Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier

Natural product-based materials have gained significant interest in replacing the petroleum-based oil chemicals with environmentally friendly materials. A corn oil-based demulsifier has been successfully synthesized by the condensation reaction of corn oil with diethanolamine in the presence of a ca...

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Main Authors: M. A., Saadiah, Nour, Abdurahman Hamid, Rosli, Mohd Yunus
Format: Article
Language:English
Published: Elsevier Ltd 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/34422/
http://umpir.ump.edu.my/id/eprint/34422/1/Synthesis%2C%20characterization%2C%20and%20demulsification%20of%20water_FULL.pdf
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author M. A., Saadiah
Nour, Abdurahman Hamid
Rosli, Mohd Yunus
author_facet M. A., Saadiah
Nour, Abdurahman Hamid
Rosli, Mohd Yunus
author_sort M. A., Saadiah
building UMP Institutional Repository
collection Online Access
description Natural product-based materials have gained significant interest in replacing the petroleum-based oil chemicals with environmentally friendly materials. A corn oil-based demulsifier has been successfully synthesized by the condensation reaction of corn oil with diethanolamine in the presence of a catalyst applied during separation via a water-in-oil (W/O) emulsion. The demulsifier was characterized by FTIR, GC-MS, and LC-QTOF-MS analyses. The surfactant's separation efficacy was studied using the Sany-glass test. The results showed that this new product efficiently demulsified the W/O emulsion with 98% separation achieved. The influence of settling time, demulsifier dosage, and temperature on the demulsification efficiency were investigated. The separation efficiency increased with increasing settling time, demulsifier dose and the temperature conditions accelerate the demulsification process. As well, the interfacial tension decreases with increases of the demulsifier dose
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spelling ump-344222023-11-15T08:02:09Z http://umpir.ump.edu.my/id/eprint/34422/ Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier M. A., Saadiah Nour, Abdurahman Hamid Rosli, Mohd Yunus T Technology (General) TP Chemical technology Natural product-based materials have gained significant interest in replacing the petroleum-based oil chemicals with environmentally friendly materials. A corn oil-based demulsifier has been successfully synthesized by the condensation reaction of corn oil with diethanolamine in the presence of a catalyst applied during separation via a water-in-oil (W/O) emulsion. The demulsifier was characterized by FTIR, GC-MS, and LC-QTOF-MS analyses. The surfactant's separation efficacy was studied using the Sany-glass test. The results showed that this new product efficiently demulsified the W/O emulsion with 98% separation achieved. The influence of settling time, demulsifier dosage, and temperature on the demulsification efficiency were investigated. The separation efficiency increased with increasing settling time, demulsifier dose and the temperature conditions accelerate the demulsification process. As well, the interfacial tension decreases with increases of the demulsifier dose Elsevier Ltd 2021 Article PeerReviewed pdf en cc_by_nc_nd_4 http://umpir.ump.edu.my/id/eprint/34422/1/Synthesis%2C%20characterization%2C%20and%20demulsification%20of%20water_FULL.pdf M. A., Saadiah and Nour, Abdurahman Hamid and Rosli, Mohd Yunus (2021) Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier. Materials Today: Proceedings, 42 (Part 1). pp. 251-258. ISSN 2214-7853. (Published) https://doi.org/10.1016/j.matpr.2021.01.145 https://doi.org/10.1016/j.matpr.2021.01.145
spellingShingle T Technology (General)
TP Chemical technology
M. A., Saadiah
Nour, Abdurahman Hamid
Rosli, Mohd Yunus
Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
title Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
title_full Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
title_fullStr Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
title_full_unstemmed Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
title_short Synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
title_sort synthesis, characterization, and demulsification of water in crude oil emulsion via a corn oil-based demulsifier
topic T Technology (General)
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/34422/
http://umpir.ump.edu.my/id/eprint/34422/
http://umpir.ump.edu.my/id/eprint/34422/
http://umpir.ump.edu.my/id/eprint/34422/1/Synthesis%2C%20characterization%2C%20and%20demulsification%20of%20water_FULL.pdf