of pyrolysis kinetics among various types of oil palm wastes
title A preliminary study of pyrolysis kinetics among various types of oil palm wastes
title_full A preliminary study of pyrolysis kinetics among various types of oil palm wastes
title_fullStr A preliminary study of pyrolysis kinetics among various types of oil palm wastes
title_full_unstemmed A preliminary study of pyrolysis kinetics among various types of oil palm wastes
title_short A preliminary study of pyrolysis kinetics among various types of oil palm wastes
title_sort preliminary study of pyrolysis kinetics among various types of oil palm wastes
topic QD Chemistry
T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/36987/
http://umpir.ump.edu.my/id/eprint/36987/
http://umpir.ump.edu.my/id/eprint/36987/
http://umpir.ump.edu.my/id/eprint/36987/1/A%20preliminary%20study%20of%20pyrolysis%20kinetics%20among%20various%20types%20of%20oil%20palm%20wastes.pdf
http://umpir.ump.edu.my/id/eprint/36987/7/A%20preliminary%20study%20of%20pyrolysis%20kinetics%20among%20various%20types%20of%20oil%20palm%20waste.pdf