Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes
This study investigates the structural and ionic conduction performance with the involvement of ethylene carbonate (EC) in a bio-based polymer electrolytes (BBPEs) system, based on alginate doped glycolic acid (GA). The solution casting technique was used to successfully prepare the BBPEs which were...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English English |
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Elsevier Ltd
2022
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| Online Access: | http://umpir.ump.edu.my/id/eprint/35857/ http://umpir.ump.edu.my/id/eprint/35857/1/%282022%29%20Involvement%20of%20ethylene%20carbonate%20on%20the%20enhancement%20H%2B%20carriers%20in%20structural%20and%20ionic%20conduction%20performance%20on%20alginate%20bio-based%20polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/35857/7/Involvement%20of%20ethylene%20carbonate%20on%20the%20enhancement%20H%2B%20carriers%20.pdf |
| _version_ | 1848824887474388992 |
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| author | Ahmad Faizrin, Fuzlin Saadiah, M. A. Hasan, Md. M. Nagao, Y. Izan Izwan, Misnon Ahmad Salihin, Samsudin |
| author_facet | Ahmad Faizrin, Fuzlin Saadiah, M. A. Hasan, Md. M. Nagao, Y. Izan Izwan, Misnon Ahmad Salihin, Samsudin |
| author_sort | Ahmad Faizrin, Fuzlin |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | This study investigates the structural and ionic conduction performance with the involvement of ethylene carbonate (EC) in a bio-based polymer electrolytes (BBPEs) system, based on alginate doped glycolic acid (GA). The solution casting technique was used to successfully prepare the BBPEs which were characterized with various approaches to evaluate their ionic conduction performance. It was revealed that at ambient temperature, an optimum ionic conductivity of 9.06 × 10−4 S cm−1 was achieved after the addition of 6 wt% EC, with an observed improvement of the amorphous phase and thermal stability. The enhancement of ionic conduction properties is believed to be due to the protonation (H+) enhancement, as proven by FTIR and TNM studies. The findings show that the developed alginate-GA-EC is a promising candidate for use as electrolytes in electrochemical devices that are based on H+ carriers. |
| first_indexed | 2025-11-15T03:20:10Z |
| format | Article |
| id | ump-35857 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T03:20:10Z |
| publishDate | 2022 |
| publisher | Elsevier Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-358572023-10-04T03:47:39Z http://umpir.ump.edu.my/id/eprint/35857/ Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes Ahmad Faizrin, Fuzlin Saadiah, M. A. Hasan, Md. M. Nagao, Y. Izan Izwan, Misnon Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry This study investigates the structural and ionic conduction performance with the involvement of ethylene carbonate (EC) in a bio-based polymer electrolytes (BBPEs) system, based on alginate doped glycolic acid (GA). The solution casting technique was used to successfully prepare the BBPEs which were characterized with various approaches to evaluate their ionic conduction performance. It was revealed that at ambient temperature, an optimum ionic conductivity of 9.06 × 10−4 S cm−1 was achieved after the addition of 6 wt% EC, with an observed improvement of the amorphous phase and thermal stability. The enhancement of ionic conduction properties is believed to be due to the protonation (H+) enhancement, as proven by FTIR and TNM studies. The findings show that the developed alginate-GA-EC is a promising candidate for use as electrolytes in electrochemical devices that are based on H+ carriers. Elsevier Ltd 2022-02 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/35857/1/%282022%29%20Involvement%20of%20ethylene%20carbonate%20on%20the%20enhancement%20H%2B%20carriers%20in%20structural%20and%20ionic%20conduction%20performance%20on%20alginate%20bio-based%20polymer%20electrolytes.pdf pdf en http://umpir.ump.edu.my/id/eprint/35857/7/Involvement%20of%20ethylene%20carbonate%20on%20the%20enhancement%20H%2B%20carriers%20.pdf Ahmad Faizrin, Fuzlin and Saadiah, M. A. and Hasan, Md. M. and Nagao, Y. and Izan Izwan, Misnon and Ahmad Salihin, Samsudin (2022) Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes. International Journal of Hydrogen Energy, 47 (12). pp. 7846-7860. ISSN 0360-3199. (Published) https://doi.org/10.1016/j.ijhydene.2021.12.124 https://doi.org/10.1016/j.ijhydene.2021.12.124 |
| spellingShingle | Q Science (General) QC Physics QD Chemistry Ahmad Faizrin, Fuzlin Saadiah, M. A. Hasan, Md. M. Nagao, Y. Izan Izwan, Misnon Ahmad Salihin, Samsudin Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| title | Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| title_full | Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| title_fullStr | Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| title_full_unstemmed | Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| title_short | Involvement of ethylene carbonate on the enhancement H+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| title_sort | involvement of ethylene carbonate on the enhancement h+ carriers in structural and ionic conduction performance on alginate bio-based polymer electrolytes |
| topic | Q Science (General) QC Physics QD Chemistry |
| url | http://umpir.ump.edu.my/id/eprint/35857/ http://umpir.ump.edu.my/id/eprint/35857/ http://umpir.ump.edu.my/id/eprint/35857/ http://umpir.ump.edu.my/id/eprint/35857/1/%282022%29%20Involvement%20of%20ethylene%20carbonate%20on%20the%20enhancement%20H%2B%20carriers%20in%20structural%20and%20ionic%20conduction%20performance%20on%20alginate%20bio-based%20polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/35857/7/Involvement%20of%20ethylene%20carbonate%20on%20the%20enhancement%20H%2B%20carriers%20.pdf |