An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass

In this work, a detailed investigation on the temperature-dependant surface features of biomass derived porous carbon nanoparticles was conducted. The carbon nanoparticles were prepared by carbonization of Caesalpinia Sappan waste pods in single step pyrolysis, using a range of temperature from 400...

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Main Authors: S., Supriya, Bhat, Vinay S., Jayeoye, Titilope John, Rujiralai, Thitima, Chong, Kwok Feng, Hegde, Gurumurthy
Format: Article
Language:English
Published: Springer Berlin Heidelberg 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/33964/
http://umpir.ump.edu.my/id/eprint/33964/7/An%20investigation%20on%20temperature%E2%80%91dependant.pdf
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author S., Supriya
Bhat, Vinay S.
Jayeoye, Titilope John
Rujiralai, Thitima
Chong, Kwok Feng
Hegde, Gurumurthy
author_facet S., Supriya
Bhat, Vinay S.
Jayeoye, Titilope John
Rujiralai, Thitima
Chong, Kwok Feng
Hegde, Gurumurthy
author_sort S., Supriya
building UMP Institutional Repository
collection Online Access
description In this work, a detailed investigation on the temperature-dependant surface features of biomass derived porous carbon nanoparticles was conducted. The carbon nanoparticles were prepared by carbonization of Caesalpinia Sappan waste pods in single step pyrolysis, using a range of temperature from 400 to 1000 °C. The systematic analysis of materials obtained at different temperatures assisted to correlate the effect of pyrolysis temperature on the surface properties. Different methods were employed which were beneficial to demonstrate the overall surface area and porous features constituted by pores of different size (micropores, mesopores) and shapes such as cylindrical or narrow slit shape. This study confirmed the optimization of material properties with rise in pyrolysis temperature; as a result, Caesalpinia Sappan derived carbon nanoparticles pyrolyzed at 1000 °C (CSCNP1000) exhibited the largest surface area (794 m2 g−1 by BET) and pore volume (0.37 cm3 g−1) in the series. The resulted carbon products were microporous/mesoporous in nature, the condition which is considered suitable for the energy storage applications. The energy storage device, supercapacitor, was fabricated which exhibited a specific capacitance of 170.5 F g−1 at 0.25 A g−1. This work demonstrated the suitability of temperature dependent surface of a carbon nanoparticle to be actively used as a cost-effective energy storage device.
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spelling ump-339642022-05-27T08:33:05Z http://umpir.ump.edu.my/id/eprint/33964/ An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass S., Supriya Bhat, Vinay S. Jayeoye, Titilope John Rujiralai, Thitima Chong, Kwok Feng Hegde, Gurumurthy QD Chemistry In this work, a detailed investigation on the temperature-dependant surface features of biomass derived porous carbon nanoparticles was conducted. The carbon nanoparticles were prepared by carbonization of Caesalpinia Sappan waste pods in single step pyrolysis, using a range of temperature from 400 to 1000 °C. The systematic analysis of materials obtained at different temperatures assisted to correlate the effect of pyrolysis temperature on the surface properties. Different methods were employed which were beneficial to demonstrate the overall surface area and porous features constituted by pores of different size (micropores, mesopores) and shapes such as cylindrical or narrow slit shape. This study confirmed the optimization of material properties with rise in pyrolysis temperature; as a result, Caesalpinia Sappan derived carbon nanoparticles pyrolyzed at 1000 °C (CSCNP1000) exhibited the largest surface area (794 m2 g−1 by BET) and pore volume (0.37 cm3 g−1) in the series. The resulted carbon products were microporous/mesoporous in nature, the condition which is considered suitable for the energy storage applications. The energy storage device, supercapacitor, was fabricated which exhibited a specific capacitance of 170.5 F g−1 at 0.25 A g−1. This work demonstrated the suitability of temperature dependent surface of a carbon nanoparticle to be actively used as a cost-effective energy storage device. Springer Berlin Heidelberg 2021-07-16 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33964/7/An%20investigation%20on%20temperature%E2%80%91dependant.pdf S., Supriya and Bhat, Vinay S. and Jayeoye, Titilope John and Rujiralai, Thitima and Chong, Kwok Feng and Hegde, Gurumurthy (2021) An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass. Journal of Nanostructure in Chemistry. pp. 1-17. ISSN 2008-9244 (Print); 2193-8865 (Online). (Published) https://doi.org/10.1007/s40097-021-00427-4 https://doi.org/10.1007/s40097-021-00427-4
spellingShingle QD Chemistry
S., Supriya
Bhat, Vinay S.
Jayeoye, Titilope John
Rujiralai, Thitima
Chong, Kwok Feng
Hegde, Gurumurthy
An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
title An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
title_full An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
title_fullStr An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
title_full_unstemmed An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
title_short An investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
title_sort investigation on temperature-dependant surface properties of porous carbon nanoparticles derived from biomass
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/33964/
http://umpir.ump.edu.my/id/eprint/33964/
http://umpir.ump.edu.my/id/eprint/33964/
http://umpir.ump.edu.my/id/eprint/33964/7/An%20investigation%20on%20temperature%E2%80%91dependant.pdf