Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application
Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high...
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| Format: | Book Chapter |
| Language: | English English English |
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Trans Tech Publications
2020
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| Online Access: | http://umpir.ump.edu.my/id/eprint/33732/ http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf |
| _version_ | 1848824331037048832 |
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| author | Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan |
| author_facet | Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan |
| author_sort | Amir Luqman, Sanusi |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high surface area, porous, and structure tunability. This paper reports the synthesis of ternary MOF of copper (Cu), nickel (Ni) and cobalt (Co) with 1,4-benzenedicarboxylic acid. The Co/Cu/Ni-MOF is synthesized using hydrothermal method at 160 °C for 12h and further develop as a BSH electrode. The physicochemical properties of MOF were characterized using FESEM, FTIR, XRD, BET and the electrochemical properties were evaluated using cyclic voltammetry (CV), charge-discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS). Electrochemical analysis indicated that the MOF has high specific capacitance (CS) of 591 F g-1 at a current density of 1 A g-1 and 519 F g-1 at scan rate of 2 mV s-1, and possess low series resistance (RS) of 0.44 Ω and equivalent distributed resistance (Rd) of 1.07 Ω. |
| first_indexed | 2025-11-15T03:11:20Z |
| format | Book Chapter |
| id | ump-33732 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English English English |
| last_indexed | 2025-11-15T03:11:20Z |
| publishDate | 2020 |
| publisher | Trans Tech Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-337322024-01-03T03:30:59Z http://umpir.ump.edu.my/id/eprint/33732/ Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan QD Chemistry TP Chemical technology Metal-organic frameworks (MOFs) composed by coordination bonds between metal ion with organic linker has a uniform combination of micro and mesoporous structures has been used for several application including battery supercapacitor hybrid. (BSH). In BSH, MOF offer several advantages including high surface area, porous, and structure tunability. This paper reports the synthesis of ternary MOF of copper (Cu), nickel (Ni) and cobalt (Co) with 1,4-benzenedicarboxylic acid. The Co/Cu/Ni-MOF is synthesized using hydrothermal method at 160 °C for 12h and further develop as a BSH electrode. The physicochemical properties of MOF were characterized using FESEM, FTIR, XRD, BET and the electrochemical properties were evaluated using cyclic voltammetry (CV), charge-discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS). Electrochemical analysis indicated that the MOF has high specific capacitance (CS) of 591 F g-1 at a current density of 1 A g-1 and 519 F g-1 at scan rate of 2 mV s-1, and possess low series resistance (RS) of 0.44 Ω and equivalent distributed resistance (Rd) of 1.07 Ω. Trans Tech Publications 2020-03-12 Book Chapter PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf pdf en http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf pdf en http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf Amir Luqman, Sanusi and Nurul Khairiyyah, Mohd Zain and Izan Izwan, Misnon and Ahmad Salihin, Samsudin and Jose, Rajan (2020) Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application. In: Materials Science Forum. Trans Tech Publications, Switzerland, pp. 17-22. ISBN 978-303571664-1 https://doi.org/10.4028/www.scientific.net/MSF.981.17 https://www.scientific.net/MSF.981.17 |
| spellingShingle | QD Chemistry TP Chemical technology Amir Luqman, Sanusi Nurul Khairiyyah, Mohd Zain Izan Izwan, Misnon Ahmad Salihin, Samsudin Jose, Rajan Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| title | Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| title_full | Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| title_fullStr | Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| title_full_unstemmed | Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| title_short | Synthesis and electrochemical properties of ternary Co-, Cu- and Ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| title_sort | synthesis and electrochemical properties of ternary co-, cu- and ni- based metal-organic frameworks electrode for battery supercapacitor hybrid application |
| topic | QD Chemistry TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/33732/ http://umpir.ump.edu.my/id/eprint/33732/ http://umpir.ump.edu.my/id/eprint/33732/ http://umpir.ump.edu.my/id/eprint/33732/1/amir.pdf http://umpir.ump.edu.my/id/eprint/33732/7/MSF.981.pdf http://umpir.ump.edu.my/id/eprint/33732/8/Synthesis%20and%20electrochemical%20properties%20of%20ternary%20.pdf |