Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis

Wax deposits are undesirable as they affect crude oil production. Wax inhibitor which changes crude oil properties like pour point, viscosity and wax appearance temperature (WAT) are used by oil industries. The efficiency of wax inhibitor poly (ethylene-co-vinyl acetate) (EVA), poly (maleic anhydrid...

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Main Authors: Priyatachni, Subramanie, Shamala Devi, Vijayakumar, Norida, Ridzuan
Format: Article
Language:English
English
Published: Taylor & Francis 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/33815/
http://umpir.ump.edu.my/id/eprint/33815/1/Effect%20of%20wax%20inhibitor%20and%20sodium%20cloisite%20Na%20nanoparticle%20on%20wax%20deposition%20of%20Malaysian%20crude%20oil%20through%20cold%20finger%20analysis.pdf
http://umpir.ump.edu.my/id/eprint/33815/7/Effect%20of%20wax%20inhibitor%20and%20sodium%20cloisite%2C%20Na%2B%20nanoparticle%20.pdf
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author Priyatachni, Subramanie
Shamala Devi, Vijayakumar
Norida, Ridzuan
author_facet Priyatachni, Subramanie
Shamala Devi, Vijayakumar
Norida, Ridzuan
author_sort Priyatachni, Subramanie
building UMP Institutional Repository
collection Online Access
description Wax deposits are undesirable as they affect crude oil production. Wax inhibitor which changes crude oil properties like pour point, viscosity and wax appearance temperature (WAT) are used by oil industries. The efficiency of wax inhibitor poly (ethylene-co-vinyl acetate) (EVA), poly (maleic anhydride-alt-1-octadecene) (MA) and sodium cloisite Na+ nanoparticle (NP) is assessed in this research to determine their effects on the wax deposition of Malaysian crude oil. Cold finger analysis was used to identify the best inhibitor to prevent the wax formation. The highest paraffin inhibition efficiency (PIE) obtained was at 80.91% when the crude oil was treated with EVA/NP blend of 1000 ppm EVA and NP of 600 ppm. The minimum amount of wax formed was at 25 °C proving that cold finger temperature plays a crucial role in altering the wax deposition. The van der Waals (vdW) molecular interaction between wax molecules and wax inhibitor was studied with molecular dynamics simulation (MD). The radial distribution function (rdf) value shifted from 2.75 Å to 3.25 Å when EVA/NP blend was used as the inhibitor, supporting the experimental data. The EVA/NP blend offers significant effect in reduction of wax deposit amount.
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spelling ump-338152022-08-02T03:49:26Z http://umpir.ump.edu.my/id/eprint/33815/ Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis Priyatachni, Subramanie Shamala Devi, Vijayakumar Norida, Ridzuan TA Engineering (General). Civil engineering (General) TC Hydraulic engineering. Ocean engineering TP Chemical technology Wax deposits are undesirable as they affect crude oil production. Wax inhibitor which changes crude oil properties like pour point, viscosity and wax appearance temperature (WAT) are used by oil industries. The efficiency of wax inhibitor poly (ethylene-co-vinyl acetate) (EVA), poly (maleic anhydride-alt-1-octadecene) (MA) and sodium cloisite Na+ nanoparticle (NP) is assessed in this research to determine their effects on the wax deposition of Malaysian crude oil. Cold finger analysis was used to identify the best inhibitor to prevent the wax formation. The highest paraffin inhibition efficiency (PIE) obtained was at 80.91% when the crude oil was treated with EVA/NP blend of 1000 ppm EVA and NP of 600 ppm. The minimum amount of wax formed was at 25 °C proving that cold finger temperature plays a crucial role in altering the wax deposition. The van der Waals (vdW) molecular interaction between wax molecules and wax inhibitor was studied with molecular dynamics simulation (MD). The radial distribution function (rdf) value shifted from 2.75 Å to 3.25 Å when EVA/NP blend was used as the inhibitor, supporting the experimental data. The EVA/NP blend offers significant effect in reduction of wax deposit amount. Taylor & Francis 2021-09-16 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33815/1/Effect%20of%20wax%20inhibitor%20and%20sodium%20cloisite%20Na%20nanoparticle%20on%20wax%20deposition%20of%20Malaysian%20crude%20oil%20through%20cold%20finger%20analysis.pdf pdf en http://umpir.ump.edu.my/id/eprint/33815/7/Effect%20of%20wax%20inhibitor%20and%20sodium%20cloisite%2C%20Na%2B%20nanoparticle%20.pdf Priyatachni, Subramanie and Shamala Devi, Vijayakumar and Norida, Ridzuan (2021) Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis. Petroleum Science and Technology, 39 (19-20). pp. 860-877. ISSN 1091-6466 (Print), 1532-2459 (Online). (Published) https://doi.org/10.1080/10916466.2021.1973496 https://doi.org/10.1080/10916466.2021.1973496
spellingShingle TA Engineering (General). Civil engineering (General)
TC Hydraulic engineering. Ocean engineering
TP Chemical technology
Priyatachni, Subramanie
Shamala Devi, Vijayakumar
Norida, Ridzuan
Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis
title Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis
title_full Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis
title_fullStr Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis
title_full_unstemmed Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis
title_short Effect of wax inhibitor and sodium cloisite, Na+ nanoparticle on wax deposition of Malaysian crude oil through cold finger analysis
title_sort effect of wax inhibitor and sodium cloisite, na+ nanoparticle on wax deposition of malaysian crude oil through cold finger analysis
topic TA Engineering (General). Civil engineering (General)
TC Hydraulic engineering. Ocean engineering
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/33815/
http://umpir.ump.edu.my/id/eprint/33815/
http://umpir.ump.edu.my/id/eprint/33815/
http://umpir.ump.edu.my/id/eprint/33815/1/Effect%20of%20wax%20inhibitor%20and%20sodium%20cloisite%20Na%20nanoparticle%20on%20wax%20deposition%20of%20Malaysian%20crude%20oil%20through%20cold%20finger%20analysis.pdf
http://umpir.ump.edu.my/id/eprint/33815/7/Effect%20of%20wax%20inhibitor%20and%20sodium%20cloisite%2C%20Na%2B%20nanoparticle%20.pdf