Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation

Mixed matrix membranes (MMMs) comprising of where polyvinyl chloride (PVC) and graphene oxide (GO) were employed in the membrane fabrication in order to improve the membrane characteristics. In this study of gas separation using mixed matrix membrane, gases such as CO2 and CH4 were used. The objecti...

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Main Authors: Raj, K. R., Sunarti, Abd Rahman
Format: Conference or Workshop Item
Language:English
Published: IOP Publishing Ltd 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/35877/
http://umpir.ump.edu.my/id/eprint/35877/1/Preliminary%20fractional%20factorial%20design%20%28FFD%29%20study%20using%20incorporation%20of%20graphene%20oxide%20in%20PVC%20in%20mixed%20matrix%20membrane.pdf
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author Raj, K. R.
Sunarti, Abd Rahman
author_facet Raj, K. R.
Sunarti, Abd Rahman
author_sort Raj, K. R.
building UMP Institutional Repository
collection Online Access
description Mixed matrix membranes (MMMs) comprising of where polyvinyl chloride (PVC) and graphene oxide (GO) were employed in the membrane fabrication in order to improve the membrane characteristics. In this study of gas separation using mixed matrix membrane, gases such as CO2 and CH4 were used. The objectives of this research were to synthesize and develop MMMs PVC/GO, and also to carry out screening to determine best factors condition for membrane to function at high selectivity. The development of MMMs PVC/GO was based on 5 factors. Based on the screening tests, the run which was made up of factors PVC 20%, GO 4%, 1 bar of pressure during gas permeation, NMP solvent, and immersion time of 300s, shows to have the highest selectivity at 26.09 which was above the upper bound lines in the Robeson's Upper bound plot. Fractional Factorial Design (FFD) was applied to study the minimalization of influenced factors during MMMs preparation. Based on the FFD run, the R-squared (R2) was 1.00. Factors that had less impact on the maximum selectivity were the time membrane immersed in water bath (s), and also gas pressure during gas permeation test.
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format Conference or Workshop Item
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institution Universiti Malaysia Pahang
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language English
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publishDate 2019
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spelling ump-358772023-05-24T04:15:10Z http://umpir.ump.edu.my/id/eprint/35877/ Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation Raj, K. R. Sunarti, Abd Rahman QD Chemistry T Technology (General) TP Chemical technology Mixed matrix membranes (MMMs) comprising of where polyvinyl chloride (PVC) and graphene oxide (GO) were employed in the membrane fabrication in order to improve the membrane characteristics. In this study of gas separation using mixed matrix membrane, gases such as CO2 and CH4 were used. The objectives of this research were to synthesize and develop MMMs PVC/GO, and also to carry out screening to determine best factors condition for membrane to function at high selectivity. The development of MMMs PVC/GO was based on 5 factors. Based on the screening tests, the run which was made up of factors PVC 20%, GO 4%, 1 bar of pressure during gas permeation, NMP solvent, and immersion time of 300s, shows to have the highest selectivity at 26.09 which was above the upper bound lines in the Robeson's Upper bound plot. Fractional Factorial Design (FFD) was applied to study the minimalization of influenced factors during MMMs preparation. Based on the FFD run, the R-squared (R2) was 1.00. Factors that had less impact on the maximum selectivity were the time membrane immersed in water bath (s), and also gas pressure during gas permeation test. IOP Publishing Ltd 2019-12-09 Conference or Workshop Item PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/35877/1/Preliminary%20fractional%20factorial%20design%20%28FFD%29%20study%20using%20incorporation%20of%20graphene%20oxide%20in%20PVC%20in%20mixed%20matrix%20membrane.pdf Raj, K. R. and Sunarti, Abd Rahman (2019) Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation. In: IOP Conference Series: Materials Science and Engineering; 1st Process Systems Engineering and Safety Symposium 2019, ProSES 2019 , 4 September 2019 , Kuantan, Pahang, Malaysia. pp. 1-15., 702 (012041). ISSN 1757-8981 (Published) https://doi.org/10.1088/1757-899X/702/1/012041
spellingShingle QD Chemistry
T Technology (General)
TP Chemical technology
Raj, K. R.
Sunarti, Abd Rahman
Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation
title Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation
title_full Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation
title_fullStr Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation
title_full_unstemmed Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation
title_short Preliminary fractional factorial design (FFD) study using incorporation of graphene oxide in PVC in mixed matrix membrane to enhance CO2 /CH4 separation
title_sort preliminary fractional factorial design (ffd) study using incorporation of graphene oxide in pvc in mixed matrix membrane to enhance co2 /ch4 separation
topic QD Chemistry
T Technology (General)
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/35877/
http://umpir.ump.edu.my/id/eprint/35877/
http://umpir.ump.edu.my/id/eprint/35877/1/Preliminary%20fractional%20factorial%20design%20%28FFD%29%20study%20using%20incorporation%20of%20graphene%20oxide%20in%20PVC%20in%20mixed%20matrix%20membrane.pdf