Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation

This paper studies the synthesis of superabsorbent carbonaceous kenaf fibre filled polymer using inverse suspension polymerisation method. The kenaf fibre was prepared using the hydrothermal carbonisation process. Inverse suspension polymerisation process involved two different solution mixtures; a...

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Main Authors: Munirah Ezzah, Tuan Zakaria, Saidatul Shima, Jamari, Suriati, Ghazali
Format: Article
Language:English
Published: Faculty Mechanical Engineering, UMP 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/33613/
http://umpir.ump.edu.my/id/eprint/33613/1/Synthesis%20of%20superabsorbent%20carbonaceous%20kenaf%20fibre%20filled_FULL.pdf
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author Munirah Ezzah, Tuan Zakaria
Saidatul Shima, Jamari
Suriati, Ghazali
author_facet Munirah Ezzah, Tuan Zakaria
Saidatul Shima, Jamari
Suriati, Ghazali
author_sort Munirah Ezzah, Tuan Zakaria
building UMP Institutional Repository
collection Online Access
description This paper studies the synthesis of superabsorbent carbonaceous kenaf fibre filled polymer using inverse suspension polymerisation method. The kenaf fibre was prepared using the hydrothermal carbonisation process. Inverse suspension polymerisation process involved two different solution mixtures; a continuous phase containing cyclohexane, span-80, and kenaf fibre filler and a dispersed phase containing partially neutralised acrylic acid, acrylamide, initiator APS, and crosslinker NN-Methylenebisacrylamide. Kenaf fibre filler addition was varied with different weight percentages (0.01- 0.05 wt%). Water absorption testing using the teabag method showed sample containing 0.04 wt% carbon filler had the highest and optimal percentage of water absorbency, 55.27 g/g while the sample containing 0.01 wt% carbon filler displayed the lowest percentage of water absorbency, 45.27 g/g. All SPC samples showed a higher rate of water absorbency compared to SAP sample which had 40.61 g/g of average water absorbency. The samples were characterised by FTIR, FESEM - EDX, Mastersizer. All synthesised samples produced were in spherical beads form. It can be concluded that kenaf fibre affects the enhancement of superabsorbent polymer performance.
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spelling ump-336132022-08-25T04:32:39Z http://umpir.ump.edu.my/id/eprint/33613/ Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation Munirah Ezzah, Tuan Zakaria Saidatul Shima, Jamari Suriati, Ghazali TP Chemical technology This paper studies the synthesis of superabsorbent carbonaceous kenaf fibre filled polymer using inverse suspension polymerisation method. The kenaf fibre was prepared using the hydrothermal carbonisation process. Inverse suspension polymerisation process involved two different solution mixtures; a continuous phase containing cyclohexane, span-80, and kenaf fibre filler and a dispersed phase containing partially neutralised acrylic acid, acrylamide, initiator APS, and crosslinker NN-Methylenebisacrylamide. Kenaf fibre filler addition was varied with different weight percentages (0.01- 0.05 wt%). Water absorption testing using the teabag method showed sample containing 0.04 wt% carbon filler had the highest and optimal percentage of water absorbency, 55.27 g/g while the sample containing 0.01 wt% carbon filler displayed the lowest percentage of water absorbency, 45.27 g/g. All SPC samples showed a higher rate of water absorbency compared to SAP sample which had 40.61 g/g of average water absorbency. The samples were characterised by FTIR, FESEM - EDX, Mastersizer. All synthesised samples produced were in spherical beads form. It can be concluded that kenaf fibre affects the enhancement of superabsorbent polymer performance. Faculty Mechanical Engineering, UMP 2021 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/33613/1/Synthesis%20of%20superabsorbent%20carbonaceous%20kenaf%20fibre%20filled_FULL.pdf Munirah Ezzah, Tuan Zakaria and Saidatul Shima, Jamari and Suriati, Ghazali (2021) Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation. Journal of Mechanical Engineering and Sciences (JMES), 11 (3). pp. 1-8. ISSN 2289-4659 (print); 2231-8380 (online). (Published) https://doi.org/10.15282/jmes.11.3.2017.2.0253 https://doi.org/10.15282/jmes.11.3.2017.2.0253
spellingShingle TP Chemical technology
Munirah Ezzah, Tuan Zakaria
Saidatul Shima, Jamari
Suriati, Ghazali
Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
title Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
title_full Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
title_fullStr Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
title_full_unstemmed Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
title_short Synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
title_sort synthesis of superabsorbent carbonaceous kenaf fibre filled polymer via inverse suspension polymerisation
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/33613/
http://umpir.ump.edu.my/id/eprint/33613/
http://umpir.ump.edu.my/id/eprint/33613/
http://umpir.ump.edu.my/id/eprint/33613/1/Synthesis%20of%20superabsorbent%20carbonaceous%20kenaf%20fibre%20filled_FULL.pdf