Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes
In the present work, amorphous bio-based polymer electrolytes (BBPEs) using alginate polymer as a matrix host and doped with varying amounts of ammonium iodide (NH4I) have been developed via the solution casting technique. The physicochemical properties of alginate-NH4I BBPEs were evaluated by using...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Elsevier Ltd
2022
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/35858/ http://umpir.ump.edu.my/id/eprint/35858/1/%282022%29%20Studies%20on%20the%20ions%20transportation%20behavior%20of%20alginate%20doped%20with%20H%2B%20carrier-based%20polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/35858/7/Studies%20on%20the%20ions%20transportation%20behavior%20of%20alginate%20doped%20with%20H.pdf |
| _version_ | 1848824887759601664 |
|---|---|
| author | Ahmad Faizrin, Fuzlin Nor Fatihah, Mazuki Nurhasniza, Mamajan Khan Saadiah, M. A. Hasan, Md. M. Nagao, Y. Ahmad Salihin, Samsudin |
| author_facet | Ahmad Faizrin, Fuzlin Nor Fatihah, Mazuki Nurhasniza, Mamajan Khan Saadiah, M. A. Hasan, Md. M. Nagao, Y. Ahmad Salihin, Samsudin |
| author_sort | Ahmad Faizrin, Fuzlin |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | In the present work, amorphous bio-based polymer electrolytes (BBPEs) using alginate polymer as a matrix host and doped with varying amounts of ammonium iodide (NH4I) have been developed via the solution casting technique. The physicochemical properties of alginate-NH4I BBPEs were evaluated by using X-Ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared (FTIR), thermal gravimetric analysis (TGA), electrical impedance spectroscopy (EIS), and transference number measurement (TNM). The BBPEs film containing 25 wt % of NH4I possessed the highest ionic conductivity of 1.29 × 10−4 S cm−1, the highest amorphous phase, and good thermal stability of up to 234 °C. Based on the Nyquist fitting approaches, the ionic conductivity of the BBPEs was primarily influenced by the ion transportation, which was due to the interplay of segmental motion between the alginate and NH4I, and also the H+ hopping mechanism, as shown by FTIR. The proton transference number (tH+ = 0.41) suggests that alginate BBPEs are promising materials in electrochemical device applications. |
| first_indexed | 2025-11-15T03:20:10Z |
| format | Article |
| id | ump-35858 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:20:10Z |
| publishDate | 2022 |
| publisher | Elsevier Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-358582023-10-04T03:42:48Z http://umpir.ump.edu.my/id/eprint/35858/ Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes Ahmad Faizrin, Fuzlin Nor Fatihah, Mazuki Nurhasniza, Mamajan Khan Saadiah, M. A. Hasan, Md. M. Nagao, Y. Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry In the present work, amorphous bio-based polymer electrolytes (BBPEs) using alginate polymer as a matrix host and doped with varying amounts of ammonium iodide (NH4I) have been developed via the solution casting technique. The physicochemical properties of alginate-NH4I BBPEs were evaluated by using X-Ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared (FTIR), thermal gravimetric analysis (TGA), electrical impedance spectroscopy (EIS), and transference number measurement (TNM). The BBPEs film containing 25 wt % of NH4I possessed the highest ionic conductivity of 1.29 × 10−4 S cm−1, the highest amorphous phase, and good thermal stability of up to 234 °C. Based on the Nyquist fitting approaches, the ionic conductivity of the BBPEs was primarily influenced by the ion transportation, which was due to the interplay of segmental motion between the alginate and NH4I, and also the H+ hopping mechanism, as shown by FTIR. The proton transference number (tH+ = 0.41) suggests that alginate BBPEs are promising materials in electrochemical device applications. Elsevier Ltd 2022-08-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/35858/1/%282022%29%20Studies%20on%20the%20ions%20transportation%20behavior%20of%20alginate%20doped%20with%20H%2B%20carrier-based%20polymer%20electrolytes.pdf pdf en http://umpir.ump.edu.my/id/eprint/35858/7/Studies%20on%20the%20ions%20transportation%20behavior%20of%20alginate%20doped%20with%20H.pdf Ahmad Faizrin, Fuzlin and Nor Fatihah, Mazuki and Nurhasniza, Mamajan Khan and Saadiah, M. A. and Hasan, Md. M. and Nagao, Y. and Ahmad Salihin, Samsudin (2022) Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes. Materials Chemistry and Physics, 287 (126207). pp. 1-12. ISSN 0254-0584. (Published) https://doi.org/10.1016/j.matchemphys.2022.126207 https://doi.org/10.1016/j.matchemphys.2022.126207 |
| spellingShingle | Q Science (General) QC Physics QD Chemistry Ahmad Faizrin, Fuzlin Nor Fatihah, Mazuki Nurhasniza, Mamajan Khan Saadiah, M. A. Hasan, Md. M. Nagao, Y. Ahmad Salihin, Samsudin Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes |
| title | Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes |
| title_full | Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes |
| title_fullStr | Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes |
| title_full_unstemmed | Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes |
| title_short | Studies on the ions transportation behavior of alginate doped with H+ carrier-based polymer electrolytes |
| title_sort | studies on the ions transportation behavior of alginate doped with h+ carrier-based polymer electrolytes |
| topic | Q Science (General) QC Physics QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/35858/ http://umpir.ump.edu.my/id/eprint/35858/ http://umpir.ump.edu.my/id/eprint/35858/ http://umpir.ump.edu.my/id/eprint/35858/1/%282022%29%20Studies%20on%20the%20ions%20transportation%20behavior%20of%20alginate%20doped%20with%20H%2B%20carrier-based%20polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/35858/7/Studies%20on%20the%20ions%20transportation%20behavior%20of%20alginate%20doped%20with%20H.pdf |