Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy

Biomedical implants of Cobalt-Chromium-Molybdenum (Co-Cr-Mo) alloys have been reported difficult to bond directly on bone when inserted in human body. In order to improve this situation several attempts have been made including coating the implants with a bioactive layer such as hydroxyapatite (HA)....

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Main Author: Mas Ayu, H.
Format: Research Report
Language:English
Published: 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/36299/
http://umpir.ump.edu.my/id/eprint/36299/1/Effect%20of%20biodegradable%20pla%20on%20hydroxyapatite%20coating%20to%20improve%20adhesion%20properties%20on%20Cr-Co-Mo%20alloy.wm.pdf
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author Mas Ayu, H.
author_facet Mas Ayu, H.
author_sort Mas Ayu, H.
building UMP Institutional Repository
collection Online Access
description Biomedical implants of Cobalt-Chromium-Molybdenum (Co-Cr-Mo) alloys have been reported difficult to bond directly on bone when inserted in human body. In order to improve this situation several attempts have been made including coating the implants with a bioactive layer such as hydroxyapatite (HA). However, major concerns arise when massive micro crack surface, delamination and low adhesion strength of HA coatings occurred which later caused the harmful releases of metal ions. The objectives of this research is to improve the adhesion strength of HA and produce crack free surface coating by adding biodegradable polylactic acid (PLA) into HA slurry as well as to enhance biocompatibility of Co-Cr-Mo alloy for long term used. In this research, the optimum HA slurry was determined by mixing different weight of PLA (1, 2 and 3 gram) before deposited on Co-Cr-Mo substrates using dip coating machine. Constant parameters for dip coating process were applied to all samples condition. Micro hardness test was done to measure the adhesion strength of the PLA/HA coating as well as to evaluate the effects of adding PLA at different weight. The corrosion resistance performance of the coated and uncoated Co-Cr-Mo substrates were investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results also proved that the mixture of 2g PLA with 1g HA into 20ml chloroform able to eliminate micro cracks with acceptable coating thickness (~10μm). It is concluded that by adding a suitable amount of PLA into HA slurry able to gain positive effect in terms of increment of the adhesion strength of HA coating as well as bioactivity performance.
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institution Universiti Malaysia Pahang
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spelling ump-362992023-02-14T08:26:39Z http://umpir.ump.edu.my/id/eprint/36299/ Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy Mas Ayu, H. TJ Mechanical engineering and machinery Biomedical implants of Cobalt-Chromium-Molybdenum (Co-Cr-Mo) alloys have been reported difficult to bond directly on bone when inserted in human body. In order to improve this situation several attempts have been made including coating the implants with a bioactive layer such as hydroxyapatite (HA). However, major concerns arise when massive micro crack surface, delamination and low adhesion strength of HA coatings occurred which later caused the harmful releases of metal ions. The objectives of this research is to improve the adhesion strength of HA and produce crack free surface coating by adding biodegradable polylactic acid (PLA) into HA slurry as well as to enhance biocompatibility of Co-Cr-Mo alloy for long term used. In this research, the optimum HA slurry was determined by mixing different weight of PLA (1, 2 and 3 gram) before deposited on Co-Cr-Mo substrates using dip coating machine. Constant parameters for dip coating process were applied to all samples condition. Micro hardness test was done to measure the adhesion strength of the PLA/HA coating as well as to evaluate the effects of adding PLA at different weight. The corrosion resistance performance of the coated and uncoated Co-Cr-Mo substrates were investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results also proved that the mixture of 2g PLA with 1g HA into 20ml chloroform able to eliminate micro cracks with acceptable coating thickness (~10μm). It is concluded that by adding a suitable amount of PLA into HA slurry able to gain positive effect in terms of increment of the adhesion strength of HA coating as well as bioactivity performance. 2020 Research Report NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/36299/1/Effect%20of%20biodegradable%20pla%20on%20hydroxyapatite%20coating%20to%20improve%20adhesion%20properties%20on%20Cr-Co-Mo%20alloy.wm.pdf Mas Ayu, H. (2020) Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy. , [Research Report] (Unpublished)
spellingShingle TJ Mechanical engineering and machinery
Mas Ayu, H.
Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy
title Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy
title_full Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy
title_fullStr Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy
title_full_unstemmed Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy
title_short Effect of biodegradable PLA on hydroxyapatite coating to improve adhesion properties on Cr-Co-Mo alloy
title_sort effect of biodegradable pla on hydroxyapatite coating to improve adhesion properties on cr-co-mo alloy
topic TJ Mechanical engineering and machinery
url http://umpir.ump.edu.my/id/eprint/36299/
http://umpir.ump.edu.my/id/eprint/36299/1/Effect%20of%20biodegradable%20pla%20on%20hydroxyapatite%20coating%20to%20improve%20adhesion%20properties%20on%20Cr-Co-Mo%20alloy.wm.pdf